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Nature Physics

Taming molecular beams

Sebastiaan Y. T. van de Meerakker, Hendrick L. Bethlem, Gerard Meijer

Published Aug 1, 2008• 244 citations
Publisher
DOI
10.1038/nphys1031

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In the last two decades, enormous progress has been made in the manipulation of molecular beams. In particular, molecular decelerators have been developed with which advanced control over neutral molecules in a beam can be achieved. By using arrays of inhomogeneous and time-varying electric (or magnetic) fields, bunches of molecules can be produced with a tunable velocity, narrow velocity spreads, and almost perfect quantum-state purity. These monochromatic or "tamed" molecular beams are ideally suited to be used in crossed-molecular-beam scattering experiments. Here, we review the first generation of these "cold and controlled" scattering experiments that have been conducted in the last decade and discuss the prospects for this emerging field of research in the years to come.
The manipulation of gas-phase molecules with electric and magnetic fields above a chip is an emerging field of research. Miniaturization of the electric and magnetic field structures allows for the creation of large field gradients and tight traps above the chip. Present-day microelectronics technology enables the integration of complicated tools and devices on a compact surface area. The molecules can be positioned extremely accurately and reproducibly above the chip where they can be held isolated from their environment and where there is excellent access to them. It is expected that several of the gas-phase molecular beam experiments that are currently being done in machines that are up to several meters in length can in the future be performed on a surface area of a few cm 2 and that many new experiments will become possible.