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Journal of Mathematical Physics

New Formulation of Stochastic Theory and Quantum Mechanics

L. de la Peña-Auerbach

Published Sep 1, 1969• 99 citations
Publisher

Abstract

The theory of stochastic motion is formulated from a new point of view. It is shown that the fundamental equations of the theory reduce to Schrödinger's equation for specific values of certain parameters. A generalized Fokker-Planck-Kolmogorov equation is obtained; with other values of the parameters, certain approximations reduce this to the Smoluchowski equation for Brownian movement. In particular, the potential function in the Schrödinger equation differs in the two cases. The usual uncertainty relations appear in a natural way in the theory, but in a broader context. A single theory thus covers both similarities and differences between quantum-mechanical and Brownian motion. Furthermore, possibilities for broadening nonrelativistic quantum mechanics are brought out and, as an example, the possible corrections due to non-Markoffian terms are briefly studied.

DOI
10.1063/1.1665009

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The theory of stochastic motion is formulated from a new point of view. It is shown that the fundamental equations of the theory reduce to Schrödinger's equation for specific values of certain parameters. A generalized Fokker-Planck-Kolmogorov equation is obtained; with other values of the parameters, certain approximations reduce this to the Smoluchowski equation for Brownian movement. In particular, the potential function in the Schrödinger equation differs in the two cases. The usual uncertainty relations appear in a natural way in the theory, but in a broader context. A single theory thus covers both similarities and differences between quantum-mechanical and Brownian motion. Furthermore, possibilities for broadening nonrelativistic quantum mechanics are brought out and, as an example, the possible corrections due to non-Markoffian terms are briefly studied.
We first point out that nonrelativistic quantum mechanics formulated at imaginary time s = it can formally be recognized as the Fokker-Planck description of a classical Brownian motion, which occurs (in general) in a medium where particles are absorbed and emitted. We next offer a new formulation of quantum dynamics, which is basically the Langevin treatment of that Brownian motion. More explicitly, we derive a noise average representation of the transition probability W ( X", s"|X', s' ) in terms of the solutions to a Langevin equation with a Gaussian white noise. Upon analytic continuation back to real time W ( X", s"|X', s' ) becomes the propagator of the original Schrödinger equation, namely we have ⟨ X", t"|X', t' ⟩ = W ( X", it"|X', it' ). The main advantage of this approach is to permit a systematic application to quantum-dynamical problems of the mathematical techniques developed in the theory of classical stochastic processes, even when vector potentials and/or time-dependent potentials are present.
It is shown that the motion of a Brownian particle in the Smoluchowski approximation may be described by a Schrödinger-like equation defining a complex probability amplitude whose norm is the same as the stochastic probability density. Furthermore, the quantum dynamical operators have a physical meaning which arises in a natural way, from the stochastic nature of the process. These operators satisfy the usual commutation relations and thus the uncertainty principle. Here the constant ℏ is replaced by a parameter depending on the characteristics of the system. In particular, the potential-energy operator for a Brownian particle subject to no external forces can be interpreted as a Rayleigh dissipative function.
Introduction. There exists a very comprehensive theory concerning the time development of probabilistic systems. This is the Theory of Stochastic processes (1). Quantum mechanics as described by the Schrödinger equation rests very heavily on probabilistic interpretation, and yet, after forty years of remarkably rapid advances and successes, it is not clear how it is related to stochastic theory. The formal similarity of certain aspects of, and equations used in these two theories are well known. The diffusion equation corresponds to the Schrödinger equation, a correspondence only marred by a square root of minus unity appearing with the time derivative in the latter equation. The Kolmogoroff–Chapman relation for probabilities in Brownian motion has an analogue (2) in quantum mechanics, not for probabilities though, but for the complex probability amplitudes. The uncertainty relation also has a stochastic analogue (3). Some of these analogous characteristics are actually symptomatic of the gulf which separates these two theories. There are solutions to the diffusion equation which have a very clear physical probabilistic meaning. This is not the case with the corresponding and formally similar solutions to the Schrödinger equation and is partly due to the √ − 1 mentioned earlier. The probabilistic interpretation of the solutions to the diffusion equation is direct and immediate. On the other hand, the probabilistic interpretation of the solutions, ψ of the Schrödinger equation involve the introduction of the probability density, p = ψ*ψ. One great difference between these two theories lies in their each having distinct principles of linear superposition. In Stochastic Theory probabilities are superposed and in quantum mechanics amplitudes or wave functions are superposed.
It is shown that a stochastic process can be viewed as a set of states (normalized positive linear functionals) over an Abelian C*-algebra. Alternatively, the stochastic process can be associated with a set of representations of the algebra as a subalgebra of the (noncommutative) C*-algebra of bounded operators in a Hilbert space. Then, an operator equation can be associated with every stochastic equation in some general conditions. The formalism is applied to Brownian motion. Then, we study the nonrelativistic motion of a single particle in stochastic electrodynamics, a theory which has been proposed as a possible alternative to quantum mechanics. The equations of motion, which are derived, coincide with the basic ones of quantum mechanics. The differences between this theory and quantum mechanics are summarized.
It is shown that to Schrödinger's equation, one may associate a Markoff process in the Smoluchowski approximation with an external force acting on the system which is a measure of its interaction with the vacuum. This interaction is, in this scheme, responsible for the stochastic character of the motion. The physical interpretation of the usual momentum and energy operators emerges in a natural way from the theory. Thus, we are immediately led to Heisenberg's uncertainty relations. However, this interpretation of quantum mechanics is valid only within the limits of validity of Smoluchowski's equation. As a simple example, we treat the one-dimensional harmonic oscillator.
In the frames of classical mechanics the generalized Langevin equation is derived for an arbitrary mechanical subsystem coupled to the harmonic bath of a solid. A time-acting temperature operator is introduced for the quantum Klein-Kramers and Smoluchowski equations, accounting for the effect of the quantum thermal bath oscillators. The model of Brownian emitters is theoretically studied and the relevant evolutionary equations for the probability density are derived. The Schrodinger equation is explained via collisions of the target point particles with the quantum force carriers, transmitting the fundamental interactions between the point particles. Thus, electrons and other point particles are no waves and the wavy chapter of quantum mechanics originated for the force carriers. A stochastic Lorentz-Langevin equation is proposed to describe the underlaying Brownian-like motion of the point particles in quantum mechanics. Considering the Brownian dynamics in the frames of the Bohmian mechanics, the density functional Bohm-Langevin equation is proposed, and the relevant Smoluchowski-Bohm equation is derived. A nonlinear master equation is proposed by proper quantization of the classical Klein-Kramers equation. Its equilibrium solution in the exact canonical Gibbs density operator, while the well-known Caldeira-Leggett equation is simply a linearization at high temperature. In the case of a free quantum Brownian particles, a new law for the spreading of the wave packet it discovered, which represents the quantum generalization of the classical Einstein law of Brownian motion. A new projector operator is proposed for the collapse of the wave function of a quantum particle moving in a classical environment. Its application results in dissipative Schrodinger equations, as well as in a new form of dissipative Liouville equation in classical mechanics.