The abnormal saturation absorption signal of sodium atom D1 line has been observed in different experimental conditions. The explanation has been presented quantitatively using the velocity-selective optical pumping model.
The sodium D resonance lines have been studied in saturated absorption with a repetitively pulsed tunable dye laser. The hyperfine splitting of the 32S21 and 32P21 states of Na23 is resolved. Measurements with a delayed probe reveal a remanent hole burning in the velocity distributions of the two ground-state levels, caused by a velocity-selective optical pumping cycle. A time-resolved observation of the collisional-velocity thermalization in the presence of Ar buffer gas is reported.
Doppler-free spectra of linear and circular dichroisms for the hyperfine structures of Na D1 and D2 lines have been obtained by means of polarization-modulated optical pumping spectroscopy. The experimental results are compared with recent theoretical calculations based on velocity-selective optical pumping in a four-level atomic system.
Theoretical analysis of D 1 lines of most stable alkali atoms in velocity selective optical pumping (VSOP) spectroscopy is presented by using the approximation of a single cycle of optical pumping in a four-level system. VSOP spectroscopy is clearly compared with polarization spectroscopy and then it is shown that the results obtained for polarization spectroscopy can be applied to the theory in VSOP spectroscopy. The relative signal intensities of Na D 1 line in polarization spectroscopy have been theoretically calculated and experimentally confirmed to be in good agreement with those in VSOP spectroscopy. The first-order theory in VSOP spectroscopy can be applied to the cases of the D 1 lines of the other alkali atoms. It is expected that the theoretical analysis can be useful for future experiments of the Doppler-free D lines in the alkali atoms.
Using an external cavity-tuned diode laser in Doppler-free saturation spectroscopy, we are able to resolve the weak-field Zeeman splittings in the hyperfine levels of the rubidium D1 line. The number of lines observed in the Zeeman structure of rubidium and their measured energy-level splittings are as expected from theory. The measured amplitudes of the saturated-absorption signals, crossover resonances, and velocity-selective optical pumping signals are used in the analysis of various theories concerning saturated-absorption spectroscopy.