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Chinese journal of atomic and molecular physics

Quantum statistical mechanics of the interaction systems of atom radiation field in the coherent state representation

Bian Qiu

Published Jan 1, 1999• 0 citations
OpenAlex

Abstract

Quantum Statistical Mechanics of interaction systems of atom radiation field is formulated by the use of the representation of coherent state direct prduct. After introducing a newly defined distribution of interaction syetems, the Bloch equation for the equilibrium density matrix is converted into partial differential equation of the type of separating variables. Formal solution of this differential equation is presented. and operator which is composed of a +,a, and its average formula are written down in the present representation.

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Quantum Statistical Mechanics of interaction systems of atom radiation field is formulated by the use of the representation of coherent state direct prduct. After introducing a newly defined distribution of interaction syetems, the Bloch equation for the equilibrium density matrix is converted into partial differential equation of the type of separating variables. Formal solution of this differential equation is presented. and operator which is composed of a +,a, and its average formula are written down in the present representation.
Quantum statistical mechanics of spin systems is formulated by the use of the representation of atomic coherent state of spin, which is specified by a complex number. After introducing a newly defined distribution function of spin, the Bloch equation for the equilibrium density matrix, the von Neumann equation for the nonequilibrium density matrix and the Heisenberg equation of motion are converted into partial differential equations of the type of separating variables respectively. Formal solutions of them are presented. Any operator which is composed of spins can be converted uniquely into a differential operator. Thus we succeed in formulating equilibrium and nonequilibrium quantum statistical mechanics in the complex variable space, which differs from the previous one in the diagonal representation of density matrix. We further introduce the interaction representation for the perturbational expansion. The linear response formula is written down in the present representation.
The theory of quantum statistical mechanics is reviewed in the light of the quantum probability theory developed in recent years by mathematicians. We show that—which is our main motivation here—the former is a special model in the framework of the latter, by extending the characteristic function in the classical probability theory to the quantum probability theory based on the requirements of quantum statistical mechanics. We find that due to the fact that fundamental dynamical variables of a quantum system must respect certain commutation relations, one has to reform the classical characteristic function defined on a Euclidean space to a normalized, nonnegative definite function defined on a group which is generated by a Lie algebra formed from these commutation relations. Our key finding is that the group-theoretical characteristic function could be adopted to replace the density matrix commonly used in quantum statistical mechanics for representing a state of the quantum ensemble, and more than that, the new representation has some significant advantages in applications. To show its advantages compared with the conventional density matrix scenario, we illustrate its applications in: solving the master equation that describes the irreversible evolution of a quantum open system; determining the pointer states of a quantum open system; and expanding the density matrix with the pointer states. In particular, thanks to the quantum characteristic function, we are able to write down the solutions of the quantum-optical master equation explicitly, obtain its steady solutions and verify that the pointer states are exactly coherent states. Besides, the Caldeira-Leggett master equation for the quantum Brownian motion and its extension to the Lindblad type are also studied.
Abstract The functional integral representation of the density matrix at thermal equilibrium in non-relativistic quantum mechanics (QM) with many degrees of freedom, in the grand canonical formulation is introduced. In QM, Hamiltonians H(p,q) can be also expressed in terms of creation and annihilation operators, a method adapted to the study of perturbed harmonic oscillators. In the holomorphic formalism, quantum operators act by multiplication and differentiation on a vector space of analytic functions. Alternatively, they can also be represented by kernels, functions of complex variables that correspond in the classical limit to a complex parametrization of phase space. The formalism is adapted to the description of many-body boson systems. To this formalism corresponds a path integral representation of the density matrix at thermal equilibrium, where paths belong to complex spaces, instead of the more usual position–momentum phase space. A parallel formalism can be set up to describe systems with many fermion degrees of freedom, with Grassmann variables replacing complex variables. Both formalisms can be generalized to quantum gases of Bose and Fermi particles in the grand canonical formulation. Field integral representations of the corresponding quantum partition functions are derived.
The review of new formulation of conventional quantum mechanics where the quantum states are identified with probability distributions is presented. The invertible map of density operators and wave functions onto the probability distributions describing the quantum states in quantum mechanics is constructed both for systems with continuous variables and systems with discrete variables by using the Born's rule and recently suggested method of dequantizer-quantizer operators. Examples of discussed probability representations of qubits (spin-1/2, two-level atoms), harmonic oscillator and free particle are studied in detail. Schrödinger and von Neumann equations, as well as equations for the evolution of open systems, are written in the form of linear classical-like equations for the probability distributions determining the quantum system states. Relations to phase-space representation of quantum states (Wigner functions) with quantum tomography and classical mechanics are elucidated.
While the dynamic state of a single particle can be specified quantum mechanically in terms of its state function, any rigorous description of the state of a many-particle system would require the complete knowledge of the dynamic state functions of all the particles. That is not always possible. On the other hand, for a large number of particles in, or near, thermal equilibrium in a uniform sample, the principles of statistical mechanics may be invoked to describe the averaged expectation values of the physically observable properties of such a many-particle system. The basic concepts of the density-matrix formalism and the quantum mechanic analog of the classical Boltzmann equation commonly used for optical and magnetic resonance problems of many-particle quantum systems are introduced in this chapter. Applications of this approach to such specific problems as the resonant interaction of electromagnetic radiation with optical media of two-level atoms, nonlinear optics, and the laser rate equations and transient dynamics are discussed in this chapter. Definitions of the density operator and the density matrix Up to this point, in studying the dynamics of quantum mechanic systems, we have assumed that the state of the system can be specified in terms of a precisely known state function |Ψ〉. On the other hand, for a macroscopic medium containing many particles, it is not always possible to know the exact dynamic states of all the particles in the medium, even for physically identical particles.