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Photoassociation of cold metastable helium atoms

G.R. Woestenenk

Published Jun 18, 2001• 1 citation
OpenAlex

Abstract

During the last decades the study of cold atoms has grown in a great measure. Research in this field has been made possible due to the development of laser cooling and trapping techniques. We use laser cooling to cool helium atoms down to a temperature of 1 mK and we are able to trap 106 atoms in our magneto-optical trap. The helium atoms are in a metastable state, the He 23S1 state, which has a lifetime of more than 2 hours. With cold atoms phenomena can be studied that are not accessible using thermal atoms, such as high resolution spectroscopy. Furthermore cold atoms are the first step towards Bose-Einstein condensation. Cold alkali-metal atoms have been extensively studied, using photoassociation spectroscopy. In this thesis the first photoassociation results for rare gas atoms, namely metastable helium atoms will be discussed. Various experiments are described and an analysis of the results is given.

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•Jan 1, 2011•0 citations
During the last decades the study of cold atoms has grown in a great measure. Research in this field has been made possible due to the development of laser cooling and trapping techniques. We use laser cooling to cool helium atoms down to a temperature of 1 mK and we are able to trap 106 atoms in our magneto-optical trap. The helium atoms are in a metastable state, the He 23S1 state, which has a lifetime of more than 2 hours. With cold atoms phenomena can be studied that are not accessible using thermal atoms, such as high resolution spectroscopy. Furthermore cold atoms are the first step towards Bose-Einstein condensation. Cold alkali-metal atoms have been extensively studied, using photoassociation spectroscopy. In this thesis the first photoassociation results for rare gas atoms, namely metastable helium atoms will be discussed. Various experiments are described and an analysis of the results is given.
In this thesis, the study of cold gases of neon atoms in different metastable states is described. It contains measurements of the collisional parameters for both the 3s[3/2]2 and the 3s'[1/2]0 metastable state and the dependence of the inelastic loss on external fields. Furthermore, the investigation of frequency dependent laser-induced collisions, and the possibility to excite photoassociation resonances is presented. Based on previous measurements we have selected 22Ne for evaporative cooling. Although, we can experimentally achieve an increase in phase-space density with evaporative cooling, the relatively high inelastic collision parameters prevent the realization of a Bose-Einstein condensate in neon. For the measurements described here, neon atoms have been confined in a magneto-optical trap, in a magnetostatic trap, or in an optical dipole trap, respectively. By laser cooling inside the magnetic trap, atomic samples with more than 95 percent occupation of the magnetic substate m=+2 could be prepared. They have a typical temperature of 0.5 mK, central densities up to 1e11 cm^-3, and a central phase-space density of up to 2.2e-7. After loading the optical dipole trap from the magnetic trap, 2.5e6 atoms with typical temperatures of 0.1 mK, and central densities up to 5e10 cm^-3 were trapped. By evaporative cooling of the atoms in the magnetic trap we could increase the phase-space density by a factor of 200 to 5e-5. Also simulations of optimized evaporation for our experimental parameters show clearly that we are limited to a phase-space density on the order of 1e-5. From these simulations it became clear that a 5-fold increase in the good-to-bad ratio for evaporative cooling suffices to reach the quantum degenerate regime. Investigating the frequency dependence of laser-induced collisions did not reveal an experimental signature for the excitation of photoassociation resonances. For the 3D3 line a frequency dependence of laser enhanced Penning ionization was observed, which is interesting in itself. The absence of the collisional enhancement effect by laser light for the transition to the 3D2 line is intriguing and for an explanation calculations are required. Measurement of the two-body loss coefficient as function of the magnetic field showed a field dependence of the inelastic loss. These losses increase towards both small and large offset fields. In the magnetic trap, we are limited to offset fields < 50 G. In this range of fields, the two-body losses are too large to achieve a Bose-Einstein condensate of magnetically trapped metastable neon. The implementation of an optical dipole trap allowed us to trap the 3P0 metastable state. From the trap loss measurements we determined the two-body loss coefficient of the 3P0 metastable state for both bosonic isotopes 20Ne and 22Ne. For 20Ne we obtained s=6(+5,-4)e-10 cm^3/s and for 22Ne s=11(+7,-6)e-10 cm^3/s. These large two-body losses make it extremely unlikely to reach degeneracy with this metastable state. Nevertheless it is important that the 3P0 metastable state can be trapped to investigate other interesting physical effects. For example, it is essential to apply the STIRAP technique for trapped atoms and to realize the proposed coherent control of collisions. There is also a large interest in a precise determination of the lifetime of this metastable state, which is of importance for the verification of QED. We can also trap neon atoms in their energetically lowest magnetic substate 3P2(m=-2) with the perspective of reducing inelastic collisions in the energetically lowest state.
This thesis presents experimental and theoretical work performed at the Laser Centre of the Vrije Universiteit in Amsterdam to study laser-cooled metastable triplet helium atoms. Samples containing about 3x10^8 helium atoms-either fermionic helium-3 atoms, bosonic helium-4 atoms or mixtures thereof-are cooled to a temperature around 1 mK and form the starting point of the presented studies. The studies include an investigation of cold ionizing collisions in the absence of resonant light, an investigation of magneto-optical trapping with ultraviolet light, a feasibility study of an atomic fountain clock based on metastable helium-3 atoms and the first demonstration of magneto-optical trapping of an isotopic mixture of metastable helium atoms.
Photoassociation is the process in which two colliding atoms absorb a photon to form an excited molecule. The development of laser-cooling techniques for producing gases at ultracold (<1mK)(<1\phantom{\rule{0.3em}{0ex}}\mathrm{mK})(<1mK) temperatures allows photoassociation spectroscopy to be performed with very high spectral resolution. Of particular interest is the investigation of molecular states whose properties can be related, with high precision, to the properties of their constituent atoms with the ``complications'' of chemical binding accounted for by a few parameters. These include bound long-range or purely long-range vibrational states in which two atoms spend most or all of their time at large internuclear separations. Low-energy atomic scattering states also share this characteristic. Photoassociation techniques have made important contributions to the study of all of these. This review describes what is special about photoassociation spectroscopy at ultracold temperatures, how it is performed, and a sampling of results including the determination of scattering lengths, their control via optical Feshbach resonances, precision determinations of atomic lifetimes from molecular spectra, limits on photoassociation rates in a Bose-Einstein condensate, and briefly, production of cold molecules. Discussions are illustrated with examples on alkali-metal atoms as well as other species. Progress in the field is already past the point where this review can be exhaustive, but an introduction is provided on the capabilities of photoassociation spectroscopy and the techniques presently in use.
This article first provides guide lines for the understanding of laser cooling and Bose Einstein Condensation, with a general bibliography of the domain. Some details are given about the case of an ultracold gas of helium atoms in the 23S1 metastable state. Obtention of BEC will be recalled, with discussion of the inhibition of Penning ionization collisions. Recent studies at ENS with photoassociation methods will be summarized, including the formation of giant dimers providing another example of ionization inhibition.
Trapped gases of ultracold metastable helium atoms are a unique experimental sys- tem. The trapped cloud’s low temperatures, the ability to selectively trap and ma- nipulate individual atomic states and the isolation provided in a vacuum chamber are all conducive to the measurement of precision atomic parameters, such as atomic transition rates. Due to it’s atomic structure helium - the simplest multi-electron atom - is a favourite test-bed for precision QED theoretical calculations compared to experimentally determined parameters. This thesis reports on a number of tran- sition rates measured for the first time with high accuracy, including the first excited metastable state lifetime, found to be 7870(510)s, the longest of any neutral atomic species yet measured. Transition rates from the 23P level to the ground state were also measured for the first time and found to be in excellent agreement with theory. Further cooling of helium produces a Bose-Einstein condensate (BEC), where all atoms are in an identical quantum state, the analogue of an optical laser. One par- ticularly interesting property a BEC posesses is long-range coherence to all orders, meaning all component particles are described by a single wavefunction. While first order coherence is measured in an interference experiment like Young’s double slit, higher order coherence is the ability for correlations to exist between groups of two, three or more particles, quantified by the measurement of correlation functions. Prior to the work in this thesis correlation functions for atoms had only been measured for second order. Here we develop a new technique which we use to show that a BEC is coherent to second and third order to 0.1% accuracy, compared to a thermal cloud which we show is incoherent. At small inter-particle spacings, there is an enhanced probability of measuring double and triple events in the thermal cloud (termed bunching). A drawback of all previous atomic correlation measurements is that the small de-Broglie wavelengths compared to the detector resolution leads to a significant reduction in the measured bunching amplitudes compared to theory. By altering our trapping configuration and temperature we are able to measure a two-particle bunching amplitude which is 88% of the theoretical maximum. This system also allowed the measurement of correlations up to 5th order in thermal gases. The near ideal bunching allowed us to demonstrate perturbations to the correlation functions due to the 1D nature of the system. These advances should lead to correlation measurements being used as a probe to characterise more exotic system properties such as low dimensionality, engineered quantum states and paticle pairing. Finally, a waveguide was created using a dipole laser beam and used to guide atoms in analogy to an optical laser in a fibre. Guided ‘atom lasers’ are likely to be important components for practical devices such as precision sensors. We demonstrate that a guided atom laser has a gaussian profile matching the lowest transverse mode of the waveguide and is first and second order coherent. In contrast guided thermal atoms show matter-wave speckle and are incoherent.