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Physical Review A

Evolution of coherences and populations in the secular approximation

Allan Tameshtit, John E. Sipe

Published Jan 1, 1994• 14 citations
Publisher

Abstract

We consider systems coupled to a heat reservoir that has a Debye density of states. In particular, starting from master equations derived in the secular (or rotating-wave) approximation, we derive expressions for the decoherence rates and energy-jump moments for systems and couplings of varying degrees of generality. We also furnish the semiclassical analogs of these expressions. Finally, using the jump moments, we examine various aspects of the energy relaxation to thermal equilibrium.

DOI
10.1103/physreva.49.89

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We consider systems coupled to a heat reservoir that has a Debye density of states. In particular, starting from master equations derived in the secular (or rotating-wave) approximation, we derive expressions for the decoherence rates and energy-jump moments for systems and couplings of varying degrees of generality. We also furnish the semiclassical analogs of these expressions. Finally, using the jump moments, we examine various aspects of the energy relaxation to thermal equilibrium.
We present a systematic thermodynamic analysis of nonsecular GKLS master equations. When some energy transitions in the system are comparable with the dissipative rate, the secular approximation is not valid, and the positivity of the dynamics must be ensured via other approximations. The dynamics then presents features reminiscent from strong coupling to the environment: e.g. the equilibrium state with an environment at thermal equilibrium is not a Gibbs state of the local system Hamiltonian and the dynamics couples energy coherences and populations. Nonetheless, we build a unified, consistent thermodynamic framework for those dynamics. We focus on two approximations beyond the full secular approximation (the local and the more accurate geometric-arithmetic approximations), and then employ systematic perturbation theory on microscopic expressions for the first and second law of thermodynamics which relate irreversibility to the increase of system-environment correlations. We show that, in spite of the weak system-bath coupling, the system-bath interaction energy participates to the energy balance, and is directly linked to the Lamb-shift Hamiltonian. We compare this microscopic entropy production with the definition based on the contractivity of the reduced system dynamics (Spohn inequality). We show that, unlike for secular master equations, the two entropy production rates differ because of the presence of non-vanishing stationary coherences in the energy eigenbasis. However, in the case of a single thermal bath, the difference is purely transient, and no work can be cyclically extracted from the steady-state despite its non-Gibbs form. Finally, we illustrate our results with simple examples, clarifying and completing the thermodynamic picture of Markovian dynamics in the quantum regime.
For sufficiently low reservoir temperatures, it is known that open quantum systems subject to decoherent interactions with the reservoir relax toward their ground state in the weak coupling limit. Within the framework of quantum master equations, this is formalized by the Born-Markov-secular (BMS) approximation, where one obtains the system Gibbs state with the reservoir temperature as a stationary state. When the solution to some problem is encoded in the (isolated) ground state of a system Hamiltonian, decoherence can therefore be exploited for computation. The computational complexity is then given by the scaling of the relaxation time with the system size nnn. We study the relaxation behavior for local and nonlocal Hamiltonians that are coupled dissipatively with local and nonlocal operators to a bosonic bath in thermal equilibrium. We find that relaxation is generally more efficient when coherences of the density matrix in the system energy eigenbasis are taken into account. In addition, the relaxation speed strongly depends on the matrix elements of the coupling operators between initial state and ground state. We show that Dicke superradiance is a special case of our relaxation models and can thus be understood as a coherence-assisted relaxation speedup.
We derive a nonperturbative bound on the distance between evolutions of open quantum systems described by time-dependent generators. We show how this result can be employed to provide an explicit upper bound on the error of the rotating-wave approximation in the presence of dissipation and decoherence. We apply the derived bound to the strong-coupling limit in open quantum systems and to the secular approximation used to obtain a master equation of the Gorini-Kossakowski-Lindblad-Sudarshan form from the Redfield master equation.
A quantum statistical model for the relaxation of two strongly coupled spin 1/2 particles toward thermal equilibrium is formulated microscopically using a master equation. Raman-type dissipation mechanisms are introduced in addition to the usual bilinear coupling between the coupled system and the reservoir. The effects of two different rotating wave approximations to derive the master equation are investigated. Decoherence is considered as a process toward thermal equilibrium for the dissipative system and is studied by observing the phase and energy relaxation.
Periodically driven open quantum systems are central to quantum thermodynamics and quantum control. These systems are typically described using Floquet-Born-Markov master equations, derived with the use of a full secular approximation, and whose thermodynamic implications are often overlooked. In this context, we show that such a strong secular approximation may lead to unphysical predictions for steady state energy currents. We then demonstrate that a coarse-grained formulation of the master equation can regularize these issues while yielding completely positive dynamics and consistent energy currents. The coarse-graining time has a clear physical interpretation, as it defines the temporal resolution at which a Markovian master equation can describe the evolution of the periodically driven system. We show the consistency and validity of our approach by comparing to an exact non-Markovian simulation in paradigmatic examples: a driven two-level system and a three-level maser coupled to hot and cold thermal reservoirs. Our work provides a practical framework for correctly applying the secular approximation in periodically driven-dissipative systems and for assessing the accuracy of master equations of the GKSL form.
We develop from first principles Markovian master equations suited for studying the time evolution of a system evolving adiabatically while coupled weakly to a thermal bath. We derive two sets of equations in the adiabatic limit, one using the rotating wave (secular) approximation that results in a master equation in Lindblad form, the other without the rotating wave approximation but not in Lindblad form. The two equations make markedly different predictions depending on whether or not the Lamb shift is included. Our analysis keeps track of the various time and energy scales associated with the various approximations we make, and thus allows for a systematic inclusion of higher order corrections, in particular beyond the adiabatic limit. We use our formalism to study the evolution of an Ising spin chain in a transverse field and coupled to a thermal bosonic bath, for which we identify four distinct evolution phases. While we do not expect this to be a generic feature, in one of these phases dissipation acts to increase the fidelity of the system state relative to the adiabatic ground state.