Important results of analyzing foundations of quantum mechanics

Leonid G. Kreidik, George P. Shpenkov

Published Jan 1, 2002• 11 citations

Abstract

The foundations of quantum mechanics are analyzed, and some problems that appeared during its crea-tion and remain unsolved today are emphasized. It is shown that the introduction of variable wave number k, depending on electron coordinates, and the omission of the azimuth part of the wave function ̂ ψ, were erro-neous. Including the azimuth factor of the wave function and taking into consideration the constant value of k result in wave-equation solutions showing a discrete nodal structure of intratomic space, and arrives at a peri-odic-nonperiodic law for behavior of atomic structures. Viewing atoms as quasi-spherical neutron molecules makes it possible to understand characteristic features of the periodic table. PACS Numbers: 03.65.Bz, 03.65.Ge 1.

Related papers

The Foundations of Quantum Physics

Some aspects of the interpretation of quantum theory are discussed.It is emphasized that quantum theory is formulated in a Cartesian coordinate system; in other coordinates the result obtained with the help of the Hamiltonian formalism and commutator relations between 'canonically conjugated' coordinate and momentum operators leads to a wrong version of quantum mechanics.In this connection the Feynman integral formalism is also discussed.In this formalism the measure is not well-defined and there is no idea how to distinguish between the true version of quantum mechanics and an incorrect one; it is rather a mnemonic rule to generate perturbation series from an undefined zero order term.The origin of time is analyzed in detail by the example of atomic collisions.It is shown that the time-dependent Schrödinger equation for the closed three-body (two nuclei + electron) system has no physical meaning since in the high impact energy limit it transforms into an equation with two independent time-like variables; the time appears in the stationary Schrödinger equation as a result of extraction of a classical subsystem (two nuclei) from a closed three-body system.Following the Einstein-Rosen-Podolsky experiment and Bell's inequality the wave function is interpreted as an actual field of information in the elementary form.The relation between physics and mathematics is also discussed.

Taylor & Francis eBooksAug 9, 20061 citation

The Historical and Physical Foundations of Quantum Mechanics

Robert Golub, S. K. Lamoreaux

Abstract Following the path by which humanity learned quantum mechanics can lead to an improved understanding of the theory and the origins of its perceived limitations. Our goal is to retrace the development by investigating primary sources, including original published papers and letters, with attention to their timing and influence. Quantum mechanics began in 1900 with the introduction of Planck’s constant, which lead to the “old” quantum theory and Bohr’s model of the atom. With the introduction of matter waves in 1924, a second more intense period began. By 1928 the complete fundamental structure of quantum mechanics was established with the introduction of the Schrödinger equation, the proof of its equivalence to Heisenberg’s matrix mechanics, and the introduction of the relativistic Dirac equation. The theory retains the same essential form today, fueling the technological revolution that began in the last century. We culminate with an introduction to quantum information and computing. This completely new physical scientific paradigm was developed largely in Germany during a period of enormous social, economic, and political upheaval—in a hostile intellectual environment—that parallels the overturning of classical physics. It is striking that all the problems debated today were immediately recognized by the founders of the theory and instructive to see how they dealt with the various issues. We emphasize the centrality of the often neglected second quantization form of the theory for questions of interpretation and give a detailed examination of von Neumann’s widely misunderstood hidden variable theorem.

Feb 28, 202310 citations

On foundation of quantum physics

Е. А. Соловьев

Some aspects of the interpretation of quantum theory are discussed. It is emphasized that quantum theory is formulated in the Cartesian coordinate system; in other coordinates the result obtained with the help of the Hamiltonian formalism and commutator relations between “canonically conjugated” coordinate and momentum operators leads to a wrong version of quantum mechanics. The origin of time is analyzed by the example of atomic collision theory in detail; it is shown that the time-dependent Schrödinger equation is meaningless since in the high-impact-energy limit it transforms into an equation with two time-like variables. Following the Einstein-Rozen-Podolsky experiment and Bell’s inequality, the wave function is interpreted as an actual field of information in the elementary form. The concept “measurement” is also discussed.

arXiv:1001.2683Physics of Atomic NucleiMay 1, 200914 citations

Quantum Mechanics: Concepts and Applications

Nouredine Zettili

Preface. 1. Origins of Quantum Physics. 1.1 Historical Note. 1.2 Particle Aspect of Radiation. 1.3 Wave Aspect of Particles. 1.4 Particles versus Waves. 1.5 Indeterministic Nature of the Microphysical World. 1.6 Atomic Transitions and Spectroscopy. 1.7 Quantization Rules. 1.8 Wave Packets. 1.9 Concluding Remarks. 1.10 Solved Problems. Exercises. 2. Mathematical Tools of Quantum Mechanics. 2.1 Introduction. 2.2 The Hilbert Space and Wave Functions. 2.3 Dirac Notation. 2.4 Operators. 2.5 Representation in Discrete Bases. 2.6 Representation in Continuous Bases. 2.7 Matrix and Wave Mechanics. 2.8 Concluding Remarks. 2.9 Solved Problems. Exercises. 3. Postulates of Quantum Mechanics. 3.1 Introduction. 3.2 The Basic Postulates of Quantum Mechanics. 3.3 The State of a System. 3.4 Observables and Operators. 3.5 Measurement in Quantum Mechanics. 3.6 Time Evolution of the System's State. 3.7 Symmetries and Conservation Laws. 3.8 Connecting Quantum to Classical Mechanics. 3.9 Solved Problems. Exercises. 4. One-Dimensional Problems. 4.1 Introduction. 4.2 Properties of One-Dimensional Motion. 4.3 The Free Particle: Continuous States. 4.4 The Potential Step. 4.5 The Potential Barrier and Well. 4.6 The Infinite Square Well Potential. 4.7 The Finite Square Well Potential. 4.8 The Harmonic Oscillator. 4.9 Numerical Solution of the Schrodinger Equation. 4.10 Solved Problems. Exercises. 5. Angular Momentum. 5.1 Introduction. 5.2 Orbital Angular Momentum. 5.3 General Formalism of Angular Momentum. 5.4 Matrix Representation of Angular Momentum. 5.5 Geometrical Representation of Angular Momentum. 5.6 Spin Angular Momentum. 5.7 Eigen functions of Orbital Angular Momentum. 5.8 Solved Problems. Exercises. 6. Three-Dimensional Problems. 6.1 Introduction. 6.2 3D Problems in Cartesian Coordinates. 6.3 3D Problems in Spherical Coordinates. 6.4 Concluding Remarks. 6.5 Solved Problems. Exercises. 7. Rotations and Addition of Angular Momenta. 7.1 Rotations in Classical Physics. 7.2 Rotations in Quantum Mechanics. 7.3 Addition of Angular Momenta. 7.4 Scalar, Vector and Tensor Operators. 7.5 Solved Problems. Exercises. 8. Identical Particles. 8.1 Many-Particle Systems. 8.2 Systems of Identical Particles. 8.3 The Pauli Exclusion Principle. 8.4 The Exclusion Principle and the Periodic Table. 8.5 Solved Problems. Exercises. 9. Approximation Methods for Stationary States. 9.1 Introduction. 9.2 Time-Independent Perturbation Theory. 9.3 The Variational Method. 9.4 The Wentzel Kramers Brillou in Method. 9.5 Concluding Remarks. 9.6 Solved Problems. Exercises. 10. Time-Dependent Perturbation Theory. 10.1 Introduction. 10.2 The Pictures of Quantum Mechanics. 10.3 Time-Dependent Perturbation Theory. 10.4 Adiabatic and Sudden Approximations. 10.5 Interaction of Atoms with Radiation. 10.6 Solved Problems. Exercises. 11. Scattering Theory. 11.1 Scattering and Cross Section. 11.2 Scattering Amplitude of Spinless Particles. 11.3 The Born Approximation. 11.4 Partial Wave Analysis. 11.5 Scattering of Identical Particles. 11.6 Solved Problems. Exercises. A. The Delta Function. A.1 One-Dimensional Delta Function. A.2 Three-Dimensional Delta Function. B. Angular Momentum in Spherical Coordinates. B.1 Derivation of Some General. B.2 Gradient and Laplacianin Spherical Coordinates. B.3 Angular Momentum in Spherical Coordinates. C. Computer Code for Solving the Schrodinger Equation. Index.

Oct 1, 200143 citations

The wave function

Donald D. Fitts

Quantum mechanics is a theory to explain and predict the behavior of particles such as electrons, protons, neutrons, atomic nuclei, atoms, and molecules, as well as the photon–the particle associated with electromagnetic radiation or light. From quantum theory we obtain the laws of chemistry as well as explanations for the properties of materials, such as crystals, semiconductors, superconductors, and superfluids. Applications of quantum behavior give us transistors, computer chips, lasers, and masers. The relatively new field of molecular biology, which leads to our better understanding of biological structures and life processes, derives from quantum considerations. Thus, quantum behavior encompasses a large fraction of modern science and technology. Quantum theory was developed during the first half of the twentieth century through the efforts of many scientists. In 1926, E. Schrödinger interjected wave mechanics into the array of ideas, equations, explanations, and theories that were prevalent at the time to explain the growing accumulation of observations of quantum phenomena. His theory introduced the wave function and the differential wave equation that it obeys. Schrödinger's wave mechanics is now the backbone of our current conceptional understanding and our mathematical procedures for the study of quantum phenomena. Our presentation of the basic principles of quantum mechanics is contained in the first three chapters. Chapter 1 begins with a treatment of plane waves and wave packets, which serves as background material for the subsequent discussion of the wave function for a free particle.

Cambridge University Press eBooksAug 26, 19990 citations

Introduction

N. J. B. Green

This introductory chapter provides an overview of quantum mechanics, which is a subject of central importance in chemistry, and is by nature a mathematical theory. The chemist's approach to the understanding of matter and its chemical transformations is to take a microscopic view, connecting experimental observation with the properties of constituent molecules. However, at the microscopic level, atoms, molecules, and their constituent particles do not obey the familiar laws of mechanics that pertain to the everyday macroscopic world. For example, the existence of molecular line spectra indicates that molecules can be found only at certain well-defined energies, unlike objects at our own scale whose energy appears to be continuously variable. This book aims to explain the fundamentals of quantum mechanics from the point of view of chemistry; describe the areas of chemistry where quantum mechanics is most important; and show how quantum mechanics is applied to chemical problems.

Oxford University Press eBooksSep 11, 19970 citations