This thesis is concerned with finding technologically useful quantum phenomena that are robust against real world imperfections. We examine three different areas covering techniques for spin measurement, photon preparation and error correction. The first research chapter presents a robust spin-measurement procedure, using an amplification approach: the state of the spin is propagated over a two-dimensional array to a point where it can be measured using standard macroscopic state mea- surement techniques. Even in the presence of decoherence, our two-dimensional scheme allows a linear growth in the total spin polarisation - an important increase over the √t obtainable in one-dimension. The work is an example of how simple propagation rules can lead to predictable macroscopic behaviour and the techniques should be applicable in other state propagation schemes. The next chapter is concerned with strategies for obtaining a robust and reliable single photon source. Using a microscopic model of electron-phonon interactions and a quantum master equation, we examine phonon-induced decoherence and assess its impact on the rate of production, and indistinguishability, of single photons emitted from an optically driven quantum dot system. We find that, above a certain threshold of desired indistinguishability, it is possible to mitigate the deleterious effects of phonons by exploiting a three-level Raman process for photon production. We introduce a master equation technique for quantum jump situations that should have wide application in other situations. The final chapter focusses on toric error correcting codes. Toric codes form part of the class of surface codes that have attracted a lot of attention due to their ability to tolerate a high level of errors, using only local operations. We investigate the power of small scale toric codes and determine the minimum size of code necessary for a first experimental demonstration of toric coding power.
This thesis is concerned with finding technologically useful quantum phenomena that are robust against real world imperfections. We examine three different areas covering techniques for spin measurement, photon preparation and error correction. The first research chapter presents a robust spin-measurement procedure, using an amplification approach: the state of the spin is propagated over a two-dimensional array to a point where it can be measured using standard macroscopic state mea- surement techniques. Even in the presence of decoherence, our two-dimensional scheme allows a linear growth in the total spin polarisation - an important increase over the √t obtainable in one-dimension. The work is an example of how simple propagation rules can lead to predictable macroscopic behaviour and the techniques should be applicable in other state propagation schemes. The next chapter is concerned with strategies for obtaining a robust and reliable single photon source. Using a microscopic model of electron-phonon interactions and a quantum master equation, we examine phonon-induced decoherence and assess its impact on the rate of production, and indistinguishability, of single photons emitted from an optically driven quantum dot system. We find that, above a certain threshold of desired indistinguishability, it is possible to mitigate the deleterious effects of phonons by exploiting a three-level Raman process for photon production. We introduce a master equation technique for quantum jump situations that should have wide application in other situations. The final chapter focusses on toric error correcting codes. Toric codes form part of the class of surface codes that have attracted a lot of attention due to their ability to tolerate a high level of errors, using only local operations. We investigate the power of small scale toric codes and determine the minimum size of code necessary for a first experimental demonstration of toric coding power.
This thesis is concerned with fault-tolerant quantum information processing using quantum error-correcting codes. It contains two major pieces of work. The first is a study of coherent noise in the context of stabilizer error-correcting codes. The second is a proposed scheme for a universal set of fault-tolerant logical gates in a particular code family built out of the 3D toric code. Chapter 1 provides an introduction to quantum computation and fault tolerance. Many basic concepts in error-correcting codes are defined. Special attention is paid to the set of code properties that are most likely to determine how easily a given fault-tolerant scheme might be implemented on a physical device. These include the fault-tolerant noise threshold and the overhead. In Chapters 2 and 3 we study the effectiveness of quantum error correction against coherent noise. Coherent errors (for example, unitary noise) can interfere constructively, so that in some cases the average infidelity of a quantum circuit subjected to coherent errors may increase quadratically with the circuit size; in contrast, when errors are incoherent (for example, depolarizing noise), the average infidelity increases at worst linearly with circuit size. We consider the performance of quantum stabilizer codes against a noise model in which a unitary rotation is applied to each qubit, where the axes and angles of rotation are nearly the same for all qubits. In Chapter 2 we introduce coherent noise and incoherent noise and a number of methods that are useful for the study of coherent noise. We study the repetition code as a basic example, and we also study a correlated noise model. In Chapter 3 we show that for the toric code subject to such independent coherent noise, and for minimal-weight decoding, the logical channel after error correction becomes increasingly incoherent as the length of the code increases, provided the noise strength decays inversely with the code distance. A similar conclusion holds for weakly correlated coherent noise. Our methods can also be used for analyzing the performance of other codes and fault-tolerant protocols against coherent noise. However, our result does not show that the coherence of the logical channel is suppressed in the more physically relevant case where the noise strength is held constant as the code block grows, and we recount the difficulties that prevented us from extending the result to that case. Nevertheless our work supports the idea that fault-tolerant quantum computing schemes will work effectively against coherent noise, providing encouraging news for quantum hardware builders who worry about the damaging effects of control errors and coherent interactions with the environment. Chapter 4 is connected to another aspect of fault tolerance, fault-tolerant logical gates. The toric code is a promising candidate for fault-tolerant quantum computation because of its high threshold and low-weight stabilizers. A universal gate set in the toric code generally requires magic state distillation, which can incur a significant qubit overhead. In this work we construct an error-correcting code in three dimensions based on the toric code that features a fault-tolerant T gate with no magic state distillation required. We further describe a subsystem version of our code which supports a universal set of fault-tolerant gates. This code can be converted into the stabilizer version using gauge-fixing. We also argue that our code can be converted to a (2+1)-D protocol, where a 2D lattice undergoes a measurement-based protocol over time. In this way, a fault-tolerant logical T gate can be realized in a 2D toric code structure.
This thesis presents the development of resource-efficient photon-distillation schemes designed to produce highly indistinguishable photons, a key requirement for large-scale photonic quantum computing. Although photons do not naturally interact, their indistinguishability enables effective interactions through quantum interference, allowing entanglement generation using only linear optical elements and measurements. In practice, however, photons are never perfectly identical. Small differences introduce decoherence, limiting the scalability and reliability of photonic quantum technologies. Addressing indistinguishability errors is therefore essential for fault-tolerant quantum computing. The thesis first reviews the importance of photon indistinguishability and the need to mitigate related errors. It then examines experimental methods for characterizing imperfections and introduces a general model of imperfect photon states. This model captures indistinguishability errors alongside additional experimental noise from photon loss and multiphoton events. A key insight is that loss and multiphoton noise together can act as an effective source of indistinguishability error. To quantify this effect, the work defines an effective indistinguishability metric, enabling practical evaluation of photon-distillation schemes under realistic conditions. The core theoretical contribution is the development of photon-distillation protocols based on multiphoton Fourier interference. Unlike earlier approaches, these schemes can asymptotically suppress indistinguishability errors to arbitrary levels while requiring only linear scaling in photon resources relative to the desired error reduction. The analysis further suggests that photon distillation, when combined with quantum error correction, can significantly reduce the overall resource overhead for fault-tolerant photonic quantum computing. Experimentally, a three-photon Fourier-based distillation protocol was demonstrated on a high-fidelity photonic processor using a resonantly driven quantum-dot single-photon source. After subtracting excess noise contributions, a 2.2-fold reduction in indistinguishability error was achieved; when excess noise was retained, a 1.2-fold net reduction was observed. These results confirm a clear below-threshold improvement in photon quality. Additional analysis suggests that optimized distillation schemes could reduce the photon cost of a logical qubit by up to a factor of four. The thesis concludes by addressing insertion loss and outlining design strategies and future directions for integrating photon-distillation components into scalable quantum architectures.
Quantum information theory is concerned with identifying how quantum mechanical resources, such as entangled quantum states, can be utilized for a number of information processing tasks, including data storage, computation, communication, and cryptography. Efficient quantum algorithms and protocols have been developed for performing some tasks (e.g., factoring large numbers, securely communicating over a public channel, and simulating quantum mechanical systems) that appear to be very difficult with just classical resources. In addition to identifying the separation between classical and quantum computational power, much of the theoretical focus in this field over the last decade has been concerned with finding novel ways of encoding quantum information that are robust against errors, which is an important step toward building practical quantum information processing devices. In this thesis I present some results on the quantum error-correcting properties of oscillator codes (also described as symplectic lattice codes) and toric codes. Any harmonic oscillator system, such as a mode of light, can be encoded with quantum information via symplectic lattice codes that are robust against shifts in the system's continuous quantum variables. I show the existence of lattice codes whose achievable rates match the one-shot coherent information over the Gaussian quantum channel. Also, I construct a family of symplectic self-dual lattices and search for optimal encodings of quantum information distributed between several oscillators. Toric codes provide encodings of quantum information into two-dimensional spin lattices that are robust against local clusters of errors and which require only local quantum operations for error correction. Numerical simulations of this system under realistic error models provide a calculation of the accuracy threshold for quantum memory using toric codes, which can be related to phase transitions in particular condensed matter models. I also present a local classical processing scheme for correcting errors on toric codes, which demonstrates that quantum information can be maintained in two dimensions by purely local quantum and classical resources.
This thesis is divided into five parts, each with an accompanying publication. In Chapter 1, I motivate the broad scientific pursuit that underlies this thesis: the quest to build universal, fault-tolerant technology that operates on the principles of quantum mechanics and quantum information theory. I motivate the use of single photons as the quantum particles of choice for this task, and I describe the open challenges facing the field of researchers embarking on this quest. This motivation pervades each subsequent chapter of this thesis, which focus in turn on overcoming four distinct technological and scientific hurdles related to these open challenges. The first of these open challenges is to demonstrate experimentally a useful single-photon source. This source of single photons ought to release just one photon at a time, in an on-demand fashion, with high-rate, low-latency, and high quantum-state purity and indistinguishability, in a single spatial mode, at the right wavelengths for a given application, and ought to satisfy certain practical constraints on size, weight, power, and sensitivity to environmental noise and perturbation. This is a long list of performance metrics, some of which are orthogonal, some not, and non-trivial tradeoffs often exist between metrics. While in this thesis we do not present a solution to this general open problem, we modestly expand scientific knowledge of one of the fundamental mechanisms behind single-photon generation. In particular, we present a new formalism for describing the quantum properties of spontaneous Stokes scattering in the Raman interaction, and we probe its effects on the quantum state purity of resulting Stokes photons both experimentally and theoretically. This is the focus of Chapter 2. Another open challenge to universal, fault-tolerant photonic quantum processing is the experimental demonstration of a useful photonic quantum memory—a device that is capable of storing and releasing single photons in a quantum-information-conserving manner, and which possesses sufficiently high performance across, again, a large set of non-orthogonal metrics. On this challenge, we have made several substantial contributions. Chapter 3 describes a novel approach to optimizing the efficiency of photonic quantum memories in atomic ensembles possessing a three-level Lambda-type energy level structure, in an experimentally friendly fashion. Chapter 4 discusses the practical side of implementing robust quantum memory in these atomic systems, where we carefully consider the theoretical sensitivity of these systems to experimental noise and perturbation. These two Chapters lead up to the experimental work described in Chapter 5, where we experimentally demonstrate a state-of-the-art and best-in-class photonic quantum memory in neutral barium vapor that possesses simultaneously high efficiency, broad bandwidth, and low noise. Our experimental demonstration features >95% storage efficiency, at roughly 3 orders of magnitude larger bandwidth (higher speed) than the previous state of the art, as well as record-low noise for Lambda-type atomic memories. The noise is so low, and the bandwidth so large, that we are able to perform a novel characterization experiment to extract the temporal amplitude and phase of the photons retrieved from our memory, based on spectral interferometry with a known reference. This is the most demanding possible characterization of one of these memories, and has direct implications for using this type of memory in quantum processing tasks that require temporally indistinguishable photons. In Chapter 6 I do the requisite summing up of the thesis, and discuss ongoing and future work on the memory project. In the various and sundry appendices I include information that will chiefly be useful for my successors in the lab, but may be of passing interest to other readers.
This thesis is concerned with studying the fascinating quantum properties of real-world nanostructures embedded in a noisy condensed matter environment. The interaction with light is used for controlling and manipulating the quantum state of the systems considered here. In some instances, laser pulses also provide a way of actively probing and controlling environmental interactions.
The first two research chapters assess two different ways of performing all-optical spin qubit gates in self-assembled quantum dots. The principal conclusion is that an `adiabatic' control technique holds the promise of achieving a high fidelity when all primary sources of decoherence are taken into account.
In the next chapter, it is shown that an optically driven quantum dot exciton interacting with the phonons of the surrounding lattice acts as a heat pump. Further, a model is developed which predicts the temperature-dependent damping of Rabi oscillations caused by bulk phonons, finding an excellent agreement with experimental data.
A different system is studied in the following chapter: two electron spin qubits with no direct interaction, yet both exchange-coupled to an optically active mediator spin. The results of this study show that these general assumptions are sufficient for generating controlled electron spin entanglement over a wide range of parameters, even in the presence of noise.
Finally, the Radical Pair model of the avian compass is investigated in the light of recent experimental results, leading to the surprising prediction that the electron spin coherence time in this molecular system seems to approach the millisecond timescale.
Nanostructures are promising building blocks for quantum technologies due to their reproducible nature and ability to self-assemble into complex structures. However, the need to control these nanostructures represents a key challenge. Hence, this thesis investigates the manipulation and creation of quantum states in certain nanostructures. The results of this thesis can be applied to quantum information processing and to extremely sensitive magnetic-field measurements.In the first research chapter, we propose and examine methods for entangling two (remote) nuclear spins through their mutual coupling to a transient optically excited electron spin. From our calculations we identify the specific molecular properties that permit high entangling power gates for different protocols.In the next research chapter, we investigate another method to create entanglement; this time between two remote electronic spins. This method uses a very sensitive magnetic-field sensor based on a crystal defect that allows the detection of single magnetic moments. The act of sensing the local field constitutes a two-qubit projective measurement. This entangling operation is remarkably robust to imperfections occurring in an experiment.The third research chapter presents an augmented sensor consisting of a nitrogen-vacancy centre for readout and an `amplifier' spin system that directly senses tiny local magnetic fields. Our calculations show that this hybrid structure has the potential to detect magnetic moments with a sensitivity and spatial resolution far beyond that of a sensor based on only a nitrogen-vacancy centre, and indeed this may be the physical limit for sensors of this class.Finally, the last research chapter investigates measurements of magnetic-field strength using an ensemble of spin-active molecules. Here, we describe a quantum strategy that can beat the common standard strategy. We identify the conditions for which this is possible and find that this crucially depends on the decoherence present in the system.