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Low Temperature Physics

Effect of the dipole–dipole interaction on the low-temperature magnetism of linear spin chains

Alexander V. Zhuravlev, I. M. Krygin

Published Mar 1, 2010• 0 citations
Publisher

Abstract

The magnetic dipole–dipole interaction in a linear chain of spins S=1∕2 with uniaxial exchange anisotropy gives raise to evolution of the system of energy levels. As the magnetic dipole interaction increases, the fastest decrease of the energy of the system is observed for a level with the maximum modulus of the spin of the system. For sufficiently large ratio of the dipole–dipole contribution to the exchange a transition occurs between the spin-gap states—antiferromagnetic and ferromagnetic. An extremely sharp change of the mean-square spin of the system at low temperatures (T<10−3J∕k) followed by a “plateau” in the temperature dependence is characteristic for a narrow neighborhood of the point at which the type of ground state changes.

DOI
10.1063/1.3331455

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The magnetic dipole–dipole interaction in a linear chain of spins S=1∕2 with uniaxial exchange anisotropy gives raise to evolution of the system of energy levels. As the magnetic dipole interaction increases, the fastest decrease of the energy of the system is observed for a level with the maximum modulus of the spin of the system. For sufficiently large ratio of the dipole–dipole contribution to the exchange a transition occurs between the spin-gap states—antiferromagnetic and ferromagnetic. An extremely sharp change of the mean-square spin of the system at low temperatures (T<10−3J∕k) followed by a “plateau” in the temperature dependence is characteristic for a narrow neighborhood of the point at which the type of ground state changes.
We study the breakdown of the magnetization plateau at the magnetization M = M S /3 ( M S is the saturation magnetization) of the S = 1/2 anisotropic spin chain with ferromagnetic-ferromagnetic-antiferromagnetic interactions. We consider the model with the isotropic ferromagnetic (trimer) coupling J F , and anisotropic antiferromagnetic coupling ( J x = J y = J AF and J z = J AF ). For the limit of large J F / J AF , the model is equivalent to the S = 3/2 XXZ chain with the exchange anisotropy . There is a phase transition between the plateau (small- ) and the no-plateau (large- ) regions. This phase transition is of the Berezinskii-Kosterlitz-Thouless type, and we determine the phase boundary from the numerical diagonalization data. For = 1, in particular, the phase transition between the plateau and the no-plateau regions occurs at the point c = 15.4.
We show that the ground state of a system of magnetic dipoles, with no electric charge, is a ferromagnetic quantum Fermi liquid at high densities, driven by the dipolar exchange energy. As in the system of classical point dipoles, the direct dipole energy is zero in this case. With decreasing density, there is a transition to an antiferromagnetic lattice state. An addition of short range hard core repulsive potential will arrest the infinite density collapse of the ferromagnetic state, and possible melting of the low density antiferromagnetic lattice state.
By means of the molecular dynamics simulation on gradual cooling processes, we investigate magnetic properties of classical spin systems only with the magnetic dipole-dipole interaction, which we call dipolar systems. Focusing on their finite-size effect, particularly their boundary geometry dependence, we study two finite dipolar squares cut out from a square lattice with Φ=0Φ=0Φ=0 and π/4π/4π/4, where ΦΦΦ is an angle between the direction of the lattice axis and that of the square boundary. Distinctly different results are obtained in the two dipolar squares. In the Φ=0Φ=0Φ=0 square, the ``from-edge-to-interior freezing'' of spins is observed. Its ground state has a multi-domain structure whose domains consist of the two among infinitely (continuously) degenerated Luttinger-Tisza (LT) ground-state orders on a bulk square lattice, i.e., the two antiferromagnetically aligned ferromagnetic chains (af-FMC) orders directed in parallel to the two lattice axes. In the Φ=π/4Φ=π/4Φ=π/4 square, on the other hand, the freezing starts from the interior of the square, and its ground state is nearly in a single domain with one of the two af-FMC orders. These geometry effects are argued to originate from the anisotropic nature of the dipole-dipole interaction which depends on the relative direction of sites in a real space of the interacting spins.
In this article, spin systems with competing interactions in an external magnetic field are investigated. The Ising model with ferromagnetic short-range forces and long-range antiferromagnetic forces is considered. Long-range forces decrease according to the power law. Long-range interaction is characterized by the rate of decrease with distance and relative intensity. The Metropolis algorithm is used for computer modeling. Two order parameters for ferromagnetic and antiferromagnetic ordering are used. The theory of finite size scaling is used. The transition temperature was defined based on Binder's cumulants for each of the order parameters. The phase diagram for the system is constructed at various values of the long-range interaction parameters. As the temperature decreases, the system can transfer from the paramagnetic phase into the ferromagnetic and antiferromagnetic ones. The type of the low-temperature phase depends on the intensity of long-range forces and does not depend on the rate of decrease of the interaction with distance. There is a boundary value of the intensity of long-range forces, below which the ferromagnetic phase is implemented, and above it is the antiferromagnetic phase. The change in the phase diagram under the influence of an external magnetic field is investigated. In an external magnetic field, the ferromagnetic phase transition becomes spread. The temperature of the antiferromagnetic phase transition in an external field decreases according to the square law. The boundary value of the intensity of long-range forces linearly grows with increasing the intensity of the external magnetic field. An increase in the boundary value in a magnetic field leads to a change in the type of the low-temperature phase. This effect is shown as a phase transition from the antiferromagnetic to the ferromagnetic phase in the external magnetic field. A comparison with the data of real experiments is carried out.
The properties of spin-1/2 antiferromagnetic chains with various types of random exchange coupling are studied via an asymptotically exact decimation renormalization-group transformation, which is a generalization of that introduced by Dasgupta and Ma. Random-singlet phases occur in which each spin is paired with one other spin that may be very far away; more exotic phases also occur. The behavior of typical and mean correlation functions is analyzed and found to be very different, with very small sets of spins dominating the latter at long distances as well as the low-temperature thermodynamics. Some of the phase transitions that occur between antiferromagnetically ordered phases and random singlet or other antiferromagnetic phases are also analyzed. For example, if a small uniaxial anisotropy perturbation is added to a random Heisenberg antiferromagnetic chain, a transition occurs from a random-singlet phase to an Ising antiferromagnetic phase, as the anisotropy changes sign from easy plane to easy axis. The staggered magnetization vanishes at the transition with critical exponent \ensuremath{\beta}=8/(1+ \ensuremath{\surd}7 ). Possible implications for the properties of random quantum magnetic systems in higher dimensions are briefly discussed.
The anisotropic XXZXXZXXZ spin-12\frac{1}{2}21​ Heisenberg chain is studied using renormalization-group theory. The specific heats and nearest-neighbor spin-spin correlations are calculated throughout the entire temperature and anisotropy ranges in both ferromagnetic and antiferromagnetic regions, obtaining a global description and quantitative results. We obtain, for all anisotropies, the antiferromagnetic spin-liquid spin-wave velocity and the Ising-like ferromagnetic excitation spectrum gap, exhibiting the spin-wave to spinon crossover. A number of characteristics of purely quantum nature are found: The in-plane interaction sixsjx+siysjy{s}_{i}^{x}{s}_{j}^{x}+{s}_{i}^{y}{s}_{j}^{y}six​sjx​+siy​sjy​ induces an antiferromagnetic correlation in the out-of-plane siz{s}_{i}^{z}siz​ component, at higher temperatures in the antiferromagnetic XXZXXZXXZ chain, dominantly at low temperatures in the ferromagnetic XXZXXZXXZ chain, and, in-between, at all temperatures in the XYXYXY chain. We find that the converse effect also occurs in the antiferromagnetic XXZXXZXXZ chain: an antiferromagnetic sizsjz{s}_{i}^{z}{s}_{j}^{z}siz​sjz​ interaction induces a correlation in the sixy{s}_{i}^{xy}sixy​ component. As another purely quantum effect, (i) in the antiferromagnet, the value of the specific heat peak is insensitive to anisotropy and the temperature of the specific heat peak decreases from the isotropic (Heisenberg) with introduction of either type (Ising or XYXYXY) of anisotropy; and (ii) in complete contrast, in the ferromagnet, the value and temperature of the specific heat peak increase with either type of anisotropy.