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Lithuanian Journal of Physics

Jucys graphs of angular momentum theory

Gintaras Merkelis

Published Jan 1, 2004• 2 citations
Publisher

Abstract

A brief review of the results obtained in Vilnius while developing the graphical methods of quantum angular momentum theory is presented. Numerous modifications and extensions of the original method proposed by A. Jucys, J. Levinson, and V. Vanagas are discussed. The application of the graphical method to the study of one-, two-electron as well as the effective operators and their matrix elements in the coordinate and second quantization representation is surveyed.

DOI
10.3952/lithjphys.44202

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A brief review of the results obtained in Vilnius while developing the graphical methods of quantum angular momentum theory is presented. Numerous modifications and extensions of the original method proposed by A. Jucys, J. Levinson, and V. Vanagas are discussed. The application of the graphical method to the study of one-, two-electron as well as the effective operators and their matrix elements in the coordinate and second quantization representation is surveyed.
This book is concerned with the practical aspects of solving angular momentum problems. The novel but fully tested-out method (the Invariant Graph Method) allows one to write down from a single graph the complete final result of the problem. The drawing of the graph involves very few simple, essentially self-evident rules. Still it is a powerful tool to easily solve the most involved physical problems. The method is introduced step-by-step in a sequence of examples, beginning with the simplest matrix elements, and ending with the most general case of a reaction including angular distributions and correlations. The many-body and particle anti-particle systems are fully developed. All aspects: wave functions, vectors, operators, Fock space state vectors and operators, etc., are treated on the same footing. All concepts of angular momentum theory acquire a transparent meaning. Hence the book is valuable not only as a handbook in problem solving, but extremely so as an adjunct in any course on advanced qunatum physics, atomic, molecular, nuclear and particle physics
This book offers a concise introduction to the angular momentum, one of the most fundamental quantities in all of quantum mechanics. Beginning with the quantization of angular momentum, spin angular momentum, and the orbital angular momentum, the author goes on to discuss the Clebsch-Gordan coefficients for a two-component system. After developing the necessary mathematics, specifically spherical tensors and tensor operators, the author then investigates the 3- j , 6- j , and 9- j symbols. Throughout, the author provides practical applications to atomic, molecular, and nuclear physics. These include partial-wave expansions, the emission and absorption of particles, the proton and electron quadrupole moment, matrix element calculation in practice, and the properties of the symmetrical top molecule.
Simple and efficient methods for adding angular momenta and for finding angular momentum eigenstates for systems of equivalent electrons are developed. Seniority quantum numbers and coefficients of fractional parentage are presented in a simple manner which does not require 6- and 9-j symbols or knowledge of group theory. Several different common representations are used in specific examples. The transformation matrices between jj- and LS-coupled states are explicitly introduced as an example of change of representation and are used to find matrix elements of the spin-orbit interaction and to examine the Zeeman effect in the two representations. The material is suitable for a graduate course in quantum mechanics.
It has been the purpose of the monograph Angular Momentum in Quantum Physics (AMQP) to develop comprehensively those aspects of angular momentum theory that are required in carrying out research in modern physics and chemistry. The emphasis there was principally on physical concepts and the symmetry principles that underlie the general applicability of angular momentum theory to a broad area of physical phenomena. Mathematical techniques were introduced within the context of the physical concepts themselves. Physical applications of angular momentum theory are to a large extent applications of specific properties of Wigner or Racah functions (more generally of 3 n-j coefficients) or of the representation functions themselves. Such applications tend to emphasize the “numerical” aspects of these functions and thus obscure the relationships to other areas of mathematics. The purpose of the present monograph is to show by specific examples the many interrelations that exist between concepts originating in angular momentum theory and various areas of mathematics. It turns out that this is a substantial task—the diversity of the interrelations is far greater than might be thought. Even a brief acquaintance with the contents of AMQP will show that the concept that recurs again and again in physical applications is that of an irreducible tensor operator with respect to a group [in our case, SU (2), the quantal rotation group]. Indeed, it is this concept that carries the mathematical apparatus of the physical theory beyond the related but much simpler results of the Lie algebraic theory of the angular momentum itself and the implied representation theory of the group SU (2).
The graphical technique of evaluation in the second quantization representation of matrix elements of operators associated with the interactions in atoms is developed. The diagrams corresponding to operators and many-electron states given in terms of irreducible tensorial product of creation and annihilation operators are considered. The general rules for the construction of the diagrams for operators and matrix elements are presented. The procedures of reduction of the diagrams to obtain the algebraic expression are discussed.
THE QUANTUM THEORY OF ANGULAR MOMENTUM began with Bohr’s enunciation of the rules for the quantization of orbital angular momentum in 1913, and the refinement of these rules by Sommerfeld [ 1 ] and Landé [ 2 ] within the framework of the old quantum theory. A basic result for angular momentum in modern quantum theory, which we call The First Fundamental Result, was given in the third foundational paper in 1926 by Born, Heisenberg, and Jordan [ 3 ], who not only gave the basic commutation relations for the components of the total angular momentum J, but all finite-dimensional Hermitian matrix representations of these components. Dirac [ 4 ] simultaneously deduced these basic commutation relations using his algebraic approach to quantum mechanics, and later gave a marvelously brief derivation of their matrix representations in his book [ 5 ]. Further developments, including the famous Pauli matrices and results relating to angular momentum selection rules for transitions in atomic systems, are given in the papers by Heisenberg and Jordan [ 6 ], Pauli [ 7 ], and Güttinger and Pauli [ 8 ]. These works, and the books by Born and Jordan [ 9 ] and Condon and Shortley [ 10 ], fixed the framework for much of the developments in angular momentum theory, which was hardly distinguishable from the general quantum theory in the context of which it was developed for the purpose of giving a consistent description of the spectra of atoms. Little emphasis was given to the universal and distinctive role of symmetry.