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ISRN Condensed Matter Physics

Factorization of the -Electron Wave Function in the Kondo Ground State

Gerd Bergmann

Published Oct 17, 2012• 0 citations
Publisher

Abstract

The multielectron wave function of an interacting electron system depends on the size of the system, that is, the number of electrons. Here the question investigated is how the wave function changes for a symmetric Friedel-Anderson impurity when the volume is doubled. It turns out that for sufficiently large volume (when the level spacing is smaller than the resonance width) the change in the wave function can be expressed in terms of a universal single-electron state centered at the Fermi level. This electron state is independent of the number of electrons and independent of the parameters of the Friedel-Anderson impurity. It is even the same universal state for a Kondo impurity and a symmetric Friedel impurity independent of any parameter. The only requirement is that the impurity has a resonance exactly at the Fermi level and that the level spacing is smaller than the resonance width. This result clarifies recent fidelity calculations.

DOI
10.5402/2012/391813

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The multielectron wave function of an interacting electron system depends on the size of the system, that is, the number of electrons. Here the question investigated is how the wave function changes for a symmetric Friedel-Anderson impurity when the volume is doubled. It turns out that for sufficiently large volume (when the level spacing is smaller than the resonance width) the change in the wave function can be expressed in terms of a universal single-electron state centered at the Fermi level. This electron state is independent of the number of electrons and independent of the parameters of the Friedel-Anderson impurity. It is even the same universal state for a Kondo impurity and a symmetric Friedel impurity independent of any parameter. The only requirement is that the impurity has a resonance exactly at the Fermi level and that the level spacing is smaller than the resonance width. This result clarifies recent fidelity calculations.
The multi-electron wave function of an interacting electron system depends on the size of the system, i.e. the number of electrons. Here the question investigated is how the wave function changes for a symmetric Friedel-Anderson impurity when the volume is doubled. It turns out that for sufficiently large volume (when the level spacing is smaller than the resonance width) the change in the wave function can be expressed in terms of a universal single-electron state |q> centered at the Fermi level. This electron state is independent of the number of electrons and independent of the parameters of the Friedel-Anderson impurity. It is even the same universal state for a Kondo impurity and a symmetric Friedel impurity independent of any parameter. The only requirement is that the impurity has a resonance exactly at the Fermi level and that the level spacing is smaller than the resonance width. This result clarifies recent fidelity calculations.
We generalize Nozi\`eres' Fermi-liquid theory for the low-energy behavior of the Kondo model to that of the single-impurity Anderson model. In addition to the electrons' phase shift at the Fermi energy, the low-energy Fermi-liquid theory is characterized by four Fermi-liquid parameters: the two given by Nozi\`eres that enter to first order in the excitation energy, and two additional ones that enter to second order and are needed away from particle-hole symmetry. We express all four parameters in terms of zero-temperature physical observables, namely the local charge and spin susceptibilities and their derivatives with respect to the local level position. We determine these in terms of the bare parameters of the Anderson model using Bethe ansatz and numerical renormalization group (NRG) calculations. Our low-energy Fermi-liquid theory applies throughout the crossover from the strong-coupling Kondo regime via the mixed-valence regime to the empty-orbital regime. From the Fermi-liquid theory, we determine the conductance through a quantum dot symmetrically coupled to two leads in the regime of small magnetic field, low temperature, and small bias voltage, and compute the coefficients of the $\ensuremath{\sim}{B}^{2}, \ensuremath{\sim}{T}^{2}$, and $\ensuremath{\sim}{V}^{2}$ terms exactly in terms of the Fermi-liquid parameters. The coefficients of T2,V2{T}^{2}, {V}^{2}T2,V2, and B2{B}^{2}B2 are found to change sign during the Kondo to empty-orbital crossover. The crossover becomes universal in the limit that the local interaction is much larger than the level width. For completeness, we also compute the shot noise and discuss the resulting Fano factor.
The quenching of degenerate impurity states in metals generally induces a long-range correlated quantum state known as the Kondo screening cloud. While a macroscopic number of particles clearly take part in forming this extended structure, assessing the number of truly entangled degrees of freedom requires a careful analysis of the relevant many-body wave function. For this purpose, we examine the natural single-particle orbitals that are eigenstates of the single-particle density (correlation) matrix for the ground state of two quantum impurity problems: the interacting resonant level model (IRLM) and the single impurity Anderson model (SIAM). As a simple and general probe for few-body versus many-body character we consider the rate of exponential decay of the correlation matrix eigenvalues towards inactive (fully empty or filled) orbitals. We find that this rate remains large in the physically most relevant region of parameter space, implying a few-body character. Genuine many-body correlations emerge only when the Kondo temperature becomes exponentially small, for instance near a quantum critical point. In addition, we demonstrate that a simple numerical diagonalization of the few-body problem restricted to the Fock space of the most correlated orbitals converges exponentially fast with respect to the number of orbitals, to the true ground state of the IRLM. We also show that finite-size effects drastically affect the correlation spectrum, shedding light on an apparent paradox arising from previous studies on short chains.
It is well known that the ground states of a Fermi liquid with and without a single Kondo impurity have an overlap that decays as a power law of the system size, expressing the Anderson orthogonality catastrophe. Ground states with two different values of the Kondo couplings have, however, a finite overlap in the thermodynamic limit. This overlap, which plays an important role in quantum quenches for impurity systems, is a universal function of the ratio of the corresponding Kondo temperatures, which is not accessible using perturbation theory or the Bethe ansatz. Using a strategy based on the integrable structure of the corresponding quantum field theory, we propose an exact formula for this overlap, which we check against extensive density matrix renormalization group calculations.
The symmetric Anderson model for a single impurity coupled to two leads is studied at strong interaction using the GW approximation within the $\ensuremath{\sigma}G\ensuremath{\sigma}W$ formalism. We find that the low-energy properties show universal scaling behavior in the asymptotic regime. While the GW scaling functions are similar in form to the scaling functions known from the numerically exact solution, they are characterized by a different parameter value indicating that GW fails to describe correctly spin correlations between the impurity and lead electrons. We also compare the GW and exact Kondo scales for a broad range of the interaction strength. In contrast to the exponential behavior shown by the exact solution, the GW Kondo scale depends algebraically on the interaction strength.
The system of several (N)(N)(N) quantum dots coupled in parallel to the same single-mode conduction channel can be modeled as a single-channel NNN-impurity Anderson model. Using the generalized Schrieffer-Wolff transformation we show that near the particle-hole symmetric point, the effective Hamiltonian in the local moment regime is the NNN-impurity S=1∕2S=1∕2S=1∕2 Kondo model. The conduction-band-mediated RKKY exchange interaction between the dots is ferromagnetic and at intermediate temperatures locks the moments into a maximal spin S=N∕2S=N∕2S=N∕2 ground state. We provide an analytical estimate for the RKKY interaction. At low temperatures the spin is partially screened by the conduction electrons to $N∕2\ensuremath{-}1∕2$ due to the Kondo effect. By comparing accurate numerical renormalization group results for magnetic susceptibility of the NNN-impurity Anderson model to the exact Bethe ansatz results of a S=N∕2S=N∕2S=N∕2 SU(2) Kondo system we show that at low-temperature the quantum dots can be described by the effective S=N∕2S=N∕2S=N∕2 Kondo model. Moreover, the Kondo temperature is independent of the number of impurities NNN. We demonstrate the robustness of the spin N∕2N∕2N∕2 ground state as well as of the associated S=N∕2S=N∕2S=N∕2 Kondo effect by studying the stability of the system with respect to various experimentally relevant perturbations. We finally explore various quantum phase transitions driven by these perturbations.