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Journal of the Physical Society of Japan

Geometric Momentum and a Probe of Embedding Effects

Quanhui Liu

Published Sep 17, 2013• 26 citations
Publisher

Abstract

As a manifold is embedded into a higher dimensional Euclidean space, quantum mechanics gives various embedding quantities. In the present study, two embedding quantities for a two-dimensional curved surface in the three-dimensional flat space, the geometric momentum and the geometric potential, are derived in a unified manner. For a particle moving on a two-dimensional sphere or a free rotation of a spherical top, the projections of both the geometric momentum \(\mathbf{p}\) and the angular momentum \(\mathbf{L}\) onto a certain Cartesian axis form a complete set of commuting observables as \([p_{i},L_{i}]=0\) (\(i=1,2,3\)), thus constituting a dynamical \((p_{i},L_{i})\) representation for the states on the two-dimensional spherical surface. The geometric momentum distribution of the states represented by spherical harmonics is successfully obtained, and this distribution for a homonuclear diatomic molecule seems within the resolution power of present momentum spectrometers and can be measured to probe the embedding effect.

DOI
10.7566/jpsj.82.104002

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As a manifold is embedded into a higher dimensional Euclidean space, quantum mechanics gives various embedding quantities. In the present study, two embedding quantities for a two-dimensional curved surface in the three-dimensional flat space, the geometric momentum and the geometric potential, are derived in a unified manner. For a particle moving on a two-dimensional sphere or a free rotation of a spherical top, the projections of both the geometric momentum (\mathbf{p}) and the angular momentum (\mathbf{L}) onto a certain Cartesian axis form a complete set of commuting observables as ([p_{i},L_{i}]=0) ((i=1,2,3)), thus constituting a dynamical ((p_{i},L_{i})) representation for the states on the two-dimensional spherical surface. The geometric momentum distribution of the states represented by spherical harmonics is successfully obtained, and this distribution for a homonuclear diatomic molecule seems within the resolution power of present momentum spectrometers and can be measured to probe the embedding effect.
As a submanifold is embedded into higher dimensional flat space, quantum mechanics gives various embedding quantities, e.g., the geometric momentum and geometric potential, etc. For a particle moving on a two-dimensional sphere or a free rotation of a spherical top, the projections of the geometric momentum p and the angular momentum L onto a certain Cartesian axis form a complete set of commuting observables as [p_{i},L_{i}]=0 (i=1,2,3). We have therefore a (p_{i},L_{i}) representation for the states on the two-dimensional spherical surface. The geometric momentum distribution of the ground states for a freely rotating rigid rotor seems within the resolution power of present momentum spectrometer and can be measured to probe the embedding effect.
In Dirac's canonical quantization theory on systems with second-class constraints, the commutators between the position, momentum, and Hamiltonian form a set of algebraic relations that are fundamental in construction of both the quantum momentum and the Hamiltonian. For a free particle on a two-dimensional sphere or a spherical top, results show that the well-known canonical momentum ${p}_{\ensuremath{\theta}}$ breaks one of the relations, while three components of the momentum expressed in the three-dimensional Cartesian system of axes as pi{p}_{i}pi​ (i=1,2,3)(i=1,2,3)(i=1,2,3) are satisfactory all around. This momentum is not only geometrically invariant but also self-adjoint, and we call it geometric momentum. The nontrivial commutators between pi{p}_{i}pi​ generate three components of the orbital angular momentum; thus the geometric momentum is fundamental to the angular one. We note that there are five different forms of the geometric momentum proposed in the current literature, but only one of them turns out to be meaningful.
When a two-dimensional curved surface is conceived as a limiting case of a curved shell of equal thickness d, where the limit d\rightarrow0 is then taken, the well-known geometric potential is induced by the kinetic energy operator, in fact by the second order partial derivatives. Applying this confining procedure to the momentum operator, in fact to the first order partial derivatives, we find the so-called geometric momentum instead. This momentum is compatible with the Dirac's canonical quantization theory on system with second-class constraints. The distribution amplitudes of the geometric momentum on the spherical harmonics are analytically determined, and they are experimentally testable for rotational states of spherical molecules such as C_{60}.
The geometric momentum was originally introduced for defining the momentum of particle constrained on a hypersurface, but it is in fact not necessarily defined on a curved surface only. If a coordinate system contains a family of hypersurfaces and a normal vector on hypersurface used as a unit vector, the geometric momentum can be defined on the family of hypersurfaces and can be used to determine a complete set of commuting observables. For instance, the spherical polar coordinate system is such a kind of coordinate, in which for a given value of radial position, the spherical surface is a hypersurface. It is well-known that any vector in the space can be decomposed into components along each axis of the spherical polar coordinates, but the geometric momentum has a different decomposition, for it requires a projection of the momentum on the hypersurface, and then needs to decompose the projection into the Cartesian coordinates of the original space where the whole spherical coordinates are defined. Explicitly, with a relation-iħ▽= p Σ + p n where-iħ▽ can be usual momentum operator in Cartesian coordinates, and p Σ is the momentum component on the hypersurface which turns out to be the geometric momentum, and p n is the momentum component along the radial direction, we have a nontrivial definition of radial momentum as p n ≡-iħ▽- p Σ. Once-iħ▽ and p Σ are measurable, p n is then indirectly measurable. The three-dimensional isotropic harmonic oscillator can be described in both the Cartesian and the spherical polar coordinates, whose quantum states thus can be examined in terms of both momentum and geometric momentum distributions. The distributions of the radial momentum are explicitly given for some states. The radial momentum operator that was introduced by Dirac has clear physical significance, in contrast to widely spreading belief that it is not measurable due to its non-self-adjoint.
With a recently introduced geometric momentum that depends on the extrinsic curvature and offers a proper description of momentum on two-dimensional sphere, we show that the annihilation operators whose eigenstates are coherent states on the sphere take the expected form αx + iβp, where α and β are two operators that depend on the angular momentum and x and p are the position and the geometric momentum, respectively. Since the geometric momentum is manifestly a consequence of embedding the two-dimensional sphere in the three-dimensional flat space, the coherent states reflects some aspects beyond the intrinsic geometry of the surfaces.
In the spirit of the thin-layer quantization approach, we give the formula of the geometric influences of a particle confined to a curved surface embedded in three-dimensional Euclidean space. The geometric contributions can result from the reduced commutation relation between the acted function depending on normal variable and the normal derivative. According to the formula, we obtain the geometric potential, geometric momentum, geometric orbital angular momentum, geometric linear Rashba, and cubic Dresselhaus spin-orbit couplings. As an example, a truncated cone surface is considered. We find that the geometric orbital angular momentum can provide an azimuthal polarization for spin, and the sign of the geometric Dresselhaus spin-orbit coupling can be flipped through the inclination angle of generatrix.