A note on the equivalence of the classical motion of rigid bodies with prescribed angular velocities and the quantum mechanical solutions for paramagnetic atoms in external fields
It is shown that both for single and coupled spin systems in external magnetic time dependent fields, the quantum mechanical solution determines a unique solution for the classical motion of a single or a coupled system of rigid bodies with prescribed angular velocities proportional to the external field, the converse being also true.
A relativistically invariant representation of the generalized momentum of a particle in an external field is proposed. In this representation, the dependence of the potentials of the interaction of the particle with the field on the particle velocity is taken into account. The exact correspondence of the expressions of energy and potential energy for the classical Hamiltonian is established, which makes identical the solutions to the problems of mechanics with relativistic and nonrelativistic approaches. The invariance of the proposed representation of the generalized momentum makes it possible to equivalently describe a physical system in geometrically conjugate spaces of kinematic and dynamic variables. Relativistic invariant equations are proposed for the action function and the wave function based on the invariance of the representation of the generalized momentum. The equations have solutions for any values of the constant interaction of the particle with the field, for example, in the problem of a hydrogen-like atom, when the atomic number of the nucleus is Z > 137. Based on the parametric representation of the action, the expression for the canonical Lagrangian, the equations of motion, and the expression for the force acting on the charge are derived when moving in an external electromagnetic field. The Dirac equation with the correct inclusion of the interaction for a particle in an external field is presented. In this form, the solutions of the equations are not limited by the value of the interaction constant. The solutions of the problem of charge motion in a constant electric field, the problems for a particle in a potential well and the passage of a particle through a potential barrier, the problems of motion in an exponential field (Morse), and also the problems of a hydrogen atom are given.
Classical dynamics of rigid bodies The difficulties in formulating the theory of spin ½ systems outlined at the end of the last chapter may be avoided if we start from a classical theory of rotation in which the translational and orientational coordinates enter on a symmetrical footing, and pass to the quantum theory via the standard canonical quantization procedure. The result is not simply the Pauli theory written in a different matrix representation but a more general physical theory which explicitly incorporates in the wave equation the extended character of the bodies considered, through moment-of-inertia-dependent terms. As expected, the spin ½ character of the wave is manifested through the dependence of the body motion on the total quantum state via quantum potential and torque terms. Spin is not usually approached from this angle in basic quantum mechanics texts so it is worthwhile to build up the theory from scratch (for a more rigorous treatment see Normand (1980) and for further details: Bopp & Haag (1950), Rosen (1951, 1984), van Winter (1954), Dankel (1970), Holland (1988a, b)). We begin by reviewing some basic results in the classical canonical theory of rigid body motion. Our treatment is confined to a rigid homogeneous sphere with moment of inertia I about any axis passing through its centre, where the centre of mass is located. The sphere carries a rigid charge and a magnetic moment. By Chasle's theorem an arbitrary displacement of a rigid body is composed of a translation together with a rotation about a line fixed in the body.
The classical equations of motion of a charged point-particle with intrinsic spin under the influence of an external electromagnetic field are restated and compared with the Heisenberg equations of motion derived from the Dirac theory. The partition of angular momentum between particle and field in the classical theory is contrasted to the Dirac theory of electron spin. The analogy between the Dirac equation and the theory of parametric amplification is pointed out.A free spinning point particle moving according to the laws of classical relativistic point-particle mechanics may move along a helix. The sum of the intrinsic spin $\ensuremath{\sigma}$ and the angular momentum of the helical motion in this classical analog of zitterbewegung is an effective spin vector S which is a constant of the motion. Because of this internal motion, the effective mass M of the particle differs from the mass m which is ascribed to it in the equations of motion. Solutions are found in which S is parallel or antiparallel to the momentum, and the sign of M is determined by the helicity. When placed in a uniform electromagnetic field, the particle behaves as if it had a rest mass M and a magnetic moment $\frac{e\ensuremath{\sigma}}{\mathrm{Mc}}$, in addition to any explicit magnetic moment that may be ascribed to it.
For a free Dirac electron, the Heisenberg equations define an internal dynamical system in the rest frame, isomorphic to a finite three-dimensional oscillator with a compact SO(5) phase space, such that the spin of the electron is the orbital angular momentum of the internal dynamics (Barut and Bracken 1980, 1981a). In the present work, the change in this internal dynamics due to an external magnetic field is studied. In order that the internal motion can be distinguished from the centre of mass motion, the solutions of the corresponding Hamilton and Heisenberg equations for the relativistic classical motion and the relativistic quantum mechanical spinless motion are also presented. The solutions for the electron exhibit the effect of the spin terms both in the internal motion and external motion, and we are able to identify the properties of the Zitterbewegung in the external field.
The Hamiltonian describing a system of particles in a rotating coordinate system is derived and it is shown that the simple classical solution of rigid flow is forbidden in quantum mechanics, even at very low angular velocities. This effect is closely parallel to the Aharonov–Bohm effect, which likewise has its origin in the single-valuedness requirement of the wave function. An analytical approach to perturbation theory is used to include the effects of the Coriolis and centrifugal forces and to derive the current flows for some independent-particle systems, that is, for the Inglis cranking model. It is shown, by explicit construction, that the currents are not rigid even when the moment of inertia assumes the rigid-flow value, as it does for the harmonic oscillator single-particle potential under conditions of self-consistency. Furthermore, it is shown that, for a more general potential, even the moment of inertia is not rigid.
The well-known Zeeman and Stark effects can lead to unusual atomic state dynamics when both magnetic and electric fields are present. In this paper we analyze quantum mechanical and classical models of the time evolution of the angular momentum of an atom in the presence of weak, orthogonal electric and magnetic fields. The anisotropic electric polarizability of the atom plays a crucial role in the dynamics. The classical model leads to nonlinear evolution equations, and we investigate how quantum mechanics ‘‘avoids’’ the nonlinearity. Finally, we note that the classical equations of motion are identical to those used to describe the time evolution of Stokes vectors for polarized light propagating in an optically nonlinear medium. The treatment is appropriate for an undergraduate course in quantum mechanics.