This paper analyzes how the existence of electron spin changes the equation for the probability current density in the quantum-mechanical continuity equation. A spinful electron moving in a potential energy field experiences the spin-orbit interaction, and that additional term in the time-dependent Schrödinger equation places an additional spin-dependent term in the probability current density. Further, making an analogy with classical magnetostatics hints that there may be an additional magnetization current contribution. This contribution seems not to be derivable from a non-relativistic time-dependent Schrödinger equation, but there is a procedure described in the quantum mechanics textbook by Landau and Lifschitz to obtain it. We utilize and extend their procedure to obtain this magnetization term, which also gives a second derivation of the spin-orbit term. We conclude with an evaluation of these terms for the ground state of the hydrogen atom with spin-orbit interaction. The magnetization contribution is generally the larger one, except very near an atomic nucleus.
This paper analyzes how the existence of electron spin changes the equation for the probability current density in the quantum-mechanical continuity equation. A spinful electron moving in a potential energy field experiences the spin-orbit interaction, and that additional term in the time-dependent Schrödinger equation places an additional spin-dependent term in the probability current density. Further, making an analogy with classical magnetostatics hints that there may be an additional magnetization current contribution. This contribution seems not to be derivable from a non-relativistic time-dependent Schrödinger equation, but there is a procedure described in the quantum mechanics textbook by Landau and Lifschitz to obtain it. We utilize and extend their procedure to obtain this magnetization term, which also gives a second derivation of the spin-orbit term. We conclude with an evaluation of these terms for the ground state of the hydrogen atom with spin-orbit interaction. The magnetization contribution is generally the larger one, except very near an atomic nucleus.
Abstract We review the literature on the Pauli equation and its current density, discussing the progression from the original phenomenological version of Pauli to its derivation by Lévy-Leblond from a linearization of the Schrödinger equation. It was established conclusively by Lévy-Leblond’s work that the spin of a spin-1/2 particle such as an electron is non-relativistic in nature, contrary to what was often stated following Dirac’s derivation of a relativistic wave equation, and his subsequent demonstration that Pauli’s spin interaction term appeared in the non-relativistic limit. In this limit, the Gordon decomposition of the associated probability current density was found to contain a spin-dependent term. Such a term does not follow, however, from the usual derivation of the current density from the Pauli equation, although various physically motivated but otherwise ad hoc explanations were put forward to account for it. We comment on the only exception to these of which we are aware implying the spin term in the current was in fact non-relativistic in nature. However, the earlier work of Lévy-Leblond had already shown, with no additional assumptions, that this term was a prominent feature of the current density derived from his equation. Hence, just as with the spin itself, the spin current was non-relativistic, claims to the contrary notwithstanding. We present a somewhat simplified derivation of the Lévy-Leblond equation and its current density, commenting on possibilities for experimental work that might indicate measurable consequences of the spin term in the current density. The presentation is at a level of quantum mechanics, electromagnetic theory, and mathematical methods typical of courses taken by first-year graduate students in physics, assuming some familiarity with Pauli spin matrices and the Dirac equation. Calculations are presented in detail, making the material suitable for use by teachers as supplementary problems for assignments, and development of theoretical concepts peculiar to the Pauli equation and its probability current density.
First, the experimental foundations for the existence of a new dynamical variable, the spin of particles, are presented. The Pauli equation is then derived in detail, two applications are given and the energy levels of a particle with spin in a constant magnetic field are studied. This is the analysis of Landau levels, which can be performed by using the known results on the spectrum of harmonic oscillators. In this chapter we also study in detail the addition of orbital angular momentum and spin, as well as the spin–orbit interaction with the resulting Thomas precession. Stern-Gerlach experiment and electron spin The hypothesis that the electron has an intrinsic magnetic moment and an angular momentum, in short a spin , was first suggested in Uhlenbeck and Goudsmit (1926). They noticed, even before the discovery of quantum mechanics, that a complete description of spectra was not possible unless a magnetic moment and a mechanical moment were ascribed to the electron, and hence the concept of an electron as a point charge was insufficient. First, let us therefore try to understand how a magnetic moment can be associated to an atomic system. For this purpose, consider for simplicity the Bohr model of an hydrogen atom, where the electron moves along a circular orbit and rotates with orbital angular momentum L .
The chapter covers some of the essential aspects of relativistic quantum mechanics. The Klein-Gordon equation and its solution in coulombic fields, how to interpret probability density and probability current derived from the Klein-Gordon equation, derivation of the Dirac equation and its covariant form, probability density and probability current for Dirac equation, positive and negative energy eigenvalues in the case of a free particle, constants of motion for relativistic treatment, presence of spin magnetic moment and spin-orbit interaction energy in the Dirac equation, and the solution of the Dirac equation for central potentials and for the hydrogen atom are presented with elegant mathematical treatment and physical interpretations. A modern and reader friendly approach is adopted for derivation of the Dirac equation, constants of motion, and for the solution of the Dirac equation for central potentials. Solved examples and unsolved exercises relating to fundamental concepts of relativistic quantum mechanics are added towards the end of chapter.
An alternative method of deriving the values of the observables of atomic systems is presented. Rather than using operators and eigenvalues the local variables method uses the continuity equation together with current densities derived from wave functions that are solutions of the Dirac or Pauli equation. The method is applied to atomic hydrogen using the usual language of quantum mechanics rather than that of geometric algebra with which the method is often associated. The picture of the atom that emerges is one in which the electron density as a whole is rotating about a central axis. The results challenge some assumptions of conventional quantum mechanics. Electron spin is shown to be a property of the dynamical motion of the electron and not an intrinsic property of the electron, the ground state of hydrogen is shown to have an orbital angular momentum of ℏ, and excited states are shown to have angular momenta that are different from the eigenvalues of the usual quantum mechanical operators. The uncertainty relations are found not to be applicable to the orthogonal components of the angular momentum. No double electron spin gyromagnetic ratio is required to account for the observed magnetic moments, and the behavior of the atom in a magnetic field is described entirely in kinetic terms.
Simple, but completely general, equations of change are derived for a property, χ†𝒪Ψ of a quantum mechanical system, where χ (r,s,t) and Ψ (r,s,t) are any two wavefunctions satisfying a time-dependent Schrödinger equation with the same Hamiltonian H, and 𝒪 is an arbitrary operator. For a Hamiltonian H0= (2m)−1 p2+V (r) the equations of change of angular momentum density and kinetic energy density are derived. The equations of change are developed for systems having Breit–Pauli type Hamiltonians which involve spin as well as external static electromagnetic fields and relativistic corrections. The velocity operator ṙ is shown to contain a spin-dependent term. The relativistic correction to the kinetic energy (p2)2 term is not consistent with the equation of continuity. An expression is derived for the rate of ’’spin flipping’’ of a hydrogen atom in an external electromagnetic field. Methods are derived for projecting the equations of change onto real three-dimensional space. Natural spin orbitals are useful for describing the equation of continuity in three dimensions; however, they cannot describe the equation of motion or the other equations of change.
We show that the antisymmetric spinor tensor representation of spin-0 relativistic quantum mechanics provides a conserved current with positive definite timelike component, interpretable as probability density. The construction runs in complete analogy to the spin-1/2 case, and provides an analogously natural one-particle Hilbert space description for spin 0. Except for the free particle, the obtained formulation proves to be inequivalent to the one based on the Klein--Gordon equation. The second quantized version may lead to new field theoretical interaction terms for zero-spin particles.