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Discrete Dynamics in Nature and Society

Irreversibility in quantum mechanics

Robert C. Bishop, Arno Böhm, Manuel Gadella

Published Jan 1, 2004• 4 citations
Publisher

Abstract

Time asymmetry and irreversibility are signal features of our world. They are the reason of our aging and the basis for our belief that effects are preceded by causes. These features have many manifestations called arrows of time. In classical physics, some of these arrows are described by the increase of entropy or probability, and others by time‐asymmetric boundary conditions of time‐symmetric equations (e.g., Maxwell or Einstein). However, there is some controversy over whether probability or boundary conditions are more fundamental. For quantum systems, entropy increase is usually associated with the effects of an environment or measurement apparatus on a quantum system and is described by the von Neumann‐Liouville equation. But since the traditional (von Neumann) axioms of quantum mechanics do not allow time‐asymmetric boundary conditions for the dynamical differential equations (Schrödinger or Heisenberg), there is no quantum analogue of the radiation arrow of time. In this paper, we review consequences of a modification of a fundamental axiom of quantum mechanics. The new quantum theory is time asymmetric and accommodates an irreversible time evolution of isolated quantum systems.

DOI
10.1155/s1026022604401046

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Time asymmetry and irreversibility are signal features of our world. They are the reason of our aging and the basis for our belief that effects are preceded by causes. These features have many manifestations called arrows of time. In classical physics, some of these arrows are described by the increase of entropy or probability, and others by time‐asymmetric boundary conditions of time‐symmetric equations (e.g., Maxwell or Einstein). However, there is some controversy over whether probability or boundary conditions are more fundamental. For quantum systems, entropy increase is usually associated with the effects of an environment or measurement apparatus on a quantum system and is described by the von Neumann‐Liouville equation. But since the traditional (von Neumann) axioms of quantum mechanics do not allow time‐asymmetric boundary conditions for the dynamical differential equations (Schrödinger or Heisenberg), there is no quantum analogue of the radiation arrow of time. In this paper, we review consequences of a modification of a fundamental axiom of quantum mechanics. The new quantum theory is time asymmetric and accommodates an irreversible time evolution of isolated quantum systems.
A slight modification of one axiom of quantum theory changes a reversible theory into a time asymmetric theory. Whereas the standard Hilbert space axiom does not distinguish mathematically between the space of states (in-states of scattering theory) and the space of observables (out-“states ” of scattering theory) the new axiom associates states and observables to two different Hardy subspaces which are dense in the same Hilbert space and analytic in the lower and upper complex energy plane, respectively. As a consequence of this new axiom the dynamical equations (Schrödinger or Heisenberg) integrate to a semigroup evolution. Extending this new Hardy space axiom to a relativistic theory provides a relativistic theory of resonance scattering and decay with Born probablilities that fulfill Einstein causality and the exponential decay law. 1 Introduction—Time Asymmetry Time asymmetry, irreversibility, time reversal non-invariance are different concepts and they are (probably) not (all) related to each other [1], [2], [3]. These concepts are usually called arrows-of-time. Time asymmetry comes from time asymmetric boundary conditions of time symmetric equations; its most prominent consequence is causality. The radiation arrow of time is its example from classical physics. Irreversibility
The discussion on time-reversal in quantum mechanics exists at least since Wigner's ``Uber die Operation der Zeitumkehr in der Quantenmechanik'' paper in 1932. If and how the dynamics of the quantum world is time-reversible has been the subject of many controversies. Some have seen quantum mechanics as fundamentally time-irreversible, see for example von Neumann, and some have seen in that the ultimate cause of time's arrow and second law behavior. In his best-selling book ``The Emperor's New Mind'', Roger Penrose argues similarly and concludes that ``our sought-for quantum gravity must be a time-asymmetric theory'' [p.351]. Not so long ago, we read yet about another project in Physicalia 26: to extend quantum mechanics into new fundamentally irreversible equations, thus proposing a new theory giving ``... une description fondamentale irreversible de tout systeme physique''.
This work investigates the fundamental connection between quantum mechanics and thermodynamics through the concept of the arrow of time. While the second law of thermodynamics identifies the arrow of time with the monotonic increase of entropy in isolated systems, closed quantum systems evolve unitarily and conserve von Neumann entropy, making the origin of irreversibility less apparent. Here we establish a no-go theorem proving that correlations in unknown states of closed quantum systems cannot be universally removed by any physical operation. This result demonstrates that correlation generation is inherently irreversible, providing a microscopic and universal basis for the arrow of time. In thermodynamic settings, this irreversibility ensures that heat flows spontaneously from hotter to colder subsystems, reproducing the Clausius formulation of the second law. More generally, the irreversible growth of correlations explains entropy increase, the approach to equilibrium, and decoherence as observable manifestations of the same principle. Our findings ground a quantum-mechanical foundation for the second law of thermodynamics and demonstrate the universality of the arrow of time.
Within the general formalism of quantum theory irreversibility and the arrow of time and the in the evolution of various physical systems are studied. Irreversible behavior often manifests itself in the guise of “entropy production.” This motivates me to begin this chapter with a brief review of quantum-mechanical entropy, a subject that Elliott Lieb has made outstanding contributions to, followed by an enumeration of examples of irreversible behavior and of an arrow of time analyzed in later sections. Subsequently, a derivation of the laws of thermodynamics from (quantum) statistical mechanics, and, in particular, of the Second Law of thermodynamics, in the forms given to it by Clausius and Carnot, is presented. In a third part, results on diffusive (Brownian) motion of a quantum particle interacting with a quasi-free quantum-mechanical heat bath are reviewed. This is followed by an outline of a theory of friction by emission of Cherenkov radiation of sound waves in a system consisting of a particle moving through a Bose–Einstein condensate and interacting with it. In what may be the most important section of this chapter, the fundamental arrow of time inherent in Quantum Mechanics is discussed.
With a choice of boundary conditions for solutions of the Schrödinger equation, state vectors and density operators even for closed systems evolve asymmetrically in time. For open systems, standard quantum mechanics consequently predicts irreversibility and signatures of the extrinsic arrow of time. The result is a new framework for the treatment of decoherence, not based on a reduced dynamics or a master equation. As an application, using a general model we quantitatively match previously puzzling experimental results and can conclude that they are the measurable consequence of the indistinguishability of separate, uncontrolled interactions between systems and their environment.
The problem of time’s arrow is (roughly) to understand why macroscopic physical processes typically evolve in a specific direction (the one we call “the future”) even though the underlying laws of physics describing the individual microscopic systems are time-reversal invariant. The standard answer to this problem is given by Boltzmann’s explanation of the II law of thermodynamics: a classical system starting in a non-equilibrium state spontaneously (i.e. with a high level of probability) tends towards equilibrium, thus implementing an irreversible process. However, this explanation has two drawbacks: 1. it needs a further assumption on the entropy of the initial state of the universe (past hypothesis); 2. microscopic systems (e.g. molecules in a box) should be represented as quantum states and not classical states. In this talk, I want to propose a different hypothesis to explain the origin of time’s arrow, based on quantum mechanics, specifically on decoherence theory. Differently from isolated systems, open quantum systems described by decoherence theory showirreversible behavior, as they evolve towards decoherence and von Neumann entropy increase. Is this behavior a sign of genuine irreversibility? And, if so, can this be linked to thermodynamic irreversibility?