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Physical Review

Statistical Mechanics for the Nonideal Bose Gas

A. E. Glassgold, Allan N. Kaufman, Kenneth Watson

Published Nov 1, 1960• 52 citations
Publisher

Abstract

The equilibrium and quasi-equilibrium properties of a system of interacting bosons are studied from a microscopic point of view. For equilibrium, the model of Bogolyubov is generalized to finite temperature by using the grand partition function. The thermodynamic properties and the pair-correlation function are calculated. The statistical mechanics for moving systems is then developed and applied to the problem of a rotating fluid. For quasi-equilibrium, general transport equations are derived from first principles, independent of statistics and model. For the Bogolyubov model, the familiar two-fluid hydrodynamics is then derived, leading to the phenomena of first and second sound.

DOI
10.1103/physrev.120.660

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The equilibrium and quasi-equilibrium properties of a system of interacting bosons are studied from a microscopic point of view. For equilibrium, the model of Bogolyubov is generalized to finite temperature by using the grand partition function. The thermodynamic properties and the pair-correlation function are calculated. The statistical mechanics for moving systems is then developed and applied to the problem of a rotating fluid. For quasi-equilibrium, general transport equations are derived from first principles, independent of statistics and model. For the Bogolyubov model, the familiar two-fluid hydrodynamics is then derived, leading to the phenomena of first and second sound.
We re-examine the way in which Bogoliubov's theory of a dilute Bose gas at T=0T=0T=0 has been extended to describe the statistical mechanics of interacting bosons at finite temperature. We show explicitly that the field-theoretic calculation of the grand partition function in this formulation amounts to a canonical trace over the eigenfunctions of the Bogoliubov Hamiltonian at fixed total number of bosons NNN, and that the additional trace over NNN that is required in the grand-canonical formalism is never carried out. This implies that what usually passes as the grand-canonical treatment of the Bogoliubov Hamiltonian is not quite grand-canonical, and is in fact a canonical one. We also show that the discontinuity in the condensate density predicted by previous formulations of this theory as the temperature TTT goes past the critical transition temperature TcT_cTc​ is a direct consequence of an inappropriate generalization of the Bogoliubov prescription to finite temperatures, and that this discontinuity disappears when this prescription is either used as a zero temperature approximation or avoided altogether. Armed with the above findings, we reformulate the statistical mechanics of interacting bosons in the canonical ensemble and derive the thermodynamics of the system. We then show how the canonical treatment can be used to setup a truly grand-canonical description of the statistical mechanics of a weakly interacting Bose gas where the average number of bosons in the system varies with temperature, unlike existing formulations where the total number of bosons NNN is taken to be a constant that does not depend on TTT. Consequences on the physics of interacting bosons are briefly discussed.
Based on a recent study of the statistical mechanical properties of the q-modified boson oscillators, we develop the statistical mechanics of the q-modified boson gas, in particular the Grand Partition Function. We derive the various thermodynamic functions for the q-boson gas including the entropy, pressure and specific heat. We demonstrate that the gas exhibits a phase transition analogous to ordinary bose condensation. We derive the equation of state and develop the virial expansion for the equation of state. Several interesting properties of the q-boson gas are derived and compared with those of the ordinary boson which may point to the physical relevance of such systems.
We analyze the equilibrium properties of a weakly interacting, trapped quasi-one-dimensional Bose gas at finite temperatures and compare different theoretical approaches. We focus in particular on two stochastic theories: a number-conserving Bogoliubov (NCB) approach and a stochastic Gross-Pitaevskii equation (SGPE) that have been extensively used in numerical simulations. Equilibrium properties like density profiles, correlation functions, and the condensate statistics are compared to predictions based upon a number of alternative theories. We find that due to thermal phase fluctuations, and the corresponding condensate depletion, the NCB approach loses its validity at relatively low temperatures. This can be attributed to the change in the Bogoliubov spectrum, as the condensate gets thermally depleted, and to large fluctuations beyond perturbation theory. Although the two stochastic theories are built on different thermodynamic ensembles (NCB, canonical; SGPE, grand-canonical), they yield the correct condensate statistics in a large Bose-Einstein condensate (BEC) (strong enough particle interactions). For smaller systems, the SGPE results are prone to anomalously large number fluctuations, well known for the grand-canonical, ideal Bose gas. Based on the comparison of the above theories to the modified Popov approach, we propose a simple procedure for approximately extracting the Penrose-Onsager condensate from first- and second-order correlation functions that is both computationally convenient and of potential use to experimentalists. This also clarifies the link between condensate and quasicondensate in the Popov theory of low-dimensional systems.
We derive coupled equations of motion for the condensate (superfluid) and noncondensate (normal fluid) degrees of freedom in a trapped Bose gas at finite temperatures. Our results are based on the Hartree-Fock-Popov approximation for the time-dependent condensate wave function, and thermodynamic local equilibrium for the noncondensate atoms. In the special case of a uniform weakly interacting gas, our hydrodynamic equations are shown to be consistent with the two-fluid equations of Landau. The collective modes in a parabolically trapped Bose gas include the analog of the out-of-phase second-sound mode in superfluid 4He{}^{4}\mathrm{He}4He.