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Progress of Theoretical Physics

Quantum Statistical Mechanics of Spin Systems in the Coherent State Representation

Toshio Tsuzuki

Published Jul 1, 1986• 1 citation
Publisher

Abstract

Quantum statistical mechanics of spin systems is formulated by the use of the representation of atomic coherent state of spin, which is specified by a complex number. After introducing a newly defined distribution function of spin, the Bloch equation for the equilibrium density matrix, the von Neumann equation for the nonequilibrium density matrix and the Heisenberg equation of motion are converted into partial differential equations of the type of separating variables respectively. Formal solutions of them are presented. Any operator which is composed of spins can be converted uniquely into a differential operator. Thus we succeed in formulating equilibrium and nonequilibrium quantum statistical mechanics in the complex variable space, which differs from the previous one in the diagonal representation of density matrix. We further introduce the interaction representation for the perturbational expansion. The linear response formula is written down in the present representation.

DOI
10.1143/ptp.76.52

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Quantum statistical mechanics of spin systems is formulated by the use of the representation of atomic coherent state of spin, which is specified by a complex number. After introducing a newly defined distribution function of spin, the Bloch equation for the equilibrium density matrix, the von Neumann equation for the nonequilibrium density matrix and the Heisenberg equation of motion are converted into partial differential equations of the type of separating variables respectively. Formal solutions of them are presented. Any operator which is composed of spins can be converted uniquely into a differential operator. Thus we succeed in formulating equilibrium and nonequilibrium quantum statistical mechanics in the complex variable space, which differs from the previous one in the diagonal representation of density matrix. We further introduce the interaction representation for the perturbational expansion. The linear response formula is written down in the present representation.
Quantum Statistical Mechanics of interaction systems of atom radiation field is formulated by the use of the representation of coherent state direct prduct. After introducing a newly defined distribution of interaction syetems, the Bloch equation for the equilibrium density matrix is converted into partial differential equation of the type of separating variables. Formal solution of this differential equation is presented. and operator which is composed of a +,a, and its average formula are written down in the present representation.
The review of new formulation of conventional quantum mechanics where the quantum states are identified with probability distributions is presented. The invertible map of density operators and wave functions onto the probability distributions describing the quantum states in quantum mechanics is constructed both for systems with continuous variables and systems with discrete variables by using the Born's rule and recently suggested method of dequantizer-quantizer operators. Examples of discussed probability representations of qubits (spin-1/2, two-level atoms), harmonic oscillator and free particle are studied in detail. Schrödinger and von Neumann equations, as well as equations for the evolution of open systems, are written in the form of linear classical-like equations for the probability distributions determining the quantum system states. Relations to phase-space representation of quantum states (Wigner functions) with quantum tomography and classical mechanics are elucidated.
The theory of quantum statistical mechanics is reviewed in the light of the quantum probability theory developed in recent years by mathematicians. We show that—which is our main motivation here—the former is a special model in the framework of the latter, by extending the characteristic function in the classical probability theory to the quantum probability theory based on the requirements of quantum statistical mechanics. We find that due to the fact that fundamental dynamical variables of a quantum system must respect certain commutation relations, one has to reform the classical characteristic function defined on a Euclidean space to a normalized, nonnegative definite function defined on a group which is generated by a Lie algebra formed from these commutation relations. Our key finding is that the group-theoretical characteristic function could be adopted to replace the density matrix commonly used in quantum statistical mechanics for representing a state of the quantum ensemble, and more than that, the new representation has some significant advantages in applications. To show its advantages compared with the conventional density matrix scenario, we illustrate its applications in: solving the master equation that describes the irreversible evolution of a quantum open system; determining the pointer states of a quantum open system; and expanding the density matrix with the pointer states. In particular, thanks to the quantum characteristic function, we are able to write down the solutions of the quantum-optical master equation explicitly, obtain its steady solutions and verify that the pointer states are exactly coherent states. Besides, the Caldeira-Leggett master equation for the quantum Brownian motion and its extension to the Lindblad type are also studied.
Abstract The functional integral representation of the density matrix at thermal equilibrium in non-relativistic quantum mechanics (QM) with many degrees of freedom, in the grand canonical formulation is introduced. In QM, Hamiltonians H(p,q) can be also expressed in terms of creation and annihilation operators, a method adapted to the study of perturbed harmonic oscillators. In the holomorphic formalism, quantum operators act by multiplication and differentiation on a vector space of analytic functions. Alternatively, they can also be represented by kernels, functions of complex variables that correspond in the classical limit to a complex parametrization of phase space. The formalism is adapted to the description of many-body boson systems. To this formalism corresponds a path integral representation of the density matrix at thermal equilibrium, where paths belong to complex spaces, instead of the more usual position–momentum phase space. A parallel formalism can be set up to describe systems with many fermion degrees of freedom, with Grassmann variables replacing complex variables. Both formalisms can be generalized to quantum gases of Bose and Fermi particles in the grand canonical formulation. Field integral representations of the corresponding quantum partition functions are derived.
A new method of treating problems of spin systems is developed, in which spin operators are transformed into two kinds of boson operators according to Schwinger's method. Usual treatment of coherent state representation is generalized to spin systems with a fixed magnitude S . Some basic properties and the relations to the atomic coherent state are investigated rather in details. The method is applied to spin relaxation process and a corresponding Fokker-Planck type equation is obtained and solved to give a multiple relaxation process due to nonlinearities. It is shown that our formulation has several advantages over other ones in some respects.