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arXiv:quant-ph/9611043 · Physical Review A

Quantum kinetic theory: A quantum kinetic master equation for condensation of a weakly interacting Bose gas without a trapping potential

Crispin W. Gardiner, P. Zoller

Published Apr 1, 1997• 163 citations
arXivHTMLPDF

Abstract

A quantum kinetic master equation (QKME) for bosonic atoms is formulated. It is a quantum stochastic equation for the kinetics of a dilute quantum Bose gas, and describes the behavior and formation of Bose condensation. The key assumption in deriving the QKME is a Markov approximation for the atomic collision terms. In the present paper the basic structure of the theory is developed, and approximations are stated and justified to delineate the region of validity of the theory. Limiting cases of the QKME include the quantum Boltzmann master equation and the Uehling-Uhlenbeck equation, as well as an equation analogous to the Gross-Pitaevskii equation.

DOI
10.1103/physreva.55.2902

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A quantum kinetic master equation (QKME) for bosonic atoms is formulated. It is a quantum stochastic equation for the kinetics of a dilute quantum Bose gas, and describes the behavior and formation of Bose condensation. The key assumption in deriving the QKME is a Markov approximation for the atomic collision terms. In the present paper the basic structure of the theory is developed, and approximations are stated and justified to delineate the region of validity of the theory. Limiting cases of the QKME include the quantum Boltzmann master equation and the Uehling-Uhlenbeck equation, as well as an equation analogous to the Gross-Pitaevskii equation.
We present results of simulations of a quantum Boltzmann master equation (QBME) describing the kinetics of a dilute Bose gas confined in a trapping potential in the regime of Bose condensation. The QBME is the simplest version of a quantum kinetic master equation derived in previous work. We consider two cases of trapping potentials: a three-dimensional square-well potential with periodic boundary conditions and an isotropic harmonic oscillator. We discuss the stationary solutions and relaxation to equilibrium. In particular, we calculate particle distribution functions, fluctuations in the occupation numbers, the time between collisions, and the mean occupation numbers of the one-particle states in the regime of onset of Bose condensation.
We introduce quantum versions of the Kac Master Equation and the Kac Boltzmann Equation. We study the steady states of each of these equations, and prove a propagation of chaos theorem that relates them. The Quantum Kac Master Equation (QKME) describes a quantum Markov semigroup, while the Kac Boltzmann Equation describes a non-linear evolution of density matrices on the single particle state space. All of the steady states of the NNN particle quantum system described by the QKME are separable, and thus the evolution described by the QKME is entanglement breaking. The results set the stage for a quantitative study of approach to equilibrium in quantum kinetic theory, and a quantitative study the rate of destruction of entanglement in a class of quantum Markov semigroups describing binary interactions.
We derive a kinetic theory for a spin-1/2 Bose-condensed gas of two-level atoms at finite temperatures. The condensate dynamics is described by a generalized Gross-Pitaevskii equation for the two-component spinor order parameter, which includes the interaction with the uncondensed fraction. The noncondensate atoms are described by a quantum kinetic equation, which is a generalization of the spin kinetic equation for spin-polarized quantum gases to include couplings to the condensate degree of freedom. The kinetic equation is used to derive hydrodynamic equations for the noncondensate spin density. The condensate and noncondensate spins are coupled directly through the exchange mean field. Collisions between the condensate and noncondensate atoms give rise to an additional contribution to the spin diffusion relaxation rate. In addition, they give rise to mutual relaxation of the condensate and noncondensate due to lack of local equilibrium between the two components.
We derive a kinetic theory for a spin-1/2 Bose-condensed gas of two-level atoms at finite temperatures. The condensate dynamics is described by a generalized Gross–Pitaevskii equation for the two-component spinor order parameter, which includes the interaction with the uncondensed fraction. The noncondensate atoms are described by a quantum kinetic equation, which is a generalization of the spin kinetic equation for spin-polarized quantum gases to include couplings to the condensate degree of freedom. The kinetic equation is used to derive hydrodynamic equations for the noncondensate spin density. The condensate and noncondensate spins are coupled directly through the exchange mean field. Collisions between the condensate and noncondensate atoms give rise to an additional contribution to the spin diffusion relaxation rate. In addition, they give rise to mutual relaxation of the condensate and noncondensate due to lack of local equilibrium between the two components.