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arXiv:1206.4197 · New Journal of Physics

Quantum adiabatic Markovian master equations

Tameem Albash, Sergio Boixo, Daniel A. Lidar, Paolo Zanardi A

Published Dec 11, 2012• 280 citations
arXivHTMLPDF

Abstract

We develop from first principles Markovian master equations suited for studying the time evolution of a system evolving adiabatically while coupled weakly to a thermal bath. We derive two sets of equations in the adiabatic limit, one using the rotating wave (secular) approximation that results in a master equation in Lindblad form, the other without the rotating wave approximation but not in Lindblad form. The two equations make markedly different predictions depending on whether or not the Lamb shift is included. Our analysis keeps track of the various time and energy scales associated with the various approximations we make, and thus allows for a systematic inclusion of higher order corrections, in particular beyond the adiabatic limit. We use our formalism to study the evolution of an Ising spin chain in a transverse field and coupled to a thermal bosonic bath, for which we identify four distinct evolution phases. While we do not expect this to be a generic feature, in one of these phases dissipation acts to increase the fidelity of the system state relative to the adiabatic ground state.

DOI
10.1088/1367-2630/14/12/123016

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We develop from first principles Markovian master equations suited for studying the time evolution of a system evolving adiabatically while coupled weakly to a thermal bath. We derive two sets of equations in the adiabatic limit, one using the rotating wave (secular) approximation that results in a master equation in Lindblad form, the other without the rotating wave approximation but not in Lindblad form. The two equations make markedly different predictions depending on whether or not the Lamb shift is included. Our analysis keeps track of the various time and energy scales associated with the various approximations we make, and thus allows for a systematic inclusion of higher order corrections, in particular beyond the adiabatic limit. We use our formalism to study the evolution of an Ising spin chain in a transverse field and coupled to a thermal bosonic bath, for which we identify four distinct evolution phases. While we do not expect this to be a generic feature, in one of these phases dissipation acts to increase the fidelity of the system state relative to the adiabatic ground state.
For adiabatically and periodically manipulated dissipative quantum systems we derive, using Floquet theory, a simple Markovian master equation. Contrary to some previous works we explicitly take into account the time dependence of the Hamiltonian and, therefore, obtain a master equation with a time-dependent dissipative part. We illustrate our theory with two examples and compare our results with the previously proposed master equations. In particular, we consider the problem of Cooper pair pumping and demonstrate the inadequacy of the secular (rotating wave) approximation when calculating the pumped charge. The secular approximation producing a master equation of the Lindblad type approximates well the quantum state (density matrix) of the system, while to determine the pumped charge a non-Lindblad master equation beyond the rotating wave approximation is necessary.
We derive a Markovian master equation that models the evolution of systems subject to driving and control fields. Our approach combines time rescaling and weak-coupling limits for the system-environment interaction with a secular approximation. The derivation makes use of the adiabatic time-evolution operator in a manner that allows for the efficient description of strong driving, while recovering the well-known adiabatic master equation in the appropriate limit. To illustrate the effectiveness of our approach, firstly we apply it to the paradigmatic case of a two-level (qubit) system subject to a form of periodic driving that remains unsolvable using a Floquet representation and lastly we extend this scenario to the situation of two interacting qubits, the first driven while the second one directly in contact with the environment. We demonstrate the reliability and broad scope of our approach by benchmarking the solutions of the derived reduced time evolution against numerically exact simulations using tensor networks. Our results provide rigorous conditions that must be satisfied by phenomenological master equations for driven systems that do not rely on first-principles derivations.
We compare different quantum master equations for the time evolution of the reduced density matrix. The widely applied secular approximation (rotating wave approximation) applied in combination with the Born-Markov approximation generates a Lindblad-type master equation ensuring for completely positive and stable evolution and is typically well applicable for optical baths. For phonon baths however, the secular approximation is expected to be invalid. The usual Markovian master equation does not generally preserve positivity of the density matrix. As a solution we propose a coarse-graining approach with a dynamically adapted coarse-graining time scale. For some simple examples we demonstrate that this preserves the accuracy of the integro-differential Born equation. For large times we analytically show that the secular approximation master equation is recovered. The method can in principle be extended to systems with a dynamically changing system Hamiltonian, which is of special interest for adiabatic quantum computation. We give some numerical examples for the spin-boson model of cases where a spin system thermalizes rapidly, and other examples where thermalization is not reached.
We construct a quantum Markovian master equation for a driven system coupled to a thermal bath. The derivation utilizes an explicit solution of the propagator of the driven system. This enables the validity of the master equation to be extended beyond the adiabatic limit. The nonadiabatic master equation (NAME) is derived employing the weak system-bath coupling limit. The NAME is valid when a separation of timescales exists between the bath dynamics and the external driving. In contrast to the adiabatic master equation, the NAME leads to coupled equations of motion for the population and coherence. We employ the NAME to solve the example of an open driven time-dependent harmonic oscillator. For the harmonic oscillator the NAME predicts the emergence of coherence associated with the dissipation term. As a result of the nonadiabatic driving the thermalization rate is suppressed. The solution is compared with both numerical calculations and the adiabatic master equation.
The Lindblad theory of open quantum systems has been successfully applied in various fields ranging from quantum optics, condensed matter physics, and quantum thermodynamics to quantum chemistry. Nevertheless, there are situations where we can compare its predictions to those of exact methods or numerically exact results and find discrepancies between them. One example is the case where a single harmonic oscillator is coupled to a thermal bath of independent harmonic oscillators. In this case, for certain parameters, the exact master equation describes equilibration of the system to a thermal state with a temperature different from the one predicted by the Lindblad master equation. The Lindblad theory, based on a weak coupling between the system and environment as well as the Born-Markov approximation, predicts that the system will evolve to a thermal state whose temperature is equal to the initial temperature of the bath. This result is a consequence of the Born approximation, which supposes that throughout the evolution, the bath only fluctuates around its initial equilibrium state. In this master thesis we study the validity of the Born approximation as well as its consistency with other approximations. By starting from a Hamiltonian for the total system we show that, if the the Born approximation is not invoked, the dynamics of the system is determined by a hierarchy of equations for matrices which can be used to reconstruct the reduced density matrix of the system. This hierarchy approach is fundamentally different from the standard approach, which describes the system dynamics with a weak-coupling master equation, because the hierarchy does not restrict the amount of entanglement possible between the system and the environment. Furthermore, we show how invoking the Born approximation reduces to the usual result and how a generalised ansatz, which we refer to as a generalised Born approximation, reduces the hierarchy to a master equation where the bath temperature is an additional degree of freedom. Finally, we analyse the conservation of the energy of the total system and its relationship to the Markov and secular approximations, and discuss whether imposing it as a condition can fix the time-dependent temperature.
For adiabatically and periodically manipulated dissipative quantum systems, we derive, using Floquet theory, a simple Markovian master equation. Contrary to some previous works, we explicitly take into account the time dependence of the Hamiltonian and, therefore, obtain a master equation with a time-dependent dissipative part. We illustrate our theory with two examples and compare our results with the previously proposed master equations. In particular, we consider the problem of Cooper-pair pumping and demonstrate the inadequacy of the secular (rotating-wave) approximation when calculating the pumped charge. The secular approximation producing a master equation of the Lindblad-type approximates well the quantum state (density matrix) of the system, while to determine the pumped charge, a non-Lindblad master equation beyond the rotating-wave approximation is necessary.