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Journal de physique

Relaxation of the sodium atom in the 4D level by collisions with noble gases. I. Experimental aspects

F. Biraben, K. Béroff, G. Grynberg, E. Giacobino

Published Jan 1, 1979• 16 citations
Publisher

Abstract

The sodium atom is excited selectively in the 4D3/2 or 4D 5/2 level using Doppler-free two-photon absorption. We analyse the fluorescence in intensity and polarization in presence of noble gas atoms. We measure the cross-sections corresponding to the transfer of population between 4D3/2 and 4D5/2 and between 4D and 4F, the relaxation of alignment in both fine sublevels and the transfer of alignment. In particular, we have observed a transfer of alignment in the case of helium and neon perturbers.

DOI
10.1051/jphys:01979004006051900

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Coherence transfer accompanying 32P1/2 → 32P3/2 excitation transfer in sodium, induced in collisions with noble gas atoms, has been investigated using methods of sensitized fluorescence. Oriented 32P1/2 sodium atoms were produced by irradiating a mixture of sodium vapor and a noble gas with D1σ+ resonance radiation, and their subsequent collisions with the buffer gas atoms resulted in the simultaneous transfer of coherence and excitation from the 2P1/2 state to the 2P3/2 state. Measurements of the ratio of circular polarizations of the D2 sensitized fluorescence and D1 resonance fluorescence resulted in the following cross sections for coherence transfer. Na–He : 7.1 ± 0.7 Å2; Na–Ne : 6.2 ± 0.6 Å2; Na–Ar : 12.0 ± 1.2 Å2; Na–Kr : 6.8 ± 0.7 Å2; Na–Xe : 6.9 ± 0.7 Å2.

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Relaxation of the sodium atom in the 4D level by collisions with noble gases. II. Theoretical aspects

G. Grynberg, E. Giacobino, F. Biraben +1 more

In previous papers [1-3] we have reported experimental measurements of the relaxation rates of the k-multipole moments in the 4D level of sodium and the 3S-4D optical coherence. In the present paper we compare the experimental values with those obtained theoretically for different types of potentials. We show that the Van der Waals C6R -6 interaction is not sufficiently anisotropic to describe the relaxation of the k multipole moments. For Ar, Kr and Xe, much better results are obtained by taking into account the next term C8R-8 in the expansion of the long-range interaction. The potentials of Pascale and Vandeplanque [4] give very good results for helium. The results are also satisfactory for Ar, Kr and Xe, but the agreement could still be improved.

Journal de physique•Jan 1, 1979•6 citations
The sodium atom is excited selectively in the 4D3/2 or 4D 5/2 level using Doppler-free two-photon absorption. We analyse the fluorescence in intensity and polarization in presence of noble gas atoms. We measure the cross-sections corresponding to the transfer of population between 4D3/2 and 4D5/2 and between 4D and 4F, the relaxation of alignment in both fine sublevels and the transfer of alignment. In particular, we have observed a transfer of alignment in the case of helium and neon perturbers.
Abstract. The cross sections for the Na.4D/! Na.4F / excitation energy transfer induced by collisions with He, Ar and Na ground-state atoms have been measured. The sodium atoms in the 4D state have been produced by two-photon excitation using cw laser radiation at 578.89 nm. Within a model which takes into account collisional population and depopulation of the 4F level as well as radiative relaxation (direct or cascade) of the 3D, 4P, 4D and 4F states ending in the 3P level, the rate for the Na.4D / ! Na.4F / collisional transfer turns out to be related to the ratio of the steady-state populations created in 3D and 4D states. They have been determined by measuring the fluorescence intensities of the 3D! 3P and 4D! 3P transitions. The measurements yield the following cross section values for those
The cross sections for the excitation energy transfer induced by collisions with He, Ar and Na ground-state atoms have been measured. The sodium atoms in the 4D state have been produced by two-photon excitation using cw laser radiation at 578.89 nm. Within a model which takes into account collisional population and depopulation of the 4F level as well as radiative relaxation (direct or cascade) of the 3D, 4P, 4D and 4F states ending in the 3P level, the rate for the collisional transfer turns out to be related to the ratio of the steady-state populations created in 3D and 4D states. They have been determined by measuring the fluorescence intensities of the and transitions. The measurements yield the following cross section values for those processes investigated: , and , at .
We measured the cross section for the collision transfer process Na(4D)+Na (3S)Na(4F)+Na(3S). The 4D state was excited by two photon absorption using a tunable dye laser. Since the direct 4F→3D fluorescence can not be detected with our apparatus, we monitored instead the cascade 3D→3P and 4D→3P fluorescence. Relative intensity of the fluorescence, combined with the measurement of sodium density, yielded cross section σ_(4D)→(4F)=1.3×10~(-14)±28％(cm~2). Our result is compared to other experiments.
Coherence transfer accompanying 32P1/2 → 32P3/2 excitation transfer in sodium, induced in collisions with noble gas atoms, has been investigated using methods of sensitized fluorescence. Oriented 32P1/2 sodium atoms were produced by irradiating a mixture of sodium vapor and a noble gas with D1σ+ resonance radiation, and their subsequent collisions with the buffer gas atoms resulted in the simultaneous transfer of coherence and excitation from the 2P1/2 state to the 2P3/2 state. Measurements of the ratio of circular polarizations of the D2 sensitized fluorescence and D1 resonance fluorescence resulted in the following cross sections for coherence transfer. Na–He : 7.1 ± 0.7 Å2; Na–Ne : 6.2 ± 0.6 Å2; Na–Ar : 12.0 ± 1.2 Å2; Na–Kr : 6.8 ± 0.7 Å2; Na–Xe : 6.9 ± 0.7 Å2.
In previous papers [1-3] we have reported experimental measurements of the relaxation rates of the k-multipole moments in the 4D level of sodium and the 3S-4D optical coherence. In the present paper we compare the experimental values with those obtained theoretically for different types of potentials. We show that the Van der Waals C6R -6 interaction is not sufficiently anisotropic to describe the relaxation of the k multipole moments. For Ar, Kr and Xe, much better results are obtained by taking into account the next term C8R-8 in the expansion of the long-range interaction. The potentials of Pascale and Vandeplanque [4] give very good results for helium. The results are also satisfactory for Ar, Kr and Xe, but the agreement could still be improved.