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physica status solidi (b)

Discrete Saturation of the Optical Absorption Line of Pr3+ in CaF2 under the Condition of Pumping

T. Sh. Abesadze, M. Punkkinen

Published Oct 1, 1985• 0 citations
Publisher
DOI
10.1002/pssb.2221310252

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Site-selective laser spectroscopy of Pr3+ C4v symmetry centers in hydrogenated CaF2 : Pr3+ and SrF2 : Pr3+ crystals

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Laser-selective excitation and optical-absorption techniques have been used to establish comprehensive sets of energy levels for both the ${\mathit{F}}^{\mathrm{\ensuremath{-}}}$ and hydrogenic varieties of the tetragonal symmetry (${\mathit{C}}_{4\mathit{v}}$) centers in ${\mathrm{SrF}}_{2}$ and ${\mathrm{CaF}}_{2}$. Polarization of the various spectral lines was used to determine the symmetry labels of many of the energy levels. Reversals of the ordering of some levels between ${\mathrm{SrF}}_{2}$ and ${\mathrm{CaF}}_{2}$ are found and, in particular, the two lowest levels (${\mathit{D}}_{1}$ and ${\mathit{D}}_{2}$) of the $^{1}$${\mathit{D}}_{2}$ multiplet, which are the originating levels for many of the observed emission transitions, have reversed-symmetry label assignments in ${\mathrm{SrF}}_{2}$ and ${\mathrm{CaF}}_{2}$. Differences were found between the ground-state Zeeman splittings for the ${\mathit{C}}_{4\mathit{v}}$ ${\mathit{F}}^{\mathrm{\ensuremath{-}}}$ and ${\mathit{D}}^{\mathrm{\ensuremath{-}}}$ centers for both ${\mathrm{SrF}}_{2}$ and ${\mathrm{CaF}}_{2}$. Fluorescence lifetimes of the ${\mathit{C}}_{4\mathit{v}}$ hydrogenic centers show a strong dependence on the particular charge-compensating ion present through nonradiative decay processes involving the respective local mode phonons. The upconversion spectra observed for ${\mathit{F}}^{\mathrm{\ensuremath{-}}}$, ${\mathit{T}}^{\mathrm{\ensuremath{-}}}$, and ${\mathit{D}}^{\mathrm{\ensuremath{-}}}$ varieties of the ${\mathit{C}}_{4\mathit{v}}$ centers in ${\mathrm{SrF}}_{2}$ and for the ${\mathit{C}}_{4\mathit{v}}$ ${\mathit{F}}^{\mathrm{\ensuremath{-}}}$ center in ${\mathrm{CaF}}_{2}$ are all consistent with excitation of specific subsets of nearby ${\mathit{C}}_{4\mathit{v}}$ centers.

Physical review. B, Condensed matter•Sep 1, 1992•34 citations

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Laser-selective excitation and optical-absorption techniques have been used to establish comprehensive sets of energy levels for both the ${\mathit{F}}^{\mathrm{\ensuremath{-}}}$ and hydrogenic varieties of the tetragonal symmetry (C4v{\mathit{C}}_{4\mathit{v}}C4v​) centers in SrF2{\mathrm{SrF}}_{2}SrF2​ and CaF2{\mathrm{CaF}}_{2}CaF2​. Polarization of the various spectral lines was used to determine the symmetry labels of many of the energy levels. Reversals of the ordering of some levels between SrF2{\mathrm{SrF}}_{2}SrF2​ and CaF2{\mathrm{CaF}}_{2}CaF2​ are found and, in particular, the two lowest levels (D1{\mathit{D}}_{1}D1​ and D2{\mathit{D}}_{2}D2​) of the 1^{1}1D2{\mathit{D}}_{2}D2​ multiplet, which are the originating levels for many of the observed emission transitions, have reversed-symmetry label assignments in SrF2{\mathrm{SrF}}_{2}SrF2​ and CaF2{\mathrm{CaF}}_{2}CaF2​. Differences were found between the ground-state Zeeman splittings for the C4v{\mathit{C}}_{4\mathit{v}}C4v​ ${\mathit{F}}^{\mathrm{\ensuremath{-}}}$ and ${\mathit{D}}^{\mathrm{\ensuremath{-}}}$ centers for both SrF2{\mathrm{SrF}}_{2}SrF2​ and CaF2{\mathrm{CaF}}_{2}CaF2​. Fluorescence lifetimes of the C4v{\mathit{C}}_{4\mathit{v}}C4v​ hydrogenic centers show a strong dependence on the particular charge-compensating ion present through nonradiative decay processes involving the respective local mode phonons. The upconversion spectra observed for ${\mathit{F}}^{\mathrm{\ensuremath{-}}}$, ${\mathit{T}}^{\mathrm{\ensuremath{-}}}$, and ${\mathit{D}}^{\mathrm{\ensuremath{-}}}$ varieties of the C4v{\mathit{C}}_{4\mathit{v}}C4v​ centers in SrF2{\mathrm{SrF}}_{2}SrF2​ and for the C4v{\mathit{C}}_{4\mathit{v}}C4v​ ${\mathit{F}}^{\mathrm{\ensuremath{-}}}$ center in CaF2{\mathrm{CaF}}_{2}CaF2​ are all consistent with excitation of specific subsets of nearby C4v{\mathit{C}}_{4\mathit{v}}C4v​ centers.