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International Journal of Modern Physics B

THERMODYNAMICS OF q-MODIFIED BOSONS

P. Narayana Swamy

Published Mar 15, 1996• 29 citations
Publisher

Abstract

Based on a recent study of the statistical mechanical properties of the q-modified boson oscillators, we develop the statistical mechanics of the q-modified boson gas, in particular the Grand Partition Function. We derive the various thermodynamic functions for the q-boson gas including the entropy, pressure and specific heat. We demonstrate that the gas exhibits a phase transition analogous to ordinary bose condensation. We derive the equation of state and develop the virial expansion for the equation of state. Several interesting properties of the q-boson gas are derived and compared with those of the ordinary boson which may point to the physical relevance of such systems.

DOI
10.1142/s0217979296000283

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Based on a recent study of the statistical mechanical properties of the q-modified boson oscillators, we develop the statistical mechanics of the q-modified boson gas, in particular the Grand Partition Function. We derive the various thermodynamic functions for the q-boson gas including the entropy, pressure and specific heat. We demonstrate that the gas exhibits a phase transition analogous to ordinary bose condensation. We derive the equation of state and develop the virial expansion for the equation of state. Several interesting properties of the q-boson gas are derived and compared with those of the ordinary boson which may point to the physical relevance of such systems.
We propose a new generalized statistical mechanics for anyons based on a simple ansatz that has the correct familiar limiting cases. We derive the anyon equation of state from the grand partition function. We develop the virial expansion and obtain all the virial coefficients. Furthermore, we demonstrate how thermodynamic quantities such as the molar specific heat can readily be calculated. We discuss the properties of semions and also demonstrate that ideal non-relativistic anyons do not exhibit finite temperature condensation.
It is known from the early work of May in 1964 that ideal Bose gas do not exhibit condensation phenomenon in two dimensions. On the other hand, it is also known that the thermostatistics arising from q-deformed oscillator algebra has no connection with the spatial dimensions of the system. Our recent work concerns the study of important thermodynamic functions such as the entropy, occupation number, internal energy and specific heat in ordinary three spatial dimensions, where we established that such thermostatistics is developed by consistently replacing the ordinary thermodynamic derivatives by the Jackson derivatives. The thermostatistics of q-deformed bosons and fermions in two spatial dimensions is an unresolved question that is the subject of this investigation. We study the principal thermodynamic functions of both bosons and fermions in the two-dimensional q-deformed formalism and we find that, different from the standard case, the specific heat of q-boson and q-fermion ideal gas, at fixed temperature and number of particles, are no longer identical.
It is known from the early work of May in 1964 that ideal Bose gas do not exhibit condensation phenomenon in two dimensions. On the other hand, it is also known that the thermostatistics arising from q-deformed oscillator algebra has no connection with the spatial dimensions of the system. Our recent work concerns the study of important thermodynamic functions such as the entropy, occupation number, internal energy and specific heat in ordinary three spatial dimensions, where we established that such thermostatistics is developed by consistently replacing the ordinary thermodynamic derivatives by the Jackson derivatives. The thermostatistics of q-deformed bosons and fermions in two spatial dimensions is an unresolved question that is the subject of this investigation. We study the principal thermodynamic functions of both bosons and fermions in the two-dimensional q-deformed formalism and we find that, different from the standard case, the specific heat of q-boson and q-fermion ideal gas, at fixed temperature and number of particles, are no longer identical.
In the study of many-particle systems both the interaction of particles can be essential and such feature as their internal (composite) structure. To describe these aspects, the theory of deformed oscillators is very efficient. Viewing the particles as p, q-deformed bosons, in the corresponding p, q-Bose gas model we obtain in explicit form virial expansion along with the 2nd to 5th virial coefficients. The obtained virial coefficients depend on the deformation parameters p, q in the form symmetric under p ↔ q, and at p → 1, q → 1 turn into those known for usual bosons. Besides real parameters, we analyze the case of complex mutually conjugate p and q and find interesting implications. Also, the critical temperature is derived (for the p, q-Bose gas) and compared with the Tc of standard case of bosons condensation. Similar results are presented for the deformed Bose gas model of the Tamm–Dancoff (TD) type.
The equilibrium and quasi-equilibrium properties of a system of interacting bosons are studied from a microscopic point of view. For equilibrium, the model of Bogolyubov is generalized to finite temperature by using the grand partition function. The thermodynamic properties and the pair-correlation function are calculated. The statistical mechanics for moving systems is then developed and applied to the problem of a rotating fluid. For quasi-equilibrium, general transport equations are derived from first principles, independent of statistics and model. For the Bogolyubov model, the familiar two-fluid hydrodynamics is then derived, leading to the phenomena of first and second sound.
The method developed in the previous paper for the treatment of the quantum-mechanical NNN-body hard-sphere problem is applied to a calculation of the grand partition function of an imperfect Bose gas with hard-sphere interactions. The grand partition function is calculated to second order in an expansion in powers of $\frac{a}{\ensuremath{\lambda}}$, where aaa is the hard-sphere diameter and $\ensuremath{\lambda}$ the thermal wavelength. The approximate equation of state for the gas phase is thereby obtained by calculating all the virial coefficients to order ${(\frac{a}{\ensuremath{\lambda}})}^{2}$.The first-order energy levels obtained in the previous paper embody some interesting physical properties. A fictitious system with exactly such energy levels is considered. The partition function for such a system can be calculated exactly and the exact equation of state obtained. It is shown that there is a phase transition, which more closely resembles an ordinary gas-liquid transition than the Bose-Einstein condensation.