Preface. 1. Origins of Quantum Physics. 1.1 Historical Note. 1.2 Particle Aspect of Radiation. 1.3 Wave Aspect of Particles. 1.4 Particles versus Waves. 1.5 Indeterministic Nature of the Microphysical World. 1.6 Atomic Transitions and Spectroscopy. 1.7 Quantization Rules. 1.8 Wave Packets. 1.9 Concluding Remarks. 1.10 Solved Problems. Exercises. 2. Mathematical Tools of Quantum Mechanics. 2.1 Introduction. 2.2 The Hilbert Space and Wave Functions. 2.3 Dirac Notation. 2.4 Operators. 2.5 Representation in Discrete Bases. 2.6 Representation in Continuous Bases. 2.7 Matrix and Wave Mechanics. 2.8 Concluding Remarks. 2.9 Solved Problems. Exercises. 3. Postulates of Quantum Mechanics. 3.1 Introduction. 3.2 The Basic Postulates of Quantum Mechanics. 3.3 The State of a System. 3.4 Observables and Operators. 3.5 Measurement in Quantum Mechanics. 3.6 Time Evolution of the System's State. 3.7 Symmetries and Conservation Laws. 3.8 Connecting Quantum to Classical Mechanics. 3.9 Solved Problems. Exercises. 4. One-Dimensional Problems. 4.1 Introduction. 4.2 Properties of One-Dimensional Motion. 4.3 The Free Particle: Continuous States. 4.4 The Potential Step. 4.5 The Potential Barrier and Well. 4.6 The Infinite Square Well Potential. 4.7 The Finite Square Well Potential. 4.8 The Harmonic Oscillator. 4.9 Numerical Solution of the Schrodinger Equation. 4.10 Solved Problems. Exercises. 5. Angular Momentum. 5.1 Introduction. 5.2 Orbital Angular Momentum. 5.3 General Formalism of Angular Momentum. 5.4 Matrix Representation of Angular Momentum. 5.5 Geometrical Representation of Angular Momentum. 5.6 Spin Angular Momentum. 5.7 Eigen functions of Orbital Angular Momentum. 5.8 Solved Problems. Exercises. 6. Three-Dimensional Problems. 6.1 Introduction. 6.2 3D Problems in Cartesian Coordinates. 6.3 3D Problems in Spherical Coordinates. 6.4 Concluding Remarks. 6.5 Solved Problems. Exercises. 7. Rotations and Addition of Angular Momenta. 7.1 Rotations in Classical Physics. 7.2 Rotations in Quantum Mechanics. 7.3 Addition of Angular Momenta. 7.4 Scalar, Vector and Tensor Operators. 7.5 Solved Problems. Exercises. 8. Identical Particles. 8.1 Many-Particle Systems. 8.2 Systems of Identical Particles. 8.3 The Pauli Exclusion Principle. 8.4 The Exclusion Principle and the Periodic Table. 8.5 Solved Problems. Exercises. 9. Approximation Methods for Stationary States. 9.1 Introduction. 9.2 Time-Independent Perturbation Theory. 9.3 The Variational Method. 9.4 The Wentzel Kramers Brillou in Method. 9.5 Concluding Remarks. 9.6 Solved Problems. Exercises. 10. Time-Dependent Perturbation Theory. 10.1 Introduction. 10.2 The Pictures of Quantum Mechanics. 10.3 Time-Dependent Perturbation Theory. 10.4 Adiabatic and Sudden Approximations. 10.5 Interaction of Atoms with Radiation. 10.6 Solved Problems. Exercises. 11. Scattering Theory. 11.1 Scattering and Cross Section. 11.2 Scattering Amplitude of Spinless Particles. 11.3 The Born Approximation. 11.4 Partial Wave Analysis. 11.5 Scattering of Identical Particles. 11.6 Solved Problems. Exercises. A. The Delta Function. A.1 One-Dimensional Delta Function. A.2 Three-Dimensional Delta Function. B. Angular Momentum in Spherical Coordinates. B.1 Derivation of Some General. B.2 Gradient and Laplacianin Spherical Coordinates. B.3 Angular Momentum in Spherical Coordinates. C. Computer Code for Solving the Schrodinger Equation. Index.
Preface. 1. Origins of Quantum Physics. 1.1 Historical Note. 1.2 Particle Aspect of Radiation. 1.3 Wave Aspect of Particles. 1.4 Particles versus Waves. 1.5 Indeterministic Nature of the Microphysical World. 1.6 Atomic Transitions and Spectroscopy. 1.7 Quantization Rules. 1.8 Wave Packets. 1.9 Concluding Remarks. 1.10 Solved Problems. Exercises. 2. Mathematical Tools of Quantum Mechanics. 2.1 Introduction. 2.2 The Hilbert Space and Wave Functions. 2.3 Dirac Notation. 2.4 Operators. 2.5 Representation in Discrete Bases. 2.6 Representation in Continuous Bases. 2.7 Matrix and Wave Mechanics. 2.8 Concluding Remarks. 2.9 Solved Problems. Exercises. 3. Postulates of Quantum Mechanics. 3.1 Introduction. 3.2 The Basic Postulates of Quantum Mechanics. 3.3 The State of a System. 3.4 Observables and Operators. 3.5 Measurement in Quantum Mechanics. 3.6 Time Evolution of the System's State. 3.7 Symmetries and Conservation Laws. 3.8 Connecting Quantum to Classical Mechanics. 3.9 Solved Problems. Exercises. 4. One-Dimensional Problems. 4.1 Introduction. 4.2 Properties of One-Dimensional Motion. 4.3 The Free Particle: Continuous States. 4.4 The Potential Step. 4.5 The Potential Barrier and Well. 4.6 The Infinite Square Well Potential. 4.7 The Finite Square Well Potential. 4.8 The Harmonic Oscillator. 4.9 Numerical Solution of the Schrodinger Equation. 4.10 Solved Problems. Exercises. 5. Angular Momentum. 5.1 Introduction. 5.2 Orbital Angular Momentum. 5.3 General Formalism of Angular Momentum. 5.4 Matrix Representation of Angular Momentum. 5.5 Geometrical Representation of Angular Momentum. 5.6 Spin Angular Momentum. 5.7 Eigen functions of Orbital Angular Momentum. 5.8 Solved Problems. Exercises. 6. Three-Dimensional Problems. 6.1 Introduction. 6.2 3D Problems in Cartesian Coordinates. 6.3 3D Problems in Spherical Coordinates. 6.4 Concluding Remarks. 6.5 Solved Problems. Exercises. 7. Rotations and Addition of Angular Momenta. 7.1 Rotations in Classical Physics. 7.2 Rotations in Quantum Mechanics. 7.3 Addition of Angular Momenta. 7.4 Scalar, Vector and Tensor Operators. 7.5 Solved Problems. Exercises. 8. Identical Particles. 8.1 Many-Particle Systems. 8.2 Systems of Identical Particles. 8.3 The Pauli Exclusion Principle. 8.4 The Exclusion Principle and the Periodic Table. 8.5 Solved Problems. Exercises. 9. Approximation Methods for Stationary States. 9.1 Introduction. 9.2 Time-Independent Perturbation Theory. 9.3 The Variational Method. 9.4 The Wentzel Kramers Brillou in Method. 9.5 Concluding Remarks. 9.6 Solved Problems. Exercises. 10. Time-Dependent Perturbation Theory. 10.1 Introduction. 10.2 The Pictures of Quantum Mechanics. 10.3 Time-Dependent Perturbation Theory. 10.4 Adiabatic and Sudden Approximations. 10.5 Interaction of Atoms with Radiation. 10.6 Solved Problems. Exercises. 11. Scattering Theory. 11.1 Scattering and Cross Section. 11.2 Scattering Amplitude of Spinless Particles. 11.3 The Born Approximation. 11.4 Partial Wave Analysis. 11.5 Scattering of Identical Particles. 11.6 Solved Problems. Exercises. A. The Delta Function. A.1 One-Dimensional Delta Function. A.2 Three-Dimensional Delta Function. B. Angular Momentum in Spherical Coordinates. B.1 Derivation of Some General. B.2 Gradient and Laplacianin Spherical Coordinates. B.3 Angular Momentum in Spherical Coordinates. C. Computer Code for Solving the Schrodinger Equation. Index.
Table of Contents 1. The Origins of Quantum Mechanics 1.1 Introduction 1.2 Blackbody Radiation The Problem with Blackbody Radiation 1.3 The Nature of Light The Photoelectric Effect The Compton Effect Is it a Particle or a Wave? 1.4 TheWave Nature of Matter 1.5 The Bohr Atom 1.6 Where do we Stand? 2. Math Interlude A: Complex Numbers and Linear Operators 2.1 Complex Numbers 2.2 Operators Definition of an Operator Eigenfunctions and Eigenvalues 3. The Schrodinger Equation 3.1 Derivation of the Schrodinger Equation 3.2 The Meaning of theWave Function 3.3 The Time-Independent Schrodinger Equation Derivation of the Time-Independent Schrodinger Equation Qualitative Solutions and the Origin of Quantization 4. One-Dimensional Time-Independent Schrodinger Equation 4.1 Unbound States: Scattering and Tunneling Scattering From Step-Function Potentials 4.2 Bound Systems The Infinite SquareWell The Harmonic Oscillator Potential 5. Math Interlude B: Linear Algebra 5.1 Properties of Linear Operators 5.2 Vector Spaces Inner Products Adjoint and Hermitian Operators Basis Sets 6. The Three-Dimensional Time-Independent Schrodinger Equation 6.1 Solution in Rectangular Coordinates 6.2 Angular Momentum 6.3 The Schrodinger Equation in Spherical Coordinates 6.4 The Hydrogen Atom 7. Math Interlude C: Matrices, Dirac Notation, and the Dirac Delta Function 7.1 The Matrix Formulation of Linear Operators 7.2 Dirac Notation 7.3 The Dirac Delta Function 8. Spin Angular Momentum 8.1 Spin Operators 8.2 Evidence for Spin 8.3 Adding Angular Momentum 8.4 The Matrix Representation of Spin 8.5 The Stern-Gerlach Experiment 8.6 Spin Precession 8.7 Spin Systems with Two Particles Noninteracting Spins Interacting Spins 8.8 Measurement Theory Hidden Variables The ManyWorlds Interpretation of Quantum Mechanics 9. Time-Independent Perturbation Theory 9.1 Derivation of Time-Independent Perturbation Theory 9.2 Perturbations to the Atomic Energy Levels Fine Structure The Lamb Shift 9.3 The Atom in External Electric or Magnetic Fields The Atom in an Electric Field: The Stark Effect The Atom in a Magnetic Field: The Zeeman Effect 10. The Variational Principle 10.1 Variational Principle: Theory 10.2 Variational Principle: Application to the Helium Atom 11. Time-Dependent Perturbation Theory 11.1 Derivation of Time-Dependent Perturbation Theory 11.2 Application: Selection Rules for Electromagnetic Radiation 12. Scattering Theory 12.1 Definition of the Cross Section 12.2 The Born Approximation 12.3 PartialWaves 13. The Multiparticle Schrodinger Equation 13.1 Wave Function for Identical Particles 13.2 Multielectron Atoms 14. Some Modern Applications of Quantum Mechanics 14.1 Magnetic Resonance Imaging 14.2 Quantum Computing 15. What Comes Next? Relativistic Quantum Mechanics 15.1 The Klein-Gordon Equation Derivation of the Klein-Gordon Equation Probability Densities and Currents 15.2 The Dirac Equation Answers and Hints for Selected End-of-Chapter Exercises Index
QUANTUM PRINCIPLES Perspective and Principles Prelude to Quantum Mechanics Stern-Gerlach Experiment Idealized Stern-Gerlach Results Classical Model Attempts Wave Functions for Two Physical-Outcome Case Process Diagrams, Operators, and Completeness Further Properties of Operators/Modulation Operator Reformulation Operator Rotation Bra-Ket Notation/Basis States Transition Amplitudes Three-Magnet Setup Example-Coherence Hermitian Conjugation Unitary Operators A Very Special Operator Matrix Representations Matrix Wave Function Recovery Expectation Values Wrap Up Problems Free Particles in One Dimension Photoelectric Effect Compton Effect Uncertainty Relation for Photons Stability of Ground States Bohr Model Fourier Transform and Uncertainty Relations Schrodinger Equation Schrodinger Equation Example Dirac Delta Functions Wave Functions and Probability Probability Current Time Separable Solutions Completeness for Particle States Particle Operator Properties Operator Rules Time Evolution and Expectation Values Wrap-Up Problems Some One-Dimensional Solutions to the Schrodinger Equation Introduction The Infinite Square Well: Differential Solution The Infinite Square Well: Operator Solution The Finite Potential Barrier Step Potential The Harmonic Oscillator The Attractive Kronig-Penny Model Bound State and Scattering Solutions Problems Hilbert Space and Unitary Transformations Introduction and Notation Inner and Outer Operator Products Operator-Matrix Relationship Hermitian Operators and Eigenkets Gram-Schmidt Orthogonalization Process Compatible Operators Uncertainty Relations and Incompatible Operators Simultaneously Measureable Operators Unitary Transformations and Change of Basis Coordinate Displacements and Unitary Transformations Schrodinger and Heisenburg Pictures of Time Evolution Free Gaussian Wave Packet in the Heisenberg Picture Potentials and the Ehrenfest Theorem Problems Three Static Approximation Methods Introduction Time-Independent Perturbation Theory Examples of Time-Independent Perturbation Theory Aspects of Degenerate Perturbation Theory WKB Semiclassical Approximation Use of the WKB Approximation in Barrier Penetration Use of the WKB Approximation in Bound States Variational Methods Problems Generalization to Three Dimensions Cartesian Basis States and Wave Functions in Three Dimensions Position/Momentum Eigenket Generalization Example: Three-Dimensional Infinite Square Well Spherical Basis States Orbital Angular Momentum Operator Effect of Angular Momentum on Basis States Energy Eigenvalue Equation and Angular Momentum Complete Set of Observables for the Radial Schrodinger Equation Specification of Angular Momentum Eigenstates Angular Momentum Eigenvectors and Spherical Harmonics Completeness and Other Properties of Spherical Harmonics Radial Eigenfunctions Problems QUANTUM PARTICLES The Three-Dimensional Radial Equation Recap of the Situation The Free Particle The Infinite Spherical Well Potential The Deuteron The Coulomb Potential: Initial Considerations The Coulomb Potential: 2-D Harmonic Oscillator Comparison The Confined Coulombic Model Problems Addition of Angular Momenta General Angular-Momentum Eigenstate Properties Combining Angular Momenta for Two Systems Explicit Example of Adding Two Spin 1/2 Systems Explicit Example of Adding Orbital Angular Momentum and Spin 1/2 Hydrogen Atom and the Choice of Basis States Hydrogen Atom and Perturbative Energy Shifts Problems Spin and Statistics The Connection between Spin and Statistics Building Wave Functions with Identical Particles Particle Occupation Basis More on Fermi-Dirac Statistics Interaction Operator and Feynman Diagrams Implications of Detailed Balance Cubical Enclosures and Particle States Maxwell-Boltzmann Statistics Bose-Einstein Statistics Fermi-Dirac Statistics The Hartree-Fock Equations Problems Quantum Particle Scattering Introduction The One-Dimensional Integral Schrodinger Equation Reflection and Transmission Amplitudes One-Dimensional Delta-Function Scattering Step-Function Potential Scattering The Born Series The Three-Dimensional Integral Schrodinger Equation The Helmholtz Equation and Plane Waves Cross Sections and the Scattering Amplitude Scattering Phase Shifts Finite-Range Potential Scattering The Three-Dimensional Born Series Identical Particle Scattering Proton-Proton Scattering Problems Connecting to the Standard Model Introduction Discrete Symmetries Parity Time Reversal Charge Conjugation Particle Primer Particle Interactions Quantum Electrodynamics Quantum Chromodynamics Weak Interactions Beyond the Standard Model Supersymmetry Superstrings Postlude Helpful Introductory Books on Particle and String Physics More Advanced Books on Particle and String Physics Problems Appendix: Notation Comments and Comparisons Appendix: Lattice Models Appendix: 2-D Harmonic Oscillator Wave Function Normalization Appendix: Allowed Standard Model Interactions Appendix: Weak Flavor Mixing Appendix: The Ising Model and More Index
The goal of Quantum Mechanics I, A Problem Text, is to enable students to solve problems appropriate to their first course in quantum mechanics. Significantly detailed solutions to traditionally posed problems dominate. Theory and rationale are addressed in prescript and postscript narratives and/or within the solved problems to guide students; and clarify vocabulary, symbology, and terminology. Applications of the postulates are presented initially using arguments from linear algebra appropriate to discrete systems with low-dimensional vectors and matrix operators, introducing orthogonality, orthonormality, Hermiticity, eigenvectors, eigenvalues, probability, expectation value, and degeneracy. These arguments blend into infinite-dimensional vectors and operators, and calculus-based arguments for continuous systems where delta functions, theta functions, and Fourier transforms are initially discussed. Dirac notation is fully developed within these first five chapters. Chapter six discusses Ehrenfest’s theorem, the Heisenberg uncertainty relations, and Gaussian wave functions and wave packets. Increasingly sophisticated potential energy functions are then treated to include the free particle, the infinite square well, the one-dimensional scattering state, the simple harmonic oscillator, the finite square well, orbital angular momentum, and the hydrogen atom. Ladder operators are featured in the developments of the simple harmonic oscillator and orbital angular momentum. The diversity of narratives and detailed solutions intend
A Brief Survey of Analytical Dynamics, Discovery of Matrix Mechanics, Mathematical Preliminaries Postulates of Quantum Theory Equations of Motion, Hamiltonian Operator and the Commutation Relations Symmetries and Conservation Laws, Classical and Quantum Integrability Classical and Quantum Mechanical Degeneracies Bound State Energies for One-Dimensional Problems Exactly Solvable Potentials, Supersymmetry and Shape Invariance Supersymmetry and Superpotential Shape Invariant Potentials Two-Body Problem Determination of the Angular Momentum Eigenvalues Methods of Integration of the Heisenberg Equations of Motion Discrete-Time Formulation of the Heisenberg's Equations of Motion Quantum Tunneling Using Discrete-Time Formulation Integration of the Operator Differential Equations Perturbation Theory Other Methods of Approximation Heisenberg Correspondence Principle, Quantization of the Equations of Motion with Higher Derivatives Determinantal Method in Potential Scattering Time-Dependent Scattering Theory The Scattering Matrix Impact Parameter Representation of the Scattering Amplitude Transition Probability Quantum Diffraction, Motion of a Charged Particle in Electromagnetic Field The Aharanov-Bohm Effect Neutron Interferometry Quantum Many-Body Problem Hartree and Hartree-Fock Approximations Second Quantization Bogoliubov Transformation for a Many-Boson System Bogoliubov Transformation for Fermions Interacting Through Pairing Forces Quantum Theory of Free Electromagnetic Field Casimir Force Interaction of Radiation with Matter Heisenberg Equations for Interaction of an Atom with Radiation Bell's Inequalities
This book presents the basic concepts and methods of quantum mechanics for upper level undergraduate students, allowing them to master its application to real physical situations. A postulate-based treatment is adopted together with a gradual development of the quantum formalism of wave functions, operators, measurement and temporal evolution. Standard topics of one-dimensional and atomic motion, angular momentum and approximation methods are presented in addition to detailed discussions of many-particle systems, atomic and nuclear radiation. Appropriate mathematical tools and techniques are provided wherever necessary. The core text is supplemented by 77 worked examples, some of which address more complex issues and aspects of present-day research. The aim is to make this textbook a realistic introduction to more advanced and specialized texts. The material provides full coverage of the subject matter, 94 problems with solutions and a further 93 with answers only