Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

Applied Physics Letters

Microfabricated alkali vapor cell with anti-relaxation wall coating

Rahel Straessle, Matthieu Pellaton, C. Affolderbach, Yves Pétremand, D. Briand, G. Mileti, Nico F. de Rooij

Published Jul 28, 2014• 71 citations
Publisher

Abstract

We present a microfabricated alkali vapor cell equipped with an anti-relaxation wall coating. The anti-relaxation coating used is octadecyltrichlorosilane and the cell was sealed by thin-film indium-bonding at a low temperature of 140 °C. The cell body is made of silicon and Pyrex and features a double-chamber design. Depolarizing properties due to liquid Rb droplets are avoided by confining the Rb droplets to one chamber only. Optical and microwave spectroscopy performed on this wall-coated cell are used to evaluate the cell's relaxation properties and a potential gas contamination. Double-resonance signals obtained from the cell show an intrinsic linewidth that is significantly lower than the linewidth that would be expected in case the cell had no wall coating but only contained a buffer-gas contamination on the level measured by optical spectroscopy. Combined with further experimental evidence this proves the presence of a working anti-relaxation wall coating in the cell. Such cells are of interest for applications in miniature atomic clocks, magnetometers, and other quantum sensors.

DOI
10.1063/1.4891248

Related papers

Towards wall-coated microfabricated cells: Alkali vapor-cells using indium thin-film low-temperature bonding

Rahel Straessle, Yves Pétremand, D. Briand +4 more

We report on the realization and evaluation of micro-fabricated alkali vapor cells using a thin-film indium bonding technique. Optical and double-resonance spectroscopy performed on the cells demonstrates their suitability for atomic clock applications. Long-term measurements show a stable pressure inside the cells and therefore an excellent hermeticity of the bonding over several months. The low bonding process temperature of ≤ 140°C combined with good bond strength makes this method a promising candidate for realizing micro-fabricated alkali cells with anti-relaxation wall-coatings.

European Frequency and Time Forum•Apr 1, 2012•3 citations

Spectroscopy in a micro-fabricated Rb cell with anti-relaxation wall-coating

Matthieu Pellaton, C. Affolderbach, G. Mileti +4 more

We report on the realization and spectroscopic evaluation of a micro-fabricated Rb vapor cell equipped with an anti-relaxation OTS wall coating. By combining different spectroscopic results, we can exclude a hypothetical buffer-gas contamination of the cell as cause of the narrow double-resonance (DR) signals observed. We thus conclude that the narrow DR signal linewidth is due to the anti-relaxation wall-coating present in the cell. This realization presents interests in view of applications in miniaturized atomic devices such as atomic clocks, magnetometers, and others.

European Frequency and Time Forum•Jun 1, 2014•7 citations

Micro-fabricated Alkali Vapor Cells for Chip Scale Atomic Clocks Sealed at Low Temperature with Thin-Film Metallic Bonding

Rahel Strässle, Matthieu Pellaton, Yves Pétremand +4 more

Micro-fabriced alkali vapor cells and applications in various fields as the heart of ultraprecise sensors, like chip scale atomic clocks, magnetometers or gyroscopes. Miniaturization asks for either new fabrication techniques or new physical concepts or both. We present here a new fabrication technique for the alkali cells which allows the integration of a anti-relaxation wall coating for alkali vapor cells in order to improve the signal for miniazurized cells.

•Jan 1, 2013•0 citations

High-temperature alkali vapor cells with antirelaxation surface coatings

Scott J. Seltzer, Michael V. Romalis

Antirelaxation surface coatings allow long spin relaxation times in alkali-metal cells without buffer gas, enabling faster diffusion of the alkali atoms throughout the cell and giving larger signals due to narrower optical linewidths. Effective coatings were previously unavailable for operation at temperatures above 80 °C. We demonstrate that octadecyltrichlorosilane (OTS) can allow potassium or rubidium atoms to experience hundreds of collisions with the cell surface before depolarizing, and that an OTS coating remains effective up to about 170 °C for both potassium and rubidium. We consider the experimental concerns of operating without buffer gas and with minimal quenching gas at high vapor density, studying the stricter need for effective quenching of excited atoms and deriving the optical rotation signal shape for atoms with resolved hyperfine structure in the spin-temperature regime. As an example of a high-temperature application of antirelaxation coated alkali vapor cells, we operate a spin-exchange relaxation-free atomic magnetometer with sensitivity of 6 fT/Hz and magnetic linewidth as narrow as 2 Hz.

arXiv:0906.3054•Journal of Applied Physics•Dec 1, 2009•139 citations

Method for characterizing self-assembled monolayers as antirelaxation wall coatings for alkali vapor cells

Youngwoo Yi, H. G. Robinson, Svenja A. Knappe +5 more

We describe a method for characterizing self-assembled monolayers (SAMs) in terms of their performance as antirelaxation wall coatings for alkali atom vapor cells. A combination of initial surface analysis and subsequent laser spectroscopy is used to provide insight into the quality of the coating, as well as its performance under the exposure to alkalis as it occurs, for example, when used in applications such as atomic magnetometers or clocks. Fused silica plates coated with octadecyltrichlorosilane SAMs were used to make cubic R87b gas cells. The surface was characterized by x-ray diffraction, contact angle measurements, and atomic force microscopy. Measurements of hyperfine resonance linewidths and frequency shifts show that the rubidium vapor atoms collide up to 40 times with the walls of the cells before their coherence relaxes and their adsorption energy is around 0.065 eV. Chemical analysis of the cell indicates some weak reactions between the coating and the rubidium atoms.

Journal of Applied Physics•Jul 15, 2008•75 citations

Developments for miniature atomic magnetometry

Linda Péroux

Sensitive and accurate magnetic-field measurements are essential in many applications, including geophysical studies, biomagnetic signal detection, navigation, event monitoring, and magnetic anomaly detection. In this context, atomic magnetometers are a particularly promising approach, combining high sensitivity and accuracy, and able to rival superconducting quantum interference devices (SQUIDs) without requiring cryogenic cooling. While the best sensitivity levels are achieved in the zero-field regime within magnetic shielding, scalar magnetometers operating in ambient fields also demonstrated remarkable sensitivities. Initiated in the 2000s, the miniaturization of atomic devices, and in particular alkali-vapor cells, paves the way for magnetometers that are both sensitive and compact, well suited to embedded measurements and field applications.This thesis contributes to the development of microfabricated vapor cells for atomic magnetometry. We propose a new filling and sealing method that overcomes some limitations of conventional approaches and could enable the fabrication of purer cells compatible with a wider range of chemical species. This strategy could also facilitate the integration of anti-relaxation coatings, which reduce relaxation caused by collisions with the cell walls. To date, no long-lasting anti-relaxation effects have been demonstrated in microfabricated cells, as traditional methods rely on high temperatures that are incompatible with these coatings.A cell design suited to the deposition of anti-relaxation coatings is presented. We then describe the fabrication and characterization of a multi-axis microfabricated cell, designed for compact atomic devices using multiple optical beams. This multi-axis cell was experimentally validated in a dual-beam magnetometry configuration using an experimental setup developed as part of this thesis.

•Mar 16, 2026•0 citations
We present a microfabricated alkali vapor cell equipped with an anti-relaxation wall coating. The anti-relaxation coating used is octadecyltrichlorosilane and the cell was sealed by thin-film indium-bonding at a low temperature of 140 °C. The cell body is made of silicon and Pyrex and features a double-chamber design. Depolarizing properties due to liquid Rb droplets are avoided by confining the Rb droplets to one chamber only. Optical and microwave spectroscopy performed on this wall-coated cell are used to evaluate the cell's relaxation properties and a potential gas contamination. Double-resonance signals obtained from the cell show an intrinsic linewidth that is significantly lower than the linewidth that would be expected in case the cell had no wall coating but only contained a buffer-gas contamination on the level measured by optical spectroscopy. Combined with further experimental evidence this proves the presence of a working anti-relaxation wall coating in the cell. Such cells are of interest for applications in miniature atomic clocks, magnetometers, and other quantum sensors.
We report on the realization and evaluation of micro-fabricated alkali vapor cells using a thin-film indium bonding technique. Optical and double-resonance spectroscopy performed on the cells demonstrates their suitability for atomic clock applications. Long-term measurements show a stable pressure inside the cells and therefore an excellent hermeticity of the bonding over several months. The low bonding process temperature of ≤ 140°C combined with good bond strength makes this method a promising candidate for realizing micro-fabricated alkali cells with anti-relaxation wall-coatings.
We report on the realization and spectroscopic evaluation of a micro-fabricated Rb vapor cell equipped with an anti-relaxation OTS wall coating. By combining different spectroscopic results, we can exclude a hypothetical buffer-gas contamination of the cell as cause of the narrow double-resonance (DR) signals observed. We thus conclude that the narrow DR signal linewidth is due to the anti-relaxation wall-coating present in the cell. This realization presents interests in view of applications in miniaturized atomic devices such as atomic clocks, magnetometers, and others.
Antirelaxation surface coatings allow long spin relaxation times in alkali-metal cells without buffer gas, enabling faster diffusion of the alkali atoms throughout the cell and giving larger signals due to narrower optical linewidths. Effective coatings were previously unavailable for operation at temperatures above 80 °C. We demonstrate that octadecyltrichlorosilane (OTS) can allow potassium or rubidium atoms to experience hundreds of collisions with the cell surface before depolarizing, and that an OTS coating remains effective up to about 170 °C for both potassium and rubidium. We consider the experimental concerns of operating without buffer gas and with minimal quenching gas at high vapor density, studying the stricter need for effective quenching of excited atoms and deriving the optical rotation signal shape for atoms with resolved hyperfine structure in the spin-temperature regime. As an example of a high-temperature application of antirelaxation coated alkali vapor cells, we operate a spin-exchange relaxation-free atomic magnetometer with sensitivity of 6 fT/Hz and magnetic linewidth as narrow as 2 Hz.
We describe a method for characterizing self-assembled monolayers (SAMs) in terms of their performance as antirelaxation wall coatings for alkali atom vapor cells. A combination of initial surface analysis and subsequent laser spectroscopy is used to provide insight into the quality of the coating, as well as its performance under the exposure to alkalis as it occurs, for example, when used in applications such as atomic magnetometers or clocks. Fused silica plates coated with octadecyltrichlorosilane SAMs were used to make cubic R87b gas cells. The surface was characterized by x-ray diffraction, contact angle measurements, and atomic force microscopy. Measurements of hyperfine resonance linewidths and frequency shifts show that the rubidium vapor atoms collide up to 40 times with the walls of the cells before their coherence relaxes and their adsorption energy is around 0.065 eV. Chemical analysis of the cell indicates some weak reactions between the coating and the rubidium atoms.
Sensitive and accurate magnetic-field measurements are essential in many applications, including geophysical studies, biomagnetic signal detection, navigation, event monitoring, and magnetic anomaly detection. In this context, atomic magnetometers are a particularly promising approach, combining high sensitivity and accuracy, and able to rival superconducting quantum interference devices (SQUIDs) without requiring cryogenic cooling. While the best sensitivity levels are achieved in the zero-field regime within magnetic shielding, scalar magnetometers operating in ambient fields also demonstrated remarkable sensitivities. Initiated in the 2000s, the miniaturization of atomic devices, and in particular alkali-vapor cells, paves the way for magnetometers that are both sensitive and compact, well suited to embedded measurements and field applications.This thesis contributes to the development of microfabricated vapor cells for atomic magnetometry. We propose a new filling and sealing method that overcomes some limitations of conventional approaches and could enable the fabrication of purer cells compatible with a wider range of chemical species. This strategy could also facilitate the integration of anti-relaxation coatings, which reduce relaxation caused by collisions with the cell walls. To date, no long-lasting anti-relaxation effects have been demonstrated in microfabricated cells, as traditional methods rely on high temperatures that are incompatible with these coatings.A cell design suited to the deposition of anti-relaxation coatings is presented. We then describe the fabrication and characterization of a multi-axis microfabricated cell, designed for compact atomic devices using multiple optical beams. This multi-axis cell was experimentally validated in a dual-beam magnetometry configuration using an experimental setup developed as part of this thesis.