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Journal of Science of Teachers' College and University

The deducing of quantum conditions based on WKB approximation method in one dimension potential well

DU Hui-qiu

Published Jan 1, 2010• 0 citations
OpenAlex

Abstract

WKB approximation method has various utilisations including the calculation of potential barrier and potential well.Deduced the quantum conditions of bound states particle for three classical models by WKB approximation method.

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Wenzel-Kramers-Brillouin (WKB) method being an approximation method in quantum mechanics has been applied widely. For the potential problems WKB approximation method is taken as an effective technology. With the help of the WKB approximation method the quantum conditions of bound States particle being in three different typical one dimension (1D) potential well models are derived in this paper. In addition, the idea of the WKB approximation method and the procedures dealing with the potential problems are demonstrated clearly, which are very helpful for understanding the quantum conditions of 1D potential well models deeply and mastering the WKB approximation method to solve some related problems in quantum mechanics.
The WKB approximation is a physically intuitive method and makes many connections with intuition about waves and classical mechanics as well as with results from the early days of quantum theory as it leads to the Bohr quantization condition. The WKB method is due to Gregor Wentzel, Hendrik Anthony Kramers and Leon Nicolas Brillouin. The method is applicable for slowly varying potentials, that is, the potentials that change not more than a few wavelengths. The WKB approximation is a physically intuitive method and makes many connections with intuition about waves and classical mechanics as well as with results from the early days of quantum theory as it leads to the Bohr quantization condition. The Schrödinger equation is solved to find the penetration of a square potential barrier. The WKB method is applied to obtain a transmission coefficient for penetration through a barrier.
Abstract Kratzer potential is a potential for bound states in molecular bonds, while negative Kratzer potential is a potential for scattering states which has a barrier form, and which clearly has properties opposite to the bound state potential. This type of potential is the main subject of this paper. When a non-relativistic particle which has lower energy moving towards the potential, then there is a probability for the particle to break through the potential. In this paper, we use the WKB (Wenztel-Kramers-Brillouin) method to analyze the physical conditions that must be met by the system in order for the tunneling processes to occur. We present these conditions in the form of the relationship among several quantum variables such as the mass of the particle, the energy of the particle, the maximum height of the barrier potential, equilibrium internuclear separation, and the enactment domain of the potential field effect on the particle when the particle breaks through that potential.
A method of approximating solutions of the one-dimensional Schr\"odinger equation is presented in this paper. The method closely resembles the usual WKB approximation. Whereas in the ordinary WKB method the exponential function is used as the basis of the approximation, in this paper the solutions of an arbitrary Schr\"odinger equation are used. The general advantage is that by proper choice of the arbitrary equation an improved approximation can be obtained. The method is illustrated by treating the potential well and potential barrier problems when there are two turning points. The approximations to the wave functions are continuous even across the turning points. The barrier transmission problem is treated uniformly for energies above and below the peak of the barrier.
The accuracy of the WKB approximation when predicting the energy splitting of bound states in a double well potential is the main subject of this paper. The splitting of almost degenerate energy levels below the top of the barrier results from the tunneling and is thus supposed to be exponentially small. By using the standard WKB quantization we deduce an analytical formula for the energy splitting, which is the usual Landau formula with additional quantum corrections. We also examine the accuracy of our and Landau formula numerically for the case of the symmetric double well quartic potential.