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arXiv:1109.5223 · Physical Review A

Geometric momentum: The proper momentum for a free particle on a two-dimensional sphere

Quanhui Liu, Liang-Hui Tang, D. M. Xun

Published Oct 3, 2011• 56 citations
arXivHTMLPDF

Abstract

In Dirac's canonical quantization theory on systems with second-class constraints, the commutators between the position, momentum, and Hamiltonian form a set of algebraic relations that are fundamental in construction of both the quantum momentum and the Hamiltonian. For a free particle on a two-dimensional sphere or a spherical top, results show that the well-known canonical momentum ${p}_{\ensuremath{\theta}}$ breaks one of the relations, while three components of the momentum expressed in the three-dimensional Cartesian system of axes as ${p}_{i}$ $(i=1,2,3)$ are satisfactory all around. This momentum is not only geometrically invariant but also self-adjoint, and we call it geometric momentum. The nontrivial commutators between ${p}_{i}$ generate three components of the orbital angular momentum; thus the geometric momentum is fundamental to the angular one. We note that there are five different forms of the geometric momentum proposed in the current literature, but only one of them turns out to be meaningful.

DOI
10.1103/physreva.84.042101

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In Dirac's canonical quantization theory on systems with second-class constraints, the commutators between the position, momentum, and Hamiltonian form a set of algebraic relations that are fundamental in construction of both the quantum momentum and the Hamiltonian. For a free particle on a two-dimensional sphere or a spherical top, results show that the well-known canonical momentum p\ensuremathθ{p}_{\ensuremath{\theta}}p\ensuremathθ​ breaks one of the relations, while three components of the momentum expressed in the three-dimensional Cartesian system of axes as pi{p}_{i}pi​ (i=1,2,3)(i=1,2,3)(i=1,2,3) are satisfactory all around. This momentum is not only geometrically invariant but also self-adjoint, and we call it geometric momentum. The nontrivial commutators between pi{p}_{i}pi​ generate three components of the orbital angular momentum; thus the geometric momentum is fundamental to the angular one. We note that there are five different forms of the geometric momentum proposed in the current literature, but only one of them turns out to be meaningful.
As a manifold is embedded into a higher dimensional Euclidean space, quantum mechanics gives various embedding quantities. In the present study, two embedding quantities for a two-dimensional curved surface in the three-dimensional flat space, the geometric momentum and the geometric potential, are derived in a unified manner. For a particle moving on a two-dimensional sphere or a free rotation of a spherical top, the projections of both the geometric momentum p\mathbf{p}p and the angular momentum L\mathbf{L}L onto a certain Cartesian axis form a complete set of commuting observables as [pi,Li]=0[p_{i},L_{i}]=0[pi​,Li​]=0 (i=1,2,3i=1,2,3i=1,2,3), thus constituting a dynamical (pi,Li)(p_{i},L_{i})(pi​,Li​) representation for the states on the two-dimensional spherical surface. The geometric momentum distribution of the states represented by spherical harmonics is successfully obtained, and this distribution for a homonuclear diatomic molecule seems within the resolution power of present momentum spectrometers and can be measured to probe the embedding effect.
For a charge-monopole pair, we have another definition of the orbital angular momentum, and the transverse part of the momentum including the vector potential turns out to be the so-called geometric momentum that is under intensive study recently. For the charge on the spherical surface with the monopole at the origin, the commutation relations between all components of both the geometric momentum and the orbital angular momentum satisfy the so(3,[Formula: see text]1) algebra. With construction of the geometrically infinitesimal displacement operator based on the geometric momentum, the so(3,[Formula: see text]1) algebra implies the Aharonov–Bohm phase shift. The related problems such as charge and flux quantization are also addressed.
When a two-dimensional curved surface is conceived as a limiting case of a curved shell of equal thickness d, where the limit d\rightarrow0 is then taken, the well-known geometric potential is induced by the kinetic energy operator, in fact by the second order partial derivatives. Applying this confining procedure to the momentum operator, in fact to the first order partial derivatives, we find the so-called geometric momentum instead. This momentum is compatible with the Dirac's canonical quantization theory on system with second-class constraints. The distribution amplitudes of the geometric momentum on the spherical harmonics are analytically determined, and they are experimentally testable for rotational states of spherical molecules such as C_{60}.
The geometric momentum was originally introduced for defining the momentum of particle constrained on a hypersurface, but it is in fact not necessarily defined on a curved surface only. If a coordinate system contains a family of hypersurfaces and a normal vector on hypersurface used as a unit vector, the geometric momentum can be defined on the family of hypersurfaces and can be used to determine a complete set of commuting observables. For instance, the spherical polar coordinate system is such a kind of coordinate, in which for a given value of radial position, the spherical surface is a hypersurface. It is well-known that any vector in the space can be decomposed into components along each axis of the spherical polar coordinates, but the geometric momentum has a different decomposition, for it requires a projection of the momentum on the hypersurface, and then needs to decompose the projection into the Cartesian coordinates of the original space where the whole spherical coordinates are defined. Explicitly, with a relation-iħ▽= p Σ + p n where-iħ▽ can be usual momentum operator in Cartesian coordinates, and p Σ is the momentum component on the hypersurface which turns out to be the geometric momentum, and p n is the momentum component along the radial direction, we have a nontrivial definition of radial momentum as p n ≡-iħ▽- p Σ. Once-iħ▽ and p Σ are measurable, p n is then indirectly measurable. The three-dimensional isotropic harmonic oscillator can be described in both the Cartesian and the spherical polar coordinates, whose quantum states thus can be examined in terms of both momentum and geometric momentum distributions. The distributions of the radial momentum are explicitly given for some states. The radial momentum operator that was introduced by Dirac has clear physical significance, in contrast to widely spreading belief that it is not measurable due to its non-self-adjoint.
As a submanifold is embedded into higher dimensional flat space, quantum mechanics gives various embedding quantities, e.g., the geometric momentum and geometric potential, etc. For a particle moving on a two-dimensional sphere or a free rotation of a spherical top, the projections of the geometric momentum p and the angular momentum L onto a certain Cartesian axis form a complete set of commuting observables as [p_{i},L_{i}]=0 (i=1,2,3). We have therefore a (p_{i},L_{i}) representation for the states on the two-dimensional spherical surface. The geometric momentum distribution of the ground states for a freely rotating rigid rotor seems within the resolution power of present momentum spectrometer and can be measured to probe the embedding effect.
For a non-relativistic particle that freely moves on a curved surface, the fundamental commutation relations between positions and momenta are insufficient to uniquely determine the operator form of the momenta. With introduction of more commutation relations between positions and Hamiltonian and those between momenta and Hamiltonian, our recent sequential studies imply that the Cartesian system of coordinates is physically preferable, consistent with Dirac' observation. In present paper, we study quantization problem of the motion constrained on the two-dimensional sphere and develop a discriminant that can be used to show how the quantization within the intrinsic geometry is improper. Two kinds of parameterization of the spherical surface are explicitly invoked to investigate the quantization problem within the intrinsic geometry.