For sufficiently low reservoir temperatures, it is known that open quantum systems subject to decoherent interactions with the reservoir relax toward their ground state in the weak coupling limit. Within the framework of quantum master equations, this is formalized by the Born-Markov-secular (BMS) approximation, where one obtains the system Gibbs state with the reservoir temperature as a stationary state. When the solution to some problem is encoded in the (isolated) ground state of a system Hamiltonian, decoherence can therefore be exploited for computation. The computational complexity is then given by the scaling of the relaxation time with the system size $n$. We study the relaxation behavior for local and nonlocal Hamiltonians that are coupled dissipatively with local and nonlocal operators to a bosonic bath in thermal equilibrium. We find that relaxation is generally more efficient when coherences of the density matrix in the system energy eigenbasis are taken into account. In addition, the relaxation speed strongly depends on the matrix elements of the coupling operators between initial state and ground state. We show that Dicke superradiance is a special case of our relaxation models and can thus be understood as a coherence-assisted relaxation speedup.
For sufficiently low reservoir temperatures, it is known that open quantum systems subject to decoherent interactions with the reservoir relax toward their ground state in the weak coupling limit. Within the framework of quantum master equations, this is formalized by the Born-Markov-secular (BMS) approximation, where one obtains the system Gibbs state with the reservoir temperature as a stationary state. When the solution to some problem is encoded in the (isolated) ground state of a system Hamiltonian, decoherence can therefore be exploited for computation. The computational complexity is then given by the scaling of the relaxation time with the system size n. We study the relaxation behavior for local and nonlocal Hamiltonians that are coupled dissipatively with local and nonlocal operators to a bosonic bath in thermal equilibrium. We find that relaxation is generally more efficient when coherences of the density matrix in the system energy eigenbasis are taken into account. In addition, the relaxation speed strongly depends on the matrix elements of the coupling operators between initial state and ground state. We show that Dicke superradiance is a special case of our relaxation models and can thus be understood as a coherence-assisted relaxation speedup.
In various fields from quantum physics to biology, the open quantum dynamics of a system consisting of interacting subsystems emphasizes its fundamental functionality. The local approach, deriving a dissipator in a master equation by ignoring the inter-subsystem interaction, has been widely used to describe the reduced dynamics due to its robustness to keep the positivity of a density operator. However, one critique is that a stationary state obtained by the approach in the limit of weak system-environment coupling is written in the form of the Gibbs state for the partial Hamiltonian by excluding the inter-subsystem interaction from the total one of the relevant system. As an alternative, the global approach, deriving a dissipator with including the inter-subsystem interaction, under the Born--Markov and secular approximations has attracted much attention, and there is debate concerning its violation of positivity in the short-term region and/or limited parameter region for the Bohr frequencies of the subsystems. In this study, we present a formalism that leads to the time-convolutionless (time-local) master equation obtained by extending the global approach beyond the Born-Markov and secular approximations. We apply it to the excitation energy transfer between interacting sites in which only the terminal site weakly interacts with a bosonic environment of finite temperature in a manner beyond the rotating-wave approximation. We find that the formulation (1) gives the short-time behavior while preserving positivity, (2) shows the oscillatory features that the secular approximation would obscure, and (3) leads to a stationary state very near to the Gibbs state for the total Hamiltonian of the relevant system.
In various fields from quantum physics to biology, the open quantum dynamics of a system consisting of interacting subsystems emphasizes its fundamental functionality. The local approach, deriving a dissipator in a master equation by ignoring the intersubsystem interaction, has been widely used to describe the reduced dynamics due to its robustness to keep the positivity of a density operator. However, one critique is that a stationary state obtained by the approach in the limit of weak system-environment coupling is written in the form of the Gibbs state for the partial Hamiltonian by excluding the intersubsystem interaction from the total one of the relevant system. As an alternative, the global approach, deriving a dissipator with including the intersubsystem interaction, under the Born-Markov and secular approximations has attracted much attention, and there is debate concerning its violation of positivity in the short-time region and/or limited parameter region for the Bohr frequencies of the subsystems. In this paper, we present a formalism that leads to the time-convolutionless (time-local) master equation obtained by extending the global approach beyond the Born-Markov and secular approximations. We apply it to the excitation energy transfer between interacting sites in which only the terminal site weakly interacts with a bosonic environment of finite temperature in a manner beyond the rotating-wave approximation. We find that the formulation (1) gives the short-time behavior while preserving positivity, (2) shows the oscillatory features that the secular approximation would obscure, and (3) leads to a stationary state very near to the Gibbs state for the total Hamiltonian of the relevant system.
We study the quantum dynamics of an open network of two-level systems which is coupled to a correlated common environment represented by a bosonic field in a thermal equilibrium state. Extensive numerical simulations of the full second-order time-convolutionless quantum master equation for the density matrix of various types of networks are performed, in order to investigate dissipation and decoherence processes and, in particular, their dependence on the spatial separation of the network sites and on the speed of the bosonic field modes. In the limit of an infinite speed the influence of the environment disappears due to the emergence of a decoherence-free subspace, while the limit of zero speed corresponds to the case in which the network sites are coupled to independent reservoirs, a case which is much easier to treat numerically. The main result of the paper is a general intuitive criterion which states that the simpler model of independent reservoirs can be used as long as the network relaxation time is smaller than the time it takes for the modes to travel the minimal distance between the network sites.
The theory of open quantum systems represents one of the major developments of quantum mechanics over the last 50 years. Its central object of study is constituted by quantum systems that cannot be regarded as fully isolated, but instead interact with additional degrees of freedom, giving rise to irreversible phenomena such as dissipation and decoherence. The tools provided by this framework are nowadays of paramount importance across many active areas of research, including quantum computation, thermodynamics, metrology and biology. In this thesis, we investigate three main topics within the field. The first contribution concerns the microscopic derivation of the evolution equations, socalled quantum master equations, for open systems which are also subject to external driving fields. Standard techniques developed for time-independent Hamiltonians encounter several difficulties in the time-dependent case, largely restricting their applicability to specific instances, such as periodic or adiabatic drivings. In contrast, a core result of the derivation presented in the thesis is that, when the environment is sufficiently Markovian (essentially, memoryless), the non-adiabatic contributions to the driving field can be neglected in a controlled fashion, yielding an accurate master equation with time-dependent generator, capable of correctly reproducing the open dynamics even for strong drivings. This result is further supported by benchmarks against numerically exact simulations. The second contribution addresses the long-time behavior of general types of (Markovian) quantum master equations, including those of the form introduced above. While this problem has been extensively analyzed in the time-independent setting, virtually no results are known for time-dependent generators. In particular, we establish the foundations of a general theory of relaxation, that is, convergence towards an asymptotic trajectory in the long-time limit, independently of the initial state. The main results include a theorem guaranteeing sufficient conditions for relaxation and the derivation of a rate function governing the convergence to the asymptotic trajectory. The analysis is further extended to a simple non-Markovian case. Moreover, we treat in detail the specific master equation derived in the first part, connecting the aforementioned relaxation property directly to the underlying microscopic dynamics. The third contribution investigates chirality-induced spin selectivity (CISS) effects from the perspective of open quantum systems. Although the majority of theoretical studies aiming to model CISS are based on a coherent description of the spin dynamics, such effects have been observed also for electrons subject to incoherent transport across molecular networks. In this regard, we provide a rigorous ab initio derivation of the microscopic Hamiltonian describing the electronic transport, incorporating electron spin effects and contributions stemming from the nuclear vibrations. Within this result, we critically revise a master equation approach aiming to explain the origin of CISS effects observed in photosynthetic complexes. Taken together, these contributions offer fresh insights and original results on the interplay between driving fields and dissipation, relaxation phenomena, and electronic spin transport in the presence of incoherent dynamics. More broadly, these results provide new theoretical tools with several potential applications in quantum technologies, from modeling of control pulses in noisy environments to quantum reservoir engineering, and contribute to a deeper understanding of the role of quantum effects in biological systems.
The loss of coherence in a general open quantum system interacting with a bosonic environment is analyzed. The reservoir is initially in a thermal state. The reduced dynamics is described by a non-Markovian time-local master equation. We consider spectral densities that are sub- or super-Ohmic at low frequencies and arbitrarily shaped at high frequencies. In the super-Ohmic regime, for noninteger frequency powers larger than 2, long time survival of coherence appears. In the latter regime, at vanishing temperature, the asymptotic amount of surviving coherence is stabilized to its initial value, up to a phase factor, by properly increasing the bandwidth and decreasing the low-frequency profile of the spectral density. For noninteger positive frequency powers less than 2, stretched exponential-like decoherence is found over long times. The relaxations to the asymptotic configurations become arbitrarily slow by approaching the frequency power 2 of the super-Ohmic regime. The same dependence on temperature, spectral density, and scale frequency appears for purity and concurrence of two qubits and coherence of a qubit.
Integrable quantum many-body systems are considered to equilibrate to generalized Gibbs ensembles (GGEs). A general mechanism of such relaxation to GGE has been shown for unitary evolutions of exactly solvable quadratic bosonic systems in the thermodynamic limit. Here, we explore the role of locality and interaction with surroundings in the relaxation by considering the reduced dynamics of a class of open systems weakly interacting with a reservoir, which is initially prepared in a locally perturbed GGE. The standard derivation of a quantum master equation fails to describe relaxation to GGE in the long-time limit in the presence of the initial perturbation. We investigate a proper quantum master equation that guarantees the relaxation to GGE to avoid this counterintuitive issue and describes the relaxation to the reduced state corresponding to GGE in the thermodynamic limit. In particular, we show that the stationary state of the open system is fully characterized by GGE of the reservoir, which is independent of the initial local perturbation.