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Physical Review A

Apparent deviations from causality in spontaneous light emission by atomic hydrogen in the mid- and far-field regions

Vincent Debierre, Thomas Durt

Published Feb 29, 2016• 4 citations
Publisher

Abstract

We investigate, in the case of the $2P\text{\ensuremath{-}}1S$ transition in atomic hydrogen, the behavior of the spontaneously emitted electromagnetic field in space-time. We focus on Glauber's wave function for the emitted photon, a quantity which we find is nonzero outside the light cone at all times after the start of the emission. We identify the uncertainty on the position of the decaying electron as a source of departure from causality in the naive sense of the term. We carry out a detailed study of the emitted electric field in the mid- and far-field regions, through analytical and numerical computations as well as asymptotic arguments.

DOI
10.1103/physreva.93.023847

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We investigate, in the case of the 2P\ensuremath-1S2P\text{\ensuremath{-}}1S2P\ensuremath-1S transition in atomic hydrogen, the behavior of the spontaneously emitted electromagnetic field in space-time. We focus on Glauber's wave function for the emitted photon, a quantity which we find is nonzero outside the light cone at all times after the start of the emission. We identify the uncertainty on the position of the decaying electron as a source of departure from causality in the naive sense of the term. We carry out a detailed study of the emitted electric field in the mid- and far-field regions, through analytical and numerical computations as well as asymptotic arguments.
We investigate, in the case of the 2p−1s2\mathrm{p}-1\mathrm{s}2p−1s transition in atomic Hydrogen, the behaviour of the spontaneously emitted electromagnetic field in spacetime. We focus on Glauber's wave function for the emitted photon, a quantity which we find is nonzero outside the lightcone at all times after the start of the emission. We identify the uncertainty on the position of the decaying electron as a source of departure from causality in the naive sense of the term. We carry out a detailed study of the emitted electric field in the mid- and far-field regions, through analytical and numerical computations as well as asymptotic arguments.
The time-dependent electric energy density surrounding a two-level atom fixed at r = 0 is studied, the atom being taken in its excited state at t = 0 and the field being initially in the vacuum state. The atom-field coupling includes both rotating and counter-rotating terms. The energy density of the spontaneously emitted field in the rotating wave approximation is shown to behave non-causally, while in the presence of the complete coupling it is shown to vanish outside a sphere of radius r = ct centred on the atom. The deviations of atomic dynamics from the exponential Wigner-Weisskopf behaviour during spontaneous decay are shown to be deeply influenced by the counter-rotating terms. It is concluded that the virtual photons induced by the counter-rotating terms in the atom-field coupling are essential in order to ensure causality and cannot be neglected in any accurate treatment of spontaneous emission.
Abstract We analyze through the expectation value of the energy density the spatial nonlocality of single photons emitted by the spontaneous decay of a Hydrogen atom. By using a minimal coupling between the quantized electromagnetic field and the atom, we compute the state of the photon under the assumption that only a single-photon is produced. The calculations are thus performed in the subspace of single-photon states which is essentially equivalent to the rotating wave approximation. We obtain a characterization of the spatial decay of the energy density. We compute the asymptotic limit of large distances from the atom at each given time, and find an algebraic behavior of 1 / r 6 . This result confirms that the energy density of single-photon states is nonlocal and the algebraic decay is far from the maximal quasiexponential localization predicted by the theory.
Starting from the postulate that the electromagnetic field appearing in the transverse set of microscopic Maxwell-Lorentz equations governing field-matter interactions, properly normalized, can be looked upon as describing one-photon-emission and -absorption processes in space and time, a first-quantized initiation of photon emission by a single atom is presented. The wave function for the emerging photon is introduced as a six-vector object constructed from the complex analytical signals of the Riemann-Silberstein vectors belonging to opposite photon helicities. When the atom is no longer electrodynamically active, the emitted photon is described in first quantization by the so-called energy wave function well known for photons in free space. From the momentum representation of the emerging photon wave function a condition on the analytical part of the transverse atomic current density is established which ensures that precisely one photon is emitted. A propagator description of the emerged photon dynamics in the coordinate representation is established. The photon propagator is introduced as a two-component spinor, where upper and lower tensor components are constructed, respectively, from positive and negative helicity combinations of the propagators describing the time-space evolution of the transverse electric and magnetic fields. It is shown that the emission region for the photon coincides with the region in space where the transverse atomic current density is nonvanishing. For a photon emitted in an electric dipole transition the emission region essentially is the near-field zone of the atom, and this zone therefore determines the initial (and best) spatial confinement of the photon. The photon emerging from an atom active for a finite time necessarily is of the polychromatic sort and the associated wave packet essentially is confined between spherical shells moving outwards with the vacuum speed of light. To illustrate the main principles of the fundamental theory in a heuristic fashion we apply it to a study of the emission of a one-photon sinusoidal wavetrain from a pointlike atom. It is found that the atomic current density needed to create just one photon is independent of the oscillation period in the train and thus depends only on the number of periods in the wave train. An explicit expression for the one-photon energy is derived, and it is shown that only for extremely short pulse trains pronounced deviations from the textbook result, $E=\ensuremath{\Elzxh}{\ensuremath{\omega}}_{0},$ occur. The radial energy flow in the coupled atom-photon system in the near-field zone of the atom is investigated, and the cycle-averaged outwards energy transport carried by the emerging photon in a given distance from the atom is determined.
This paper presents a quantum-field-theoretic formulation of the hydrogen 2p → 1s Lyman-α transition, replacing the semiclassical Bohr–Maxwell description with the modern framework of quantum electrodynamics. The initial and final bound-electron states are described by the Dirac equation in the proton’s Coulomb field, with the Schrödinger equation recovered as the leading nonrelativistic limit. The electromagnetic radiation field is quantized, and photon emission is generated by the QED interaction Hamiltonian. The transition amplitude is evaluated from the atomic current and quantized electromagnetic field, leading through Fermi’s golden rule to the spontaneous-emission rate and Einstein coefficient A₂₁. Energy and momentum conservation require the emitted photon to carry the atomic transition energy, including the small correction associated with proton recoil. At leading order, the Lyman-α photon has ΔE ≈ 10.2 eV, ν ≈ 2.47 × 10¹⁵ Hz, and λ ≈ 121.6 nm. In the electric-dipole approximation, the field-theoretic calculation reduces to the standard matrix element of the interaction Hamiltonian H_int = −μ·E, thereby connecting QED directly to the transition dipole moment, oscillator strength, Einstein A coefficient, and radiative lifetime. The calculation reproduces the accepted numerical results for hydrogen while identifying their origin in the coupling between the quantized electron field and the quantized electromagnetic field. The paper also explains how classical electrodynamics is recovered from QED. Maxwell’s equations govern the expectation values of the electromagnetic-field operators in the appropriate classical-field limit, particularly for coherent states containing many photons. A single spontaneously emitted Lyman-α photon, however, remains a genuinely quantum excitation rather than a classical electromagnetic wave. Leading corrections beyond the nonrelativistic Coulomb approximation are then considered, including relativistic fine structure, the Lamb shift, and atomic recoil. The resulting treatment provides a rigorous bridge from the historical Bohr model and Schrödinger wave mechanics to Dirac theory and full QED, verifying the Lyman-α energy, frequency, wavelength, transition probability, and radiative decay structure within a unified quantum-field framework.