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Journal of Physics B Atomic and Molecular Physics

Measured lifetimes in zinc I and zinc II using the electron-photon delayed-coincidence technique

David A. Shaw, GEORGE C. KING, A Adams

Published Jan 28, 1978• 12 citations
Publisher

Abstract

The electron-photon delayed-coincidence technique has been used to measure the lifetimes of excited states in neutral and singly ionised natural zinc. These states, with their lifetimes, are Zn I: 5 1 S (41.1+or-0.4) ns, 4 1 D (21.1+or-0.4) ns, 6 1 S (103+or-3) ns, 5 1 D (89+or-4) ns; Zn II: 4p 2 P (3.2+or-0.2) ns.
DOI
10.1088/0022-3700/11/2/009

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The electron-photon delayed coincidence technique has been used to measure precisely the lifetime for the 4p 1 P 0 state in calcium. The lifetime of this state was obtained by measuring the time correlation spectrum between the inelastically scattered electrons and the corresponding de-excitation photons. By using the least-squares fitting program to fit Gale's equation to the data points, a value of (4.15±0.17) ns was obtained. The result was compared to some of the earlier experimental measurements.
We have developed an interesting and widely applicable technique for measuring lifetimes of low-lying levels of neutral atoms and their first few ionization states. The cascade-photon-coincidence method has been extended by using a light source consisting of excited atoms sputtered from a solid by 10-keV argon ions. We have measured the lifetimes of the 4p2{4\mathrm{p}}^{2}4p2P3/2o{\mathrm{P}}_{3\mathrm{/}2}^{\mathrm{o}}P3/2o​ state of Ca II, the 6p2{6\mathrm{p}}^{2}6p2P3/2o{\mathrm{P}}_{3\mathrm{/}2}^{\mathrm{o}}P3/2o​ state of Ba II, and the 4p2{4\mathrm{p}}^{2}4p2P3/2o{\mathrm{P}}_{3\mathrm{/}2}^{\mathrm{o}}P3/2o​ state of Al III. These measurements are in good agreement with earlier work.
A direct measurement of the natural lifetime for the (3p54s3{p}^{5}4s3p54s) 3P1^{3}P_{1}3P1​ state of argon has been made using a modified delayed-coincidence method. Argon atoms are repetitively excited by pulses of electrons. For each pulse, the decaying light signal is sampled for a time $\ensuremath{\Delta}t$ at some delay time t1{t}_{1}t1​ after the excitation is terminated. The exponential decay is then reconstructed as the delay time is changed. Collision effects are not important in the pressure region (5.0\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}6}$-2.0\ifmmode\times\else\texttimes\fi{}${10}^{\ensuremath{-}4}$ Torr) of the experiment and the effects due to cascading are eliminated by keeping the energy of the bombarding electrons low enough so that excitation of the 3p54p3{p}^{5}4p3p54p levels is negligible. The measured lifetime is dependent upon the argon pressure, and this effect is attributed to resonance trapping; a value of 21\ifmmode\pm\else\textpm\fi{}2 nsec is obtained for the natural lifetime by using the existing theories of resonance trapping to extrapolate the data to zero pressure.
A delayed-coincidence technique has been used to measure the lifetime of the 5d6p1F35d6p^{1}F_{3}5d6p1F3​ state of atomic barium. An intermediate, 6s5d1D26s5d^{1}D_{2}6s5d1D2​ metastable state of barium atoms in an atomic beam was populated by electron bombardment, and a pulsed cw laser was employed to excite atoms from the metastable state to the 5d6p1F35d6p^{1}F_{3}5d6p1F3​ state. A time-to-amplitude convertor was used to measure the time distribution of the fluorescent light. The value obtained for the lifetime was (44.5\ifmmode\pm\else\textpm\fi{}1.8) nsec.