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Chapman & Hall/CRC eBooks

ANGULAR MOMENTUM IN QUANTUM MECHANICS

Vishnu S. Mathur, Surendra Singh

Published Dec 12, 2008• 904 citations
Publisher

Abstract

The invariance of the Hamiltonian of a physical system under spatial rotation, together with the connection between the rotation operator Rˆn(θ) and the angular momentum operator Jˆ ≡ (Jˆx, Jˆy, Jˆz), leads to the principle of conservation of angular momentum [Chapter 6, Sec. 6.3] and to the status of total angular momentum as a constant of motion. This makes angular momentum a very important quantity in quantum mechanics.

DOI
10.1201/b17176-10

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The invariance of the Hamiltonian of a physical system under spatial rotation, together with the connection between the rotation operator Rˆn(θ) and the angular momentum operator Jˆ ≡ (Jˆx, Jˆy, Jˆz), leads to the principle of conservation of angular momentum [Chapter 6, Sec. 6.3] and to the status of total angular momentum as a constant of motion. This makes angular momentum a very important quantity in quantum mechanics.
Angular momentum is a very important and revealing property of many physical systems. In classical mechanics the principle of conservation of angular momentum is a powerful aid to the solution of such problems as the orbits of planets and satellites and the behaviour of gyroscopes and tops. The role of angular momentum in quantum mechanics is probably even more important and this will be the subject of the present chapter and the next. We shall find that the operators representing the components of angular momentum do not commute with each other, although they all commute with the operator representing the total angular momentum. It follows that no pair of these components can be measured compatibly and we shall therefore look for a set of eigenfunctions that are common to the operators representing the total angular momentum and one of its components. We shall find that the angular momentum eigenvalues always form a discrete set and that, in the case of a central field, the operators commute with the Hamiltonian, implying that the total angular momentum and one component can be measured compatibly with the energy in this case, so that their values, once measured, remain constant in time. Consideration of angular momentum will also enable us to make predictions about the behaviour of atoms in magnetic fields, and we shall find that these are in agreement with experiment only if we assume that the electron (in common with many other fundamental particles) has an intrinsic “spin” angular momentum in addition to the “orbital” angular momentum associated with its motion. The interaction between spin and orbital angular momenta leads to detailed features of the atomic spectra which are known as “fine structure.” We shall also use the measurement of angular momentum to illustrate the quantum theory of measurement discussed in the previous chapter.
In this chapter we shall treat two of the most important observables of quantum mechanical systems: angular momentum and spin. We shall argue that angular momentum is the generator of rotations. In quantummechanics, angular momentum is quantized in units of the reduced Planck constant. The quantization of angular momentum is dealt with by finding the angular momentum eigenvalues and eigenstates. We shall then apply the theory of angular momentum to study the hydrogen atom. Spin is an intrinsic angular momentum of subatomic particles and therefore corresponds to an important intrinsic degree of freedom. We shall discuss briefly how spin was discovered and many of its important properties. Finally, we shall also explore here some further subtleties of quantum theory.a When we consider quantum systems in two or three spatial dimensions, we need to take into account also the effect of rotations. In this case, we need to introduce a physical quantity called the angular momentum, that is, themomentum induced by or connected with rotations. In classical physics the angular momentum of a particle about a given origin is defined by [see Fig. 8.1]
This chapter shows that the three operators are Hermitian and (in a rotationally invariant system) commute with the Hamiltonian; therefore they are observable constants of the motion. It finds out what their physical significance is. By knowing from classical mechanics, the constant of the motion arising from rotational invariance is the angular momentum. The angular momentum may split up into two parts: orbital and intrinsic. The orbital part can always be described by the dependence of a wave function, whereas the intrinsic part is by definition contained in the transformation property of the wave function. In the case of a single component (scalar), no intrinsic angular momentum exists. There are—apart from the vector addition and the scalar product—two other ways of combining two vectors: the direct sum and the direct product. Both occur in the theory of angular momentum, in fact whenever symmetry is involved.
The recent two papers have successively proposed the concepts and more precise expressions of strict conservation or statistical conservation of physical quantities, which are different from the expression of a conserved quantity in quantum mechanics. The Hamiltonian operator of the system discussed in this paper are independent of time, so it is commutative with the operators of an angular momentum itself, its component and its square, so that all these quantities are conserved quantities. In an isolated composite system, one of the angular momentum components of the total system are strictly conserved, while the angular momentum components of the subsystems can only be conserved statistically, both of which can be expressed in terms of eigenvalues and eigenfunctions. Generally, angular momentum itself does not have eigenvalues and eigenfunctions, so it cannot be expressed as strict conservation in terms of these concepts. Although there are eigenvalues and eigenfunctions for the square of angular momentum, they cannot express strict conservation either. And they can only be expressed as statistical conservation.
This chapter considers rotational motion as the second class of motion of an object around a fixed point and angular momentum, which is one of the most important topics in quantum mechanics. It discusses the rotational motion and angular momentum in terms of solutions of the Schrödinger equation and see how its properties emerge from the operators for angular momentum and their commutation relations. It also examines the quantum mechanical description of a particle travelling on a circular ring, which applies to the motion of a bead on a circle of wire and any body rotating in a plane. The chapter describes the moment of inertia the property, which determines the characteristics of the rotational motion of a body. It cites a particle of mass m travelling on a circle of radius r in the xy-plane and its potential energy that is constant and taken to be zero.