With a choice of boundary conditions for solutions of the Schrödinger equation, state vectors and density operators even for closed systems evolve asymmetrically in time. For open systems, standard quantum mechanics consequently predicts irreversibility and signatures of the extrinsic arrow of time. The result is a new framework for the treatment of decoherence, not based on a reduced dynamics or a master equation. As an application, using a general model we quantitatively match previously puzzling experimental results and can conclude that they are the measurable consequence of the indistinguishability of separate, uncontrolled interactions between systems and their environment.
With a choice of boundary conditions for solutions of the Schrödinger equation, state vectors and density operators even for closed systems evolve asymmetrically in time. For open systems, standard quantum mechanics consequently predicts irreversibility and signatures of the extrinsic arrow of time. The result is a new framework for the treatment of decoherence, not based on a reduced dynamics or a master equation. As an application, using a general model we quantitatively match previously puzzling experimental results and can conclude that they are the measurable consequence of the indistinguishability of separate, uncontrolled interactions between systems and their environment.
The extrinsic quantum mechanical arrow of time is understood to be a consequence of the interaction between quantum systems and their environment. A choice of boundary conditions for the Schrödinger equation results in a different time asymmetry intrinsic to quantum mechanical dynamics and independent of environmental interactions. Correct application of the intrinsically asymmetric dynamics, however, leads unavoidably to predictions of the experimental signatures of the extrinsic arrow of time. We are led to a new, model-independent mechanism for quantum decoherence. We need not invoke a master equation or a phase-destroying, non-Hermitian Hamiltonian operator. As an application, we calculate predictive probabilities for the decoherence measured in Rabi oscillations experiments. We can also show that a previously puzzling experimental result, unexplained within the formalism of the quantum master equation, is in fact expected and is the measurable consequence of the indistinguishability of separate, uncontrolled interactions between systems and their environment.
Time asymmetry and irreversibility are signal features of our world. They are the reason of our aging and the basis for our belief that effects are preceded by causes. These features have many manifestations called arrows of time. In classical physics, some of these arrows are described by the increase of entropy or probability, and others by time‐asymmetric boundary conditions of time‐symmetric equations (e.g., Maxwell or Einstein). However, there is some controversy over whether probability or boundary conditions are more fundamental. For quantum systems, entropy increase is usually associated with the effects of an environment or measurement apparatus on a quantum system and is described by the von Neumann‐Liouville equation. But since the traditional (von Neumann) axioms of quantum mechanics do not allow time‐asymmetric boundary conditions for the dynamical differential equations (Schrödinger or Heisenberg), there is no quantum analogue of the radiation arrow of time. In this paper, we review consequences of a modification of a fundamental axiom of quantum mechanics. The new quantum theory is time asymmetric and accommodates an irreversible time evolution of isolated quantum systems.
Quantum decoherence is widely regarded as the principal dynamical mechanism through which classical behaviour emerges from quantum dynamics. This review presents a technical account of decoherence as an open-system phenomenon, emphasizing its mathematical framework, microscopic models, experimental evidence, and foundational implications. Starting from system-environment interactions and reduced density operators, we introduce completely positive trace-preserving maps and Lindblad master equations. We then discuss pure dephasing, pointer-state selection, quantum Brownian motion, spin-boson dynamics, and collisional decoherence. Experimental evidence from atom and molecular interferometry, superconducting qubits, and mesoscopic platforms is examined. Finally, the review assesses the role of decoherence in the quantum measurement problem. Decoherence explains preferred-basis selection and practical suppression of interference, but it does not independently account for the occurrence of a unique measurement outcome.
Suppose a single qubit is repeatedly prepared and evolved under imperfectly-controlled conditions. A drunk model represents uncontrolled interactions on each experimental trial as random or stochastic terms in the qubits Hamiltonian operator. Time evolution of states is generated by a stochastic differential equation whose sample paths evolve according to the Schrödinger equation. For models with Gaussian white noise which is independent of the qubits state, the expectation value of the solution obeys a master equation which is identical to the high-temperature limit of the Bloch equation. Drunk models predict that experimental data can appear consistent with decoherence even if qubit states evolve by unitary transformations. Examples are shown in which reversible evolution appears to cause irreversible information loss. This paradox is resolved by distinguishing between the true state of a system and the estimated state inferred from an experimental dataset.
A persistent focus on the concept of emergence as a core element of the scientific method allows a clean separation, insofar as this is possible, of the physical and philosophical aspects of the problem of outcomes in quantum mechanics. The philosophical part of the problem is to explain why a closed system has definite experimental outcomes. The physical part is to show mathematically that there exists a limit in which the contradiction between unitary Schroedinger dynamics and a reduction process leading to distinct outcomes becomes negligible according to an explicitly stated criterion, and to make this criterion as objective as possible. The physical problem is solved here by redefining the notion of a quantum state and finding a suitable measure for the change of state upon reduction. The appropriate definition of the quantum state is not as a ray or density operator in Hilbert space, but rather as an equivalence class consisting of all density operators in a given subspace, the members of which all describe the same experimental outcome. For systems containing only subsystems that are integrated with their environments, these equivalence classes can be represented mathematically by projection operators, and the resulting formalism is closely related to that used by von Neumann to study the increase of entropy predicted by the second law of thermodynamics. However, nearly isolated subsystems are reduced only indirectly, as a consequence of their interaction with integrated subsystems. The reduced states of isolated subsystems are the same conditional states used in the definition of quantum discord. The key concepts of decoherence theory can all be adapted to fit this definition of a quantum state, resulting in a unified theory capable of resolving, in principle, all aspects of the quantum measurement problem. The theory thus obtained is weakly objective but not strongly objective.
The aim of this paper is to review a new perspective about decoherence, according to which formalisms originally devised to deal just with closed or open systems can be subsumed under a closed-system approach that generalizes the traditional account of the phenomenon. This new viewpoint dissolves certain conceptual difficulties of the orthodox open-system approach but, at the same time, shows that the openness of the quantum system is not the essential ingredient for decoherence, as commonly claimed. Moreover, when the behavior of a decoherent system is described from a closed-system perspective, the account of decoherence turns out to be more general than that supplied by the open-system approach, and the quantum-to-classical transition defines unequivocally the realm of classicality by identifying the observables with classical-like behavior.