By using the multi-step excitation technique, Sr atoms are excited from ground state 5S2 to (4d3/2np, nf)J=1 and (4d5/2np, nf)J=1 autoionizing states via valence state 4d23P0. Their Stark spectra near n = 12, 13, 14 in an electric field of 0-5kV/cm are observed and discussed.