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Cambridge University Press eBooks

Introduction to spin

Giampiero V. M. Esposito, Giuseppe Marmo, Gennaro Miele, George Sudarshan

Published Oct 31, 2014• 0 citations
Publisher

Abstract

First, the experimental foundations for the existence of a new dynamical variable, the spin of particles, are presented. The Pauli equation is then derived in detail, two applications are given and the energy levels of a particle with spin in a constant magnetic field are studied. This is the analysis of Landau levels, which can be performed by using the known results on the spectrum of harmonic oscillators. In this chapter we also study in detail the addition of orbital angular momentum and spin, as well as the spin–orbit interaction with the resulting Thomas precession. Stern-Gerlach experiment and electron spin The hypothesis that the electron has an intrinsic magnetic moment and an angular momentum, in short a spin , was first suggested in Uhlenbeck and Goudsmit (1926). They noticed, even before the discovery of quantum mechanics, that a complete description of spectra was not possible unless a magnetic moment and a mechanical moment were ascribed to the electron, and hence the concept of an electron as a point charge was insufficient. First, let us therefore try to understand how a magnetic moment can be associated to an atomic system. For this purpose, consider for simplicity the Bohr model of an hydrogen atom, where the electron moves along a circular orbit and rotates with orbital angular momentum L .

DOI
10.1017/cbo9781139875950.010

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Angular momentum 1

A.P. French, Edwin F. Taylor

Angular momentum plays a similarly important role in atomic systems, such as an electron subject to the central force provided by the Coulomb field of a nucleus. This chapter introduces the properties of angular momentum, both orbital and spin, in the quantum-mechanical scheme of things. The angular momentum of atomic systems is inseparable from the magnetic properties of atoms. The various permitted values of the quantized angular momentum play a central role in determining the number and variety of possible quantum states in atomic systems. The Stern-Gerlach experiment was deliberately designed to test whether or not the angular momentum of individual neutral atoms is quantized in a magnetic field. As in the development of the Schrodinger equation, classical physics gives some hints of the correct forms of these angular momentum operators. The chapter discusses rough estimate using the Neils Bohr theory and attributing the magnetic moment to the orbital motion of the electron.

Routledge eBooks•May 11, 2018•0 citations
First, the experimental foundations for the existence of a new dynamical variable, the spin of particles, are presented. The Pauli equation is then derived in detail, two applications are given and the energy levels of a particle with spin in a constant magnetic field are studied. This is the analysis of Landau levels, which can be performed by using the known results on the spectrum of harmonic oscillators. In this chapter we also study in detail the addition of orbital angular momentum and spin, as well as the spin–orbit interaction with the resulting Thomas precession. Stern-Gerlach experiment and electron spin The hypothesis that the electron has an intrinsic magnetic moment and an angular momentum, in short a spin , was first suggested in Uhlenbeck and Goudsmit (1926). They noticed, even before the discovery of quantum mechanics, that a complete description of spectra was not possible unless a magnetic moment and a mechanical moment were ascribed to the electron, and hence the concept of an electron as a point charge was insufficient. First, let us therefore try to understand how a magnetic moment can be associated to an atomic system. For this purpose, consider for simplicity the Bohr model of an hydrogen atom, where the electron moves along a circular orbit and rotates with orbital angular momentum L .
Abstract In this chapter we discuss the intrinsic angular momentum called spin. Starting from the magnetic dipole moment related to orbital angular momentum, we focus on the hydrogen atom and consider the effect of an external magnetic field, resulting in Larmor precession and Zeeman splitting. We then turn to the discovery of spin in the Stern-Gerlach experiment. After providing a mathematical description of spin-1/2 systems in terms of two-component spinors and Pauli matrices, we illustrate projective measurements for the example of spin. The relationship between the Lie groups SU(2) and SO(3) is discussed in the context of the transformation of spinors under rotations. We analyse how the presence of spin alters the description of the hydrogen atom. Discussing the addition of angular momenta and the Pauli exclusion principle leads us to the structure of electronic orbitals. Finally, we discuss the occupation of electronic energy levels in heavier nuclei
In the introductory remarks to Chapter 5 mention was made of the 1925 proposal of Uhlenbeck and Goudsmit that to an electron there should be assigned an intrinsic angular momentum or spin S = (S x , S y , S z )—this in addition to its quantum angular momentum (or orbital angular momentum) M = (M x , M y , M z ) defined in (5.4.4). This is not to be taken to mean that an electron actually spins about an axis in some physical way. Experiments (in particular the noted Stern-Gerlach experiment) have provided adequate justification for the proposed concept of spin, a proposal also made by R. Bichowsky and H. Urey. Dirac has shown that the notion of spin is necessary if quantum mechanics and Einstein relativity are to be consistent theories. Chemical properties of atoms, and their ability to combine and form molecules, the splitting of spectral lines by a magnetic field applied to an atom (i.e., the Zeeman effect, which we discuss later), all depend on this important notion.
Spin and helicityTraditionally, in textbooks on quantum mechanics, spin is introduced via an idealized Stern-Gerlach experiment in which a non-relativistic beam of silver atoms passes through an inhomogeneous magnetic field.Each atom is treated as a single valence electron of charge -e in an s-state.The subsequent splitting of the beam into two indicates the two-valuedness of Sz, which is related to the value 1/2 for s, and the magnitude of the splitting shows that the magnetic moment /l is related to s by e /l = -~s, me the proportionality factor (the gyromagnetic ratio) being twice as big as the factor that classically gives the magnetic moment due to the orbital angular momentum of a point charge.Historically, however, it seems that the early Stern-Gerlach experiments, begun in 1922, had no influence at all upon the discovery of spin, simply because they were too imprecise.Rather, the concept of spin appeared after a long and tedious battle to understand the splitting patterns and separations in line spectra.Several people had for various reasons discussed classical models of rotating charge distributions but Kronig, in 1924, was the first to show that an electron with spin 1/2 would explain the pattern of what we would today call L • S splitting, as well as anomalies in the Zeeman effect.He realized, though, that the gyromagnetic ratio ( -ejmc) needed for the latter would give L • S splittings twice as big as those observed.It is said that Pauli expressed his negative reaction to Kronig's idea with such vehemence that Kronig never published his work (Mehra and Rechenberg, 1982).Soon thereafter, in 1925, the same idea occurred to Uhlenbeck and Goudsmit (1925), who proceeded to a detailed analysis of the splittings, concluding at first that everything worked beautifully, but then becoming aware, as a consequence of a comment by Heisenberg, of the factor-of-2 inconsistency mentioned above.
This chapter analyses the orbital angular momentum to three dimensions and introduces the spin angular momentum of the electron. The description of a localized particle in orbit requires a superposition of eigenfunctions analogous to the packet state that describes motion in one dimension. If the distance between molecules is fixed, all the energy changes are rotational kinetic energy changes, and the quantization of total angular momentum gives rise to discrete rotational energy levels. The analysis of orbital angular momentum is a powerful tool for describing molecular rotation. The Stern-Gerlach experiment and many other lines of evidence show that the measured magnetic moment associated with an electron spin is almost exactly one Bohr magneton. When orbital angular momentum and spin angular momentum both exist in the same atom, the magnetic moments that result from orbital and spin angular momenta interact to cause a splitting in the corresponding energy level.
Quantization of spin and orbital angular momenta in standard quantum mechanics is rooted in the fundamental rotational symmetry of space in conjunction with the results of experiments on atomic and subatomic particles conducted with the Stern-Gerlach apparatus. We explain some of the most important features of spin and orbital angular momenta as inescapable consequences of elementary Stern-Gerlach experiments viewed in light of the rotational symmetry of space. The rotation operator is first derived for spin-½ particles, then extended to spin-1 particles by treating the case of a hydrogen atom in its ground state, where the spin of the proton combines with that of the electron to create a spin-1 triplet state. Along the way, we examine the evolution of a particle’s spin state under an applied magnetic field, where the interaction energy arises from the existence of a magnetic dipole moment for each particle in proportion to its spin angular momentum. Whereas a constant magnetic field B0 causes the particle’s magnetic moment to gyrate around the direction of B0, it will be seen that the presence of a small oscillating magnetic field perpendicular to B0 brings about the so-called Rabi oscillations, which involve periodic flippings of the particle’s spin orientation. In the case of a hydrogen atom in its ground state, the interaction between the magnetic dipole moments of the proton and the electron splits the ground state between a lower energy singlet having a net angular momentum of zero (spin-0 state), and a higher energy triplet having a total angular momentum of ħ (spin-1 state). This hyperfine splitting is the source of the well-known 21-cm line observed in the spectrum of the hydrogen atom, which arises from transitions between the atom’s singlet and triplet states. In the final section, we put forward an argument (originally made by Richard Feynman) that ties the rotational symmetry of space to the conservation of angular momentum in quantum mechanics. The argument is, in fact, quite general, enabling one to deduce other conservation laws from various inherent symmetries of quantum mechanical systems.
Angular momentum plays a similarly important role in atomic systems, such as an electron subject to the central force provided by the Coulomb field of a nucleus. This chapter introduces the properties of angular momentum, both orbital and spin, in the quantum-mechanical scheme of things. The angular momentum of atomic systems is inseparable from the magnetic properties of atoms. The various permitted values of the quantized angular momentum play a central role in determining the number and variety of possible quantum states in atomic systems. The Stern-Gerlach experiment was deliberately designed to test whether or not the angular momentum of individual neutral atoms is quantized in a magnetic field. As in the development of the Schrodinger equation, classical physics gives some hints of the correct forms of these angular momentum operators. The chapter discusses rough estimate using the Neils Bohr theory and attributing the magnetic moment to the orbital motion of the electron.