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Physical Review A

Quantum kinetic equation of a Bose gas

Bo-jun Yang, Shu-guang Yao

Published Feb 1, 1992• 0 citations
Publisher

Abstract

The quantum kinetic equation of a Bose gas is derived by means of the Bogoliubov approach and the Wigner distribution function from the Liouville--von Neumann equation. It is an improved Boltzmann-Uehling-Uhlenbeck equation including the correctional binary collision with many-body effects.
DOI
10.1103/physreva.45.2294

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A quantum kinetic master equation (QKME) for bosonic atoms is formulated. It is a quantum stochastic equation for the kinetics of a dilute quantum Bose gas, and describes the behavior and formation of Bose condensation. The key assumption in deriving the QKME is a Markov approximation for the atomic collision terms. In the present paper the basic structure of the theory is developed, and approximations are stated and justified to delineate the region of validity of the theory. Limiting cases of the QKME include the quantum Boltzmann master equation and the Uehling-Uhlenbeck equation, as well as an equation analogous to the Gross-Pitaevskii equation.
The Boltzmann equation is the traditional framework in which one extends the time-dependent mean field classical description of a many-body system to include the effect of particle-particle collisions in an approximate manner. A semiclassical extension of this approach to quantum many-body systems was suggested by Uehling and Uhlenbeck in 1933 for both Fermi and Bose statistics, and many further developments of this approach are known as the Boltzmann-Uehling-Uhlenbeck (BUU) equations. Here I introduce a pure quantum version of the BUU type of equations, which is mathematically equivalent to a generalized time-dependent density functional theory extended to superfluid systems. As expected, during nonequilibrium processes the quantum Boltzmann one-body entropy increases during evolution.
By means of the time-smoothing method developed in the previous papers of this series, the quantum kinetic equation is derived from the principles of statistical mechanics. In this paper, we avoid the BBGKY hierarchy; instead we use the Liouville-von Neumann equation for the time-smoothed density matrix. The Boltzmann distribution function is defined in terms of this time-smoothed density matrix. The present scheme may be applied to strong-coupling systems even if they are not in near equilibrium.
At low temperatures the De Broglie wavelength of the gas particles becomes on the order of their average separation, and the effects of their indistinguishability become important. In the absence of a phase transition in the gas, the quantum mechanical Wigner distribution function for a dilute gas of fermions or bosons satisfies the Uehling-Uhlenbeck equation. This equation satisfies an H- theorem with equilibrium solutions being ideal boson or ideal fermion distributions. Navier-Stokes equations can be derived by standard methods. A low temperature gas of weakly interacting bosons undergoes a Bose-Einstein condensation with a macroscopically occupied ground state. A different approach is required to describe the non-equilibrium processes in such a situation. A kinetic equation can be derived for the Bogoliubov excitations in the gas at very low temperatures. The associated hydrodynamic equations are the Landau-Khaltnikov, two fluid equations, and explicit expressions are obtained for the six associated transport coefficients.
The Boltzmann equation is the traditional framework in which one extends the time-dependent mean field classical description of a many-body system to include the effect of particle-particle collisions in an approximate manner. A semiclassical extension of this approach to quantum many-body systems was suggested by Uehling and Uhlenbeck in 1933 for both Fermi and Bose statistics, and many further generalization of this approach are known as the Boltzmann-Uehling-Uhlenbeck (BUU) equations. Here I suggest a pure quantum version of the BUU type of equations, which is mathematically equivalent to a generalized Time-Dependent Density Functional Theory extended to superfluid systems.