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From the Analogues between Mechanics and Optics to Schrödinger Wave Mechanics

Yong-Yi Huang

Published Jan 1, 2013• 0 citations
OpenAlex

Abstract

th , 2012; revised: Jan. 8 th , 2013; accepted: Jan. 16 th , 2013 Abstract: In order that students have a whole realization of the wave mechanics foundation, we review the two impor- tant enlightened steps in details, i.e. the analogues between mechanics and optics, de Broglie matter wave. Based on the duality of wave and particle, we report the whole process that Schrodinger founded his wave mechanics. We introduce Schrodinger's interesting and deep method of deriving wave equation to quantum mechanics teaching.

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th , 2012; revised: Jan. 8 th , 2013; accepted: Jan. 16 th , 2013 Abstract: In order that students have a whole realization of the wave mechanics foundation, we review the two impor- tant enlightened steps in details, i.e. the analogues between mechanics and optics, de Broglie matter wave. Based on the duality of wave and particle, we report the whole process that Schrodinger founded his wave mechanics. We introduce Schrodinger's interesting and deep method of deriving wave equation to quantum mechanics teaching.
Quantum mechanics is one of basics theories of modern physics, and it is also a theory established with some debates of assumptions. However, in the teaching process, if the assumption of wave-particle duality is directly given, it will be particularly difficult for students to understand. Therefore, based on the teaching practice and previous research, we assume that light corresponds to a kind of real particle starting from the classical electromagnetic theory, according to the description methods of wave optics and geometric optics, and the form of functional equations. Subsequently, employing Planck's quantum conditions, we discuss the connection between the wave nature and particle nature of light. And then the Planck-Einstein relation and the de Broglie relationship are derived, which reflect the wave-particle duality of light and real particle.
Abstract In this paper I explain how I usually introduce the Schrödinger equation during the quantum mechanics course. My preferred method is the chronological one. Since the Schrödinger equation belongs to a special case of wave equations I start the course with introducing the wave equation. The Schrödinger equation is derived with the help of the two quantum concepts introduced by Max Planck, Einstein, and de Broglie, i.e. the energy of a photon E = ћ ω and the wavelength of the de Broglie wave λ = h / p . Finally, the difference between the classical wave equation and the quantum Schrödinger one is explained in order to help the students to grasp the meaning of quantum wavefunction Ψ ( r , t ) . A comparison of the present method to the approaches given by the authors of quantum mechanics textbooks as well as that of the original Nuffield A level is presented. It is found that the present approach is different from those given by these authors, except by Weinberg or Dicke and Wittke. However, the approach is in line with the original Nuffield A level one.
Most authors of textbooks on quantum mechanics either postulate or sketch a short `ad hoc` derivation of Schrodinger's equation. In this work we give a detailed derivation of Schrodinger's equation from the Hamilton-Jacobi equation and the Eikonal equation in geometrical optics. We start from the historical debates on the nature of light -- whether it is a beam of particles, or waves in the aether. We derive the Eikonal equation and show the conditions when a wave can behave as a beam of particles. Then we discuss several experiments with an electron gun, that show clearly diffraction and interference of a single electron. Next, in order to explain these experiments, we derive Schrodinger's equation by comparing Hamilton-Jacobi equation in classical mechanics with the Eikonal equation in geometrical optics. To do that, we first show how to derive the wave equation from the Eikonal equation (not the other way around!). Second, we use this method to derive Schrodinger's equation from the Hamilton-Jacobi equation. Next, we derive Born's statistical rule using the early understanding of de Broglie that both particles and waves exist. Afterwards, we show that historically people preferred to remove the particles (as well as their trajectories) altogether from de Broglie's ideas but retained Born's rule (the so called Copenhagen interpretation). These derivations of the foundations of quantum mechanics do not follow precisely the history of the subject. Rather we select some early ideas and experiments in a judicious manner to present Schrodinger's equation in a logical and ordered way. We use the electron gun experiments instead of black body radiation and photoelectric effect. Our derivation may bring more light and satisfaction for the undergraduate students about the confusing and rather mysterious subject of quantum mechanics.
Unpublished letters of late 1925 between Einstein and Schrödinger and the doctoral thesis of de Broglie reveal sources of Schrödinger’s inspiration to invent wave mechanics. Schrödinger saw a congenial similarity of de Broglie’s work on the stability of the atom with his own earlier speculation in relativity, which he noted to Einstein. But the last chapter of de Broglie’s thesis, on quantum statistics of gases, which is unfamiliar to many modern readers, provided Schrödinger with the method of treatment of a gas of material particles considered as a system of modes of vibration, of ’’matter waves.’’ This method especially, and other successes of de Broglie’s ’’ingenious thesis,’’ convinced Schrödinger to take seriously the first part, on the conditions of stability of the atom in a wave picture. Thus he sought and found an equation to describe the states of the electron from the matter-wave viewpoint.
The wave-particle duality for light has been well established by various experiments, such as Young’s double slit experiment and the photoelectric effect. This led de Broglie to propose that a particle also has wave characteristics. Schrödinger further established the wave equation for a moving particle. Many times, quantum mechanics textbooks do not show how Schrödinger’s equation was developed in an intuitive manner that is appropriate at the undergraduate level. This article presents a new approach for introducing Schrödinger’s equation. This new approach starts with Maxwell’s equations and then applies the quantized energy of a light wave and special relativity. This more intuitive approach should help undergraduate students understand the origin of Schrödinger’s equation in a more natural way.
Where did we get that [equation] from? Nowhere. It is not possible to derive it from anything you know. It came out of the mind of Schrödinger. Richard Feynman De Broglie's matter waves The early struggles of physicists towards a quantum theory were mostly concerned with attempts to understand the nature of light. The traditional picture of light as a wave motion had been challenged by Planck and Einstein. They had shown that certain experimental results that were impossible to understand in terms of a wave picture could be easily explained if light was thought of as a stream of particles, now called photons. William Bragg, who, with his son, won the 1915 Nobel Prize for studies of crystal structure using X-rays, summarized this dilemma for physics by exclaiming in despair that he was teaching the corpuscular theory of light on Mondays, Wednesdays and Fridays, and the undulatory theory on Tuesdays, Thursdays and Saturdays! Physicists were still wrestling with these apparently contradictory properties of light when, in 1924, Prince Louis de Broglie (pronounced ‘de Broy’) suggested that all matter, even objects that we usually think of as particles – such as electrons – should also display wavelike behaviour! This revolutionary idea was completely unexpected and, what is more, was included by de Broglie in his Ph. D. thesis. Like most people, physicists are generally reluctant to accept any wild new idea, especially if there is not a shred of evidence to support it.