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arXiv:1409.3451 · Physical Review B

Fermi-liquid theory for the single-impurity Anderson model

Christophe Mora, Cătălin Paşcu Moca, Jan von Delft, Gergely Zaránd

Published Aug 10, 2015• 54 citations
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Abstract

We generalize Nozi\`eres' Fermi-liquid theory for the low-energy behavior of the Kondo model to that of the single-impurity Anderson model. In addition to the electrons' phase shift at the Fermi energy, the low-energy Fermi-liquid theory is characterized by four Fermi-liquid parameters: the two given by Nozi\`eres that enter to first order in the excitation energy, and two additional ones that enter to second order and are needed away from particle-hole symmetry. We express all four parameters in terms of zero-temperature physical observables, namely the local charge and spin susceptibilities and their derivatives with respect to the local level position. We determine these in terms of the bare parameters of the Anderson model using Bethe ansatz and numerical renormalization group (NRG) calculations. Our low-energy Fermi-liquid theory applies throughout the crossover from the strong-coupling Kondo regime via the mixed-valence regime to the empty-orbital regime. From the Fermi-liquid theory, we determine the conductance through a quantum dot symmetrically coupled to two leads in the regime of small magnetic field, low temperature, and small bias voltage, and compute the coefficients of the $\ensuremath{\sim}{B}^{2}, \ensuremath{\sim}{T}^{2}$, and $\ensuremath{\sim}{V}^{2}$ terms exactly in terms of the Fermi-liquid parameters. The coefficients of ${T}^{2}, {V}^{2}$, and ${B}^{2}$ are found to change sign during the Kondo to empty-orbital crossover. The crossover becomes universal in the limit that the local interaction is much larger than the level width. For completeness, we also compute the shot noise and discuss the resulting Fano factor.

DOI
10.1103/physrevb.92.075120

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We generalize Nozi`eres' Fermi-liquid theory for the low-energy behavior of the Kondo model to that of the single-impurity Anderson model. In addition to the electrons' phase shift at the Fermi energy, the low-energy Fermi-liquid theory is characterized by four Fermi-liquid parameters: the two given by Nozi`eres that enter to first order in the excitation energy, and two additional ones that enter to second order and are needed away from particle-hole symmetry. We express all four parameters in terms of zero-temperature physical observables, namely the local charge and spin susceptibilities and their derivatives with respect to the local level position. We determine these in terms of the bare parameters of the Anderson model using Bethe ansatz and numerical renormalization group (NRG) calculations. Our low-energy Fermi-liquid theory applies throughout the crossover from the strong-coupling Kondo regime via the mixed-valence regime to the empty-orbital regime. From the Fermi-liquid theory, we determine the conductance through a quantum dot symmetrically coupled to two leads in the regime of small magnetic field, low temperature, and small bias voltage, and compute the coefficients of the \ensuremath∼B2,\ensuremath∼T2\ensuremath{\sim}{B}^{2}, \ensuremath{\sim}{T}^{2}\ensuremath∼B2,\ensuremath∼T2, and \ensuremath∼V2\ensuremath{\sim}{V}^{2}\ensuremath∼V2 terms exactly in terms of the Fermi-liquid parameters. The coefficients of T2,V2{T}^{2}, {V}^{2}T2,V2, and B2{B}^{2}B2 are found to change sign during the Kondo to empty-orbital crossover. The crossover becomes universal in the limit that the local interaction is much larger than the level width. For completeness, we also compute the shot noise and discuss the resulting Fano factor.
This paper is a corrected version of Phys. Rev. B 95, 165404 (2017), which we have retracted because it contained a trivial but fatal sign error that lead to incorrect conclusions. We extend a recently developed Fermi liquid (FL) theory for the asymmetric single-impurity Anderson model [C. Mora et al., Phys. Rev. B 92, 075120 (2015)] to the case of an arbitrary local magnetic field. To describe the system's low-lying quasiparticle excitations for arbitrary values of the bare Hamiltonian's model parameters, we construct an effective low-energy FL Hamiltonian whose FL parameters are expressed in terms of the local level's spin-dependent ground-state occupations and their derivatives with respect to level energy and local magnetic field. These quantities are calculable with excellent accuracy from the Bethe ansatz solution of the Anderson model. Applying this effective model to a quantum dot in a nonequilibrium setting, we obtain exact results for the curvature of the spectral function, cA{c}_{A}cA​, describing its leading $\ensuremath{\sim}{\ensuremath{\varepsilon}}^{2}$ term, and the transport coefficients cV{c}_{V}cV​ and cT{c}_{T}cT​, describing the leading $\ensuremath{\sim}{V}^{2}$ and $\ensuremath{\sim}{T}^{2}$ terms in the nonlinear differential conductance. A sign change in cA{c}_{A}cA​ or cV{c}_{V}cV​ is indicative of a change from a local maximum to a local minimum in the spectral function or nonlinear conductance, respectively, as is expected to occur when an increasing magnetic field causes the Kondo resonance to split into two subpeaks. We find that the fields BA{B}_{A}BA​, BT{B}_{T}BT​, and BV{B}_{V}BV​ at which cA{c}_{A}cA​, cT{c}_{T}cT​, and cV{c}_{V}cV​ change sign, respectively, are all of order TK{T}_{K}TK​, as expected, with BA=BT=BV=0.75073TK{B}_{A}={B}_{T}={B}_{V}=0.75073{T}_{K}BA​=BT​=BV​=0.75073TK​ in the Kondo limit.
We study the nonequilibrium transport properties of fully (exactly) screened Kondo quantum dots subject to a finite bias voltage or a finite temperature. First, we calculate the Fermi-liquid coefficients of the conductance for models with arbitrary spin, i.e., its leading behavior for small bias voltages or temperatures. Second, we determine the low-temperature behavior of the static susceptibility from the exactly known Bethe ansatz results for the magnetization. Third, we study the crossover from strong to weak coupling in the spin-1/2 and the spin-1 models coupled to one or two screening channels, respectively. Using a real-time renormalization group method we calculate the static and dynamical spin-spin correlation functions for the spin-1/2 model as well as the linear and differential conductance and the static susceptibility for the spin-1 model. We define various Kondo scales and discuss their relations. We assess the validity of the renormalization-group treatment by comparing with known results for the temperature dependence of the linear conductance and static susceptibility as well as the Fermi-liquid behavior at low energies.
We study the three-body Fermi liquid effects in the SU(NNN) Anderson impurity model within the strong interaction limit $U\ensuremath{\rightarrow}\ensuremath{\infty}$, where the occupation number Nd{N}_{d}^{}Nd​ of the impurity levels varies over the range of 0<Nd<10<{N}_{d}^{}<10<Nd​<1. The three-body correlations arise among the impurity electrons when the electron-hole symmetry, the time-reversal symmetry, or both are broken by external fields or potentials. They play a key role in low-energy transport, particularly in the next-to-leading-order terms of power expansion with respect to temperature TTT and bias voltage eVeVeV. Using the numerical renormalization group approach, we calculate the differential conductance and nonlinear current noise through quantum dots, as well as the thermal conductivity of both quantum dots and magnetic alloys. Specifically, we focus on the SU(2) and SU(4) cases, demonstrating how the three-body correlations evolve in the strong interaction limit across the 1/N1/N1/N-filling Kondo regime at ${N}_{d}^{}\ensuremath{\simeq}1.0$ and the valence fluctuation regime where the occupation number Nd{N}_{d}^{}Nd​ varies rapidly with the position ${\ensuremath{\epsilon}}_{d}^{}$ of the impurity levels. We also show that the three-body correlations strongly couple with asymmetries in the tunnel couplings between quantum dots and reservoirs. For N=4N=4N=4, this coupling significantly affects the order (eV)3{(eV)}^{3}(eV)3 nonlinear current through the quarter-filling Kondo state, where the electron-hole symmetry is broken. In particular, in the $U\ensuremath{\rightarrow}\ensuremath{\infty}$ limit, the expansion coefficients exhibit clear plateau structures associated with the Kondo effect at ${N}_{d}^{}\ensuremath{\simeq}1.0$. Our formulation and analysis pave the way for deducing the three-body correlations from the low-energy experiments on the next-to-leading-order transport.
We present a comprehensive Fermi liquid description for thermoelectric transport and current noise, applicable to multilevel quantum dots (QD) and magnetic alloys (MA) without electron-hole or time-reversal symmetry. Our formulation for the low-energy transport is based on an Anderson model with NNN discrete impurity levels, and is asymptotically exact at low energies, up to the next-leading order terms in power expansions with respect to temperature TTT and bias voltage eVeVeV. The expansion coefficients can be expressed in terms of the Fermi liquid parameters, which include the three-body correlation functions defined with respect to the equilibrium ground state in addition to the linear susceptibilities and the occupation number Nd{N}_{d}^{}Nd​ of impurity electrons. We apply this formulation to the SU(N)\mathrm{SU}(N)SU(N) symmetric QD and MA, and calculate the correlation functions for N=4N=4N=4 and 6, using numerical renormalization group approach. The three-body correlations are shown to be determined by a single parameter over a wide range of electron fillings $1\ensuremath{\lesssim}{N}_{d}^{}\ensuremath{\lesssim}N\ensuremath{-}1$ for strong Coulomb interactions UUU, and they also exhibit the plateau structures due to the SU(N)\mathrm{SU}(N)SU(N) Kondo effects at integer values of Nd{N}_{d}^{}Nd​. We find that the Lorenz number $L=\ensuremath{\kappa}/(T\ensuremath{\sigma})$ for QD and MA, defined as the ratio of the thermal conductivity $\ensuremath{\kappa}$ to the electrical conductivity $\ensuremath{\sigma}$, deviates from the universal Wiedemann-Franz value ${\ensuremath{\pi}}^{2}/(3{e}^{2})$ as the temperature increases from T=0T=0T=0, showing the T2{T}^{2}T2 dependence, the coefficient for which depends on the three-body correlations away from half filling. Furthermore, we find that the current noise for the SU(4) quantum dots and that for SU(6) show a pronounced difference at the quarter Nd/N=1/4{N}_{d}^{}/N=1/4Nd​/N=1/4 and 3/43/43/4 fillings. In particular, the linear noise for N=4N=4N=4 exhibits a flat peak while the peak for N=6N=6N=6 shows a round shape, reflecting the fact that, at these filling points, the SU(N)\mathrm{SU}(N)SU(N) Kondo effects occur for $N\ensuremath{\equiv}0$ (mod 4), whereas the intermediate-valence fluctuations occur for $N\ensuremath{\equiv}2$ (mod 4). We also demonstrate the role of three-body correlations on the nonlinear current noise and the other transport coefficients.
Using different techniques, and Fermi-liquid relationships, we calculate the variation with the applied magnetic field (up to second order) of the zero-temperature equilibrium conductance through a quantum dot described by the impurity Anderson model. We focus on the strong-coupling limit $U\ensuremath{\gg}\mathrm{\ensuremath{\Delta}}$, where UUU is the Coulomb repulsion and $\mathrm{\ensuremath{\Delta}}$ is half the resonant-level width, and consider several values of the dot level energy Ed{E}_{d}Ed​, ranging from the Kondo regime ${\ensuremath{\epsilon}}_{F}\ensuremath{-}{E}_{d}\ensuremath{\gg}\mathrm{\ensuremath{\Delta}}$ to the intermediate-valence regime ${\ensuremath{\epsilon}}_{F}\ensuremath{-}{E}_{d}\ensuremath{\sim}\mathrm{\ensuremath{\Delta}}$, where ${\ensuremath{\epsilon}}_{F}$ is the Fermi energy. We have mainly used the density-matrix renormalization group (DMRG) and the numerical renormalization group (NRG) combined with renormalized perturbation theory (RPT). Results for the dot occupancy and magnetic susceptibility from the DMRG and NRG+RPT\mathrm{NRG}+\mathrm{RPT}NRG+RPT are compared with the corresponding Bethe ansatz results for $U\ensuremath{\rightarrow}\ensuremath{\infty}$, showing an excellent agreement once Ed{E}_{d}Ed​ is renormalized by a constant Haldane shift. For $U<3\mathrm{\ensuremath{\Delta}}$ a simple perturbative approach in UUU agrees very well with the other methods. The conductance decreases with the applied magnetic field for dot occupancies ${n}_{d}\ensuremath{\sim}1$ and increases for ${n}_{d}\ensuremath{\sim}0.5$ or ${n}_{d}\ensuremath{\sim}1.5$ regardless of the value of UUU. We also relate the energy scale for the magnetic-field dependence of the conductance with the width of the low-energy peak in the spectral density of the dot.
We study the higher-order Fermi-liquid relations of Kondo systems for arbitrary impurity-electron fillings, extending the many-body quantum theoretical approach of Yamada and Yosida. It includes, partly, a microscopic clarification of the related achievements based on Nozi\`eres' phenomenological description: Filippone, Moca, von Delft, and Mora [Phys. Rev. B 95, 165404 (2017)]. In our formulation, the Fermi-liquid parameters such as the quasiparticle energy, damping, and transport coefficients are related to each other through the total vertex ${\mathrm{\ensuremath{\Gamma}}}_{\ensuremath{\sigma}{\ensuremath{\sigma}}^{\ensuremath{'}};{\ensuremath{\sigma}}^{\ensuremath{'}}\ensuremath{\sigma}}(\ensuremath{\omega},{\ensuremath{\omega}}^{\ensuremath{'}};{\ensuremath{\omega}}^{\ensuremath{'}},\ensuremath{\omega})$, which may be regarded as a generalized Landau quasiparticle interaction. We obtain exactly this function up to linear order with respect to the frequencies $\ensuremath{\omega}$ and ${\ensuremath{\omega}}^{\ensuremath{'}}$ using the antisymmetry and analytic properties. The coefficients acquire additional contributions of three-body fluctuations away from half filling through the nonlinear susceptibilities. We also apply the formulation to nonequilibrium transport through a quantum dot, and clarify how the zero-bias peak evolves in a magnetic field.