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arXiv:2208.04183 · Physical review. E

Exactly solvable toy model of autocatalysis: Irreversible relaxation after a quantum quench

Roberto D. Merlin

Published Jul 6, 2023• 0 citations
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Abstract

A resolvable quantum many-body Hamiltonian is introduced that mimics the behavior of the autocatalytic chemical reaction A+B⇄2B involving two different molecular species, A and B. The model also describes two nonlinearly coupled modes of an optical cavity. Consistent with the current understanding of the relaxation dynamics of integrable systems in isolation, the wave function following a quantum quench exhibits irreversibility with retention of the memory about its initial conditions. Salient features of the model include a marked similarity with conventional quantum decay and a total B-to-A conversion, with associated classical-like behavior of the wave function, when the initial state does not contain A-type molecules.

DOI
10.1103/physreve.108.014104

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A resolvable quantum many-body Hamiltonian is introduced that mimics the behavior of the autocatalytic chemical reaction A+B⇄2B involving two different molecular species, A and B. The model also describes two nonlinearly coupled modes of an optical cavity. Consistent with the current understanding of the relaxation dynamics of integrable systems in isolation, the wave function following a quantum quench exhibits irreversibility with retention of the memory about its initial conditions. Salient features of the model include a marked similarity with conventional quantum decay and a total B-to-A conversion, with associated classical-like behavior of the wave function, when the initial state does not contain A-type molecules.
In a quantum many-body system, such as atoms, molecules, and atomic nuclei, interparticle interactions generate a complex quantum level scheme that can be analyzed progressively: from the simplest picture of independent quasiparticles moving in a self-consistent mean field to more complete descriptions that include residual interactions and the opening of decay channels above some excitation thresholds. Residual interactions lead to two seemingly contrasting phenomena: the emergence of collective modes (such as rotational and vibrational excitations) associated with specific symmetries, and internal thermalization, which gives rise to features of quantum chaos and causes these collective modes to damp. The picture becomes more intricate once decay channels become energetically accessible, allowing the system to decay irreversibly by means such as particle emission and thus transition to an open quantum regime. In this work, we investigate the competition between internal many-body dynamics and explicit, irreversible decay. These processes can occur on comparable timescales, leading to an initial stage of rapid dynamics followed by equilibration. We show that the decay of the faster components drives the system into an exponentially decaying regime, characterized by a noisy decay current. For this study, we adopt a general, albeit simplified, model of a collective mode embedded in a chaotic background and coupled to open decay channels. The interplay of timescales revealed in this framework appears to reflect universal features of open quantum systems.
The nonequilibrium dynamics of molecular devices is studied in the framework of a generic model for single-molecule transistors: a resonant level coupled by displacement to a single vibrational mode. In the limit of a broad level and in the vicinity of the resonance, the model can be controllably reduced to a form quadratic in bosonic operators, which in turn is exactly solvable. The response of the system to a broad class of sudden quenches and ac drives is thus computed in a nonperturbative manner, providing an asymptotically exact solution in the limit of weak electron-phonon coupling. From the analytic solution, we are able to (1) explicitly show that the system thermalizes following a local quantum quench, (2) analyze in detail the time scales involved, (3) show that the relaxation time in response to a quantum quench depends on the observable in question, and (4) reveal how the amplitude of long-time oscillations evolves as the frequency of an ac drive is tuned across the resonance frequency. Explicit analytical expressions are given for all physical quantities and all nonequilibrium scenarios under study.
We study the dynamic response of an sss-wave BCS-BEC (atomic-molecular) condensate to detuning quenches within the two-channel model beyond the weak-coupling BCS limit. At long times after the quench, the condensate ends up in one of three main asymptotic states (nonequilibrium phases), which are qualitatively similar to those in other fermionic condensates defined by a global complex order parameter. In phase I the amplitude of the order parameter vanishes as a power law, in phase II it goes to a nonzero constant, and in phase III it oscillates persistently. We construct exact quench phase diagrams that predict the asymptotic state (including the many-body wave function) depending on the initial and final detunings and on the Feshbach resonance width. Outside of the weak-coupling regime, both the mechanism and the time dependence of the relaxation of the amplitude of the order parameter in phases I and II are modified. Also, quenches from arbitrarily weak initial to sufficiently strong final coupling do not produce persistent oscillations in contrast to the behavior in the BCS regime. The most remarkable feature of coherent condensate dynamics in various fermion superfluids is an effective reduction in the number of dynamic degrees of freedom as the evolution time goes to infinity. As a result, the long-time dynamics can be fully described in terms of just a few new collective dynamical variables governed by the same Hamiltonian only with ``renormalized'' parameters. Combining this feature with the integrability of the underlying (e.g., the two-channel) model, we develop and consistently present a general method that explicitly obtains the exact asymptotic state of the system.
Understanding the nonequilibrium behavior of quantum systems is a major goal of contemporary physics. Much research is currently focused on the dynamics of many-body systems in low-dimensional lattices following a quench, i.e., a sudden change of parameters. Already such a simple setting poses substantial theoretical challenges for the investigation of the real-time postquench quantum dynamics. In classical many-body systems, the Kolmogorov-Mehl-Johnson-Avrami model describes the phase transformation kinetics of a system that is quenched across a first-order phase transition. Here, we show that a similar approach can be applied for shedding light on the quench dynamics of an interacting gas of Rydberg atoms, which has become an important experimental platform for the investigation of quantum nonequilibrium effects. We are able to gain an analytical understanding of the time evolution following a sudden quench from an initial state devoid of Rydberg atoms and identify strikingly different behaviors of the excitation growth in the classical and quantum regimes. Our approach allows us to describe quenches near a nonequilibrium phase transition and provides an approximate analytical solution deep in the quantum domain.
We study isolated many-body quantum systems after a quench and show that their dynamics depends on the interplay between the initial state and the Hamiltonian dictating the evolution. The systems are in the nonperturbative regime. The relaxation process is controlled by the width of the energy distribution of the initial state and may be very similar for both chaotic and integrable Hamiltonians. We derive an analytical expression for the fidelity decay, which displays excellent agreement with our numerical results. This decay is Gaussian and may persist until saturation. Analytical expressions that describe very well the initial evolution of the Shannon entropy and of few-body observables are also provided. The analyses are developed for deterministic one-dimensional systems and initial states of interest to current experiments with cold atoms in optical lattices.
A crossover between different power-law relaxation behaviors of many-body periodically driven integrable systems has come to light in recent years. We demonstrate, using integrable quantum systems, that similar kinds of dynamical transitions may also occur in the relaxation of such systems following a sudden quench. Particularly, we observe two distinct power-law relaxation behaviors following a sudden quench in the integrable XY model, depending upon whether the quenched Hamiltonian lies in the commensurate or the incommensurate phase. The relaxation behavior for quenches at and near the boundary line, called the disorder line (DL), separating these phases is also characterized. The relaxation at the DL shows a scaling exponent different from that for quenches to either of the commensurate or incommensurate phases. The transitions occur through a crossover from the commensurate or incommensurate scaling behavior to the DL scaling behavior. The crossover time diverges as a power law as the parameters of the final quenched Hamiltonian approach the DL. The transitions are also observed to be robust under weak integrability-breaking perturbations but disappear following strongly chaotic quenches.