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Lettere al nuovo cimento della societa italiana di fisica/Lettere al nuovo cimento

A solvable model for irreversible quantum phenomena

Silvio Bergia, F. Cannata, Bruno Giorgini, V. Zamboni

Published Jun 1, 1985• 4 citations
Publisher
DOI
10.1007/bf02749588

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arXiv:2208.04183•Physical review. E•Jul 6, 2023•0 citations
This paper is intended to provide the axiomatic study of nonequilibrium quantum statistical mechanics with some simple and rigorously solvable models. The models considered here are obtained as generalizations of the Ising model. They illustrate and allow a rational discussion of the following concepts relevant to the theory of irreversible phenomena: coarse-graining and time-smoothing, ergodicity, recurrences, impossibility of a Markovian description of the approach to equilibrium for some physical systems, justification of the various random phase assumptions, properties of the interaction responsible for the approach to equilibrium, master equations, etc.
The randomness of some irreversible quantum phenomena is a central question because irreversible phenomena break quantum coherence and thus yield an irreversible loss of information. The case of quantum jumps observed in the fluorescence of a single two-level atom illuminated by a quasi-resonant laser beam is a worked example where statistical interpretations of quantum mechanics still meet some difficulties because the basic equations are fully deterministic and unitary. In such a problem with two different time scales, the atom makes coherent optical Rabi oscillations between the two states, interrupted by random emissions (quasi-instantaneous) of photons where coherence is lost. To describe this system, we already proposed a novel approach, which is completed here. It amounts to putting a probability on the density matrix of the atom and deducing a general "kinetic Kolmogorov-like" equation for the evolution of the probability. In the simple case considered here, the probability only depends on a single variable θ describing the state of the atom, and p(θ,t) yields the statistical properties of the atom under the joint effects of coherent pumping and random emission of photons. We emphasize that p(θ,t) allows the description of all possible histories of the atom, as in Everett's many-worlds interpretation of quantum mechanics. This yields solvable equations in the two-level atom case.
A resolvable quantum many-body Hamiltonian is introduced that mimics the behavior of the autocatalytic chemical reaction A+B⇄2B involving two different molecular species, A and B. The model also describes two nonlinearly coupled modes of an optical cavity. Consistent with the current understanding of the relaxation dynamics of integrable systems in isolation, the wave function following a quantum quench exhibits irreversibility with retention of the memory about its initial conditions. Salient features of the model include a marked similarity with conventional quantum decay and a total B-to-A conversion, with associated classical-like behavior of the wave function, when the initial state does not contain A-type molecules.