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Connecting asymmetric time evolution to the dynamical irreversibility of open quantum systems

Peter William Bryant

Published Aug 1, 2012• 0 citations
OpenAlex

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When using a time asymmetric quantum theory, one must identify the time evolution parameter with a duration in time rather than with a time coordinate value. This identification restricts the options for the quantum mechanical environment of open quantum systems. The restriction may be important for interpretational questions concerning irreversibility or entanglement, but there is no measurable difference between a reduced dynamics within a time symmetric theory or within a time asymmetric theory.
Irreversible behavior in open stochastic dynamical systems is quantified by stochastic entropy production, a property that measures the difference in likelihoods of forward and subsequent backward system evolution. But for a closed system, governed by deterministic dynamics, such an approach is not appropriate. Instead, we can consider the difference in likelihoods of forward and "obverse" behavior: the latter being a backward trajectory initiated at the same time as the forward trajectory. Such a comparison allows us to define "dissipation production," an analog of stochastic entropy production. It quantifies the breakage of a property of the evolution termed "obversibility" just as stochastic entropy production quantifies a breakage of reversibility. Both are manifestations of irreversibility. In this study we discuss dissipation production in a quantum system. We consider a simple, deterministic, two-level quantum system characterized by a statistical ensemble of state vectors, and we provide numerical results to illustrate the ideas. We consider cases that both do and do not satisfy an Evans-Searles Fluctuation Theorem for the dissipation production, and hence identify conditions under which the system displays time-asymmetric average behavior: an arrow of time.
We develop a perturbation theory to estimate the finite time corrections around a quasi static trajectory, in which a quantum system is able to equilibrate at each instant with its environment. The results are then applied to non equilibrium thermodynamics, in which context we are able to provide a connection between the irreversible contributions and the microscopic details of the dynamical map generating the evolution. Turning the attention to finite time Carnot engines, we found a universal connection between the spectral density esponent of the hot/cold thermal baths and the efficiency at maximum power, giving also a new interpretation to already known results such as the Curzon-Ahborn and the Schmiedl-Seifert efficiencies.