In the general case, quantum-mechanical quantities are represented by operators in position- or momentum-space representations, but in phase space they are represented by functions. The correspondence between classical mechanics and quantum mechanics is non-unique as a consequence of [
Abstract For present purposes, the first thing to recall about quantum mechanics is that all dynamical quantities, instead of being functions of the location of a system in phase space as in classical mechanics, are now represented by operators in a Hilbert space of quantum states. In particular, the quantum analog of the classical phase space distribution function is the quantum mechanical density matrix. Since this is seldom discussed in introductory texts on either quantum mechanics or statistical mechanics, it may be helpful to summarize some of its basic properties.
It is shown that phase-space distribution functions that characterize a single-particle quantum system obey a certain "generalized non-negativity condition," which reflects the fact that the density operator is a positive operator. A corresponding criterion is obtained for the associated characteristic functions and is found to resemble, to some extent, Bochner's theorem of classical probability theory. Necessary and sufficient conditions on a phase-space representation of quantum mechanics are also derived, which ensure that all the possible distribution functions in that representation are non-negative; but it is also shown that such distribution functions are not joint probabilities for position and momentum. In fact, our results readily provide a new proof of theorems of Wigner, and of Cohen and Margenau, which imply that quantum mechanics cannot be formulated as a stochastic theory in phase space.
The paper interprets the concept “operator in the separable complex Hilbert space” (particalry, “Hermitian operator” as “quantity” is defined in the “classical” quantum mechanics) by that of “quantum information”. As far as wave function is the characteristic function of the probability (density) distribution for all possible values of a certain quantity to be measured, the definition of quantity in quantum mechanics means any unitary change of the probability (density) distribution. It can be represented as a particular case of “unitary” qubits. The converse interpretation of any qubits as referring to a certain physical quantity implies its generalization to non-Hermitian operators, thus neither unitary, nor conserving energy. Their physical sense, speaking loosely, consists in exchanging temporal moments therefore being implemented out of the space-time “screen”. “Dark matter” and “dark energy” can be explained by the same generalization of “quantity” to non-Hermitian operators only secondarily projected on the pseudo-Riemannian space-time.
Abstract The functional integral representation of the density matrix at thermal equilibrium in non-relativistic quantum mechanics (QM) with many degrees of freedom, in the grand canonical formulation is introduced. In QM, Hamiltonians H(p,q) can be also expressed in terms of creation and annihilation operators, a method adapted to the study of perturbed harmonic oscillators. In the holomorphic formalism, quantum operators act by multiplication and differentiation on a vector space of analytic functions. Alternatively, they can also be represented by kernels, functions of complex variables that correspond in the classical limit to a complex parametrization of phase space. The formalism is adapted to the description of many-body boson systems. To this formalism corresponds a path integral representation of the density matrix at thermal equilibrium, where paths belong to complex spaces, instead of the more usual position–momentum phase space. A parallel formalism can be set up to describe systems with many fermion degrees of freedom, with Grassmann variables replacing complex variables. Both formalisms can be generalized to quantum gases of Bose and Fermi particles in the grand canonical formulation. Field integral representations of the corresponding quantum partition functions are derived.