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Europhysics Letters (EPL)

Langevin Formulation of Quantum Dynamics

M. Roncadelli

Published Oct 14, 1991• 9 citations
Publisher

Abstract

We first point out that nonrelativistic quantum mechanics formulated at imaginary time s = it can formally be recognized as the Fokker-Planck description of a classical Brownian motion, which occurs (in general) in a medium where particles are absorbed and emitted. We next offer a new formulation of quantum dynamics, which is basically the Langevin treatment of that Brownian motion. More explicitly, we derive a noise average representation of the transition probability W ( X", s"|X', s' ) in terms of the solutions to a Langevin equation with a Gaussian white noise. Upon analytic continuation back to real time W ( X", s"|X', s' ) becomes the propagator of the original Schrödinger equation, namely we have ⟨ X", t"|X', t' ⟩ = W ( X", it"|X', it' ). The main advantage of this approach is to permit a systematic application to quantum-dynamical problems of the mathematical techniques developed in the theory of classical stochastic processes, even when vector potentials and/or time-dependent potentials are present.

DOI
10.1209/0295-5075/16/7/001

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We first point out that nonrelativistic quantum mechanics formulated at imaginary time s = it can formally be recognized as the Fokker-Planck description of a classical Brownian motion, which occurs (in general) in a medium where particles are absorbed and emitted. We next offer a new formulation of quantum dynamics, which is basically the Langevin treatment of that Brownian motion. More explicitly, we derive a noise average representation of the transition probability W ( X", s"|X', s' ) in terms of the solutions to a Langevin equation with a Gaussian white noise. Upon analytic continuation back to real time W ( X", s"|X', s' ) becomes the propagator of the original Schrödinger equation, namely we have ⟨ X", t"|X', t' ⟩ = W ( X", it"|X', it' ). The main advantage of this approach is to permit a systematic application to quantum-dynamical problems of the mathematical techniques developed in the theory of classical stochastic processes, even when vector potentials and/or time-dependent potentials are present.
A simple scheme of unified description of different physical phenomena by using the Langevin type equations is reviewed. Within this approach much attention is being paid to the study of Brownian and quantum motions. Stochastic equations with a white noise term give all characteristics of the Brownian motion. Some generalization of the Langevin type equations allows us to obtain nonlinear equations of particles' motion, which are formally equivalent to the Schrödinger equation. Thus, we establish Nelson's stochastic mechanics on the basis of the Langevin equation.
It has long been recognized that the dynamics of linear quantum systems is classical in the Wigner representation. Yet many conceptually important linear problems are typically analyzed using such generally applicable techniques as influence functionals and Bogoliubov transformations. In this Letter we point out that the classical equations of motion provide a simpler and more intuitive formalism for linear quantum systems. We examine the important problem of Brownian motion in the independent oscillator model, and show that the quantum dynamics is described directly and completely by a c-number Langevin equation. We are also able to apply recent insights into quantum Brownian motion to show that the classical Fokker-Planck equation is always local in time, regardless of the spectral density of the environment.
Recently, a novel quantization technique has been put forward, which yields the imaginary-time quantum-mechanical propagator as a noise average involving the solutions of a Langevin equation in configuration space with a Gaussian white noise. Contrary to previous attempts, this strategy does not require any knowledge about the ground-state quantum dynamics. Our aim is to show that this approach can be cast in a different form, which exhibits a manifest connection with classical mechanics (at imaginary time). The advantages of this strategy are pointed out and illustrated by taking the harmonic oscillator as an example.
The theory of stochastic motion is formulated from a new point of view. It is shown that the fundamental equations of the theory reduce to Schrödinger's equation for specific values of certain parameters. A generalized Fokker-Planck-Kolmogorov equation is obtained; with other values of the parameters, certain approximations reduce this to the Smoluchowski equation for Brownian movement. In particular, the potential function in the Schrödinger equation differs in the two cases. The usual uncertainty relations appear in a natural way in the theory, but in a broader context. A single theory thus covers both similarities and differences between quantum-mechanical and Brownian motion. Furthermore, possibilities for broadening nonrelativistic quantum mechanics are brought out and, as an example, the possible corrections due to non-Markoffian terms are briefly studied.
The recently proposed Langevin formulation of quantum dynamics yields the propagator at imaginary time as a noise average involving the solutions to a certain Langevin equation with a Gaussian white noise. The main advantage of this approach is to permit a stochastic treatment of quantum systems even when no solutions to the Schrödinger equation are known. We show how the Langevin formulation works in the space of a (nonrelativistic) particle in a uniform magnetic field with arbitary time dependence. We are able to evaluate the quantum-mechanical propagator exactly. As far as we know, this is a new result of considerable interest for atomic and molecular physics.
In the frames of classical mechanics the generalized Langevin equation is derived for an arbitrary mechanical subsystem coupled to the harmonic bath of a solid. A time-acting temperature operator is introduced for the quantum Klein-Kramers and Smoluchowski equations, accounting for the effect of the quantum thermal bath oscillators. The model of Brownian emitters is theoretically studied and the relevant evolutionary equations for the probability density are derived. The Schrodinger equation is explained via collisions of the target point particles with the quantum force carriers, transmitting the fundamental interactions between the point particles. Thus, electrons and other point particles are no waves and the wavy chapter of quantum mechanics originated for the force carriers. A stochastic Lorentz-Langevin equation is proposed to describe the underlaying Brownian-like motion of the point particles in quantum mechanics. Considering the Brownian dynamics in the frames of the Bohmian mechanics, the density functional Bohm-Langevin equation is proposed, and the relevant Smoluchowski-Bohm equation is derived. A nonlinear master equation is proposed by proper quantization of the classical Klein-Kramers equation. Its equilibrium solution in the exact canonical Gibbs density operator, while the well-known Caldeira-Leggett equation is simply a linearization at high temperature. In the case of a free quantum Brownian particles, a new law for the spreading of the wave packet it discovered, which represents the quantum generalization of the classical Einstein law of Brownian motion. A new projector operator is proposed for the collapse of the wave function of a quantum particle moving in a classical environment. Its application results in dissipative Schrodinger equations, as well as in a new form of dissipative Liouville equation in classical mechanics.