The well-known Zeeman and Stark effects can lead to unusual atomic state dynamics when both magnetic and electric fields are present. In this paper we analyze quantum mechanical and classical models of the time evolution of the angular momentum of an atom in the presence of weak, orthogonal electric and magnetic fields. The anisotropic electric polarizability of the atom plays a crucial role in the dynamics. The classical model leads to nonlinear evolution equations, and we investigate how quantum mechanics ‘‘avoids’’ the nonlinearity. Finally, we note that the classical equations of motion are identical to those used to describe the time evolution of Stokes vectors for polarized light propagating in an optically nonlinear medium. The treatment is appropriate for an undergraduate course in quantum mechanics.
The well-known Zeeman and Stark effects can lead to unusual atomic state dynamics when both magnetic and electric fields are present. In this paper we analyze quantum mechanical and classical models of the time evolution of the angular momentum of an atom in the presence of weak, orthogonal electric and magnetic fields. The anisotropic electric polarizability of the atom plays a crucial role in the dynamics. The classical model leads to nonlinear evolution equations, and we investigate how quantum mechanics ‘‘avoids’’ the nonlinearity. Finally, we note that the classical equations of motion are identical to those used to describe the time evolution of Stokes vectors for polarized light propagating in an optically nonlinear medium. The treatment is appropriate for an undergraduate course in quantum mechanics.
A quantum model for calculating the combined Stark and Zeeman effects of simultaneously applied electric and magnetic fields is presented. Our focus here is on atoms with hyperfine structure, such as Cesium. Matrix representations of the Stark, Zeeman, and hyperfine interaction operators are constructed using angular momentum theory and spherical tensor algebra. Matrix elements are evaluated in order to determine the energy-level dependence on the applied fields and reveal intriguing state dynamics in both parallel and orthogonal electric and magnetic fields. The fundamental physics is relevant for an advanced undergraduate or graduate quantum mechanics course.
In this paper, a coherent superposition of angular-momentum states created by absorption of polarized light by molecules is analyzed. Attention is paid to the time evolution of wave packets representing the spatial orientation of the internuclear axis of a diatomic molecule. Two examples are considered in detail. Molecules absorbing light in a permanent magnetic field experiencing the Zeeman effect and molecules absorbing light in a permanent electric field experiencing the quadratic Stark effect. In a magnetic field, we have a wave packet that evolves in time exactly as a classical dipole oscillator in a permanent magnetic field (classical-physics picture of the Zeeman effect). In the second case, we have a wave packet that goes through periodical changes of shape of the packet with revivals of the initial shape. This is pure quantum behavior. The classical motion of angular momentum in an electric field in the case of a quadratic Stark effect is known to be a periodic. Solutions obtained for wave packet evolution are briefly compared with Rydberg-state coherent wave packets and harmonic-oscillator wave packets. Zeeman and Stark effects in small molecules continuously attract the attention of researchers, theoreticians, as well as experimentalists. These investigations allow us to obtain a deeper understanding of the interaction of molecules with stationary external fields and also can be used as a practical tool to measure different molecular characteristics, such as permanent electric or magnetic dipole moments, intramolecular perturbations, etc. It is worthwhile analyzing these effects as an evolution of wave packets. All this motivates a comparison of the quantum and classical picture of Zeeman and Stark effects in molecules.PACS No.: 33.55.Be
A thorough unified treatment is given of the quantum-mechanical operators and wave functions for a molecular system (composed of N moving charged particles) in static uniform electric and magnetic fields E and B. The treatment is rigorous within the nonrelativistic approximation. The system may either be neutral or charged. The fields may have arbitrary intensities and orientations. Close correspondence is maintained between the classical and quantum-mechanical treatments. The wave functions are expressed both in the time-independent energy representation and in time-dependent wave packets. Three types of momentum play important roles. For single-particle systems they are the canonical momentum P, the mechanical momentum $\mathit{\ensuremath{\Pi}}=\mathit{P}\ensuremath{-}(\frac{e}{c})\mathit{A}=M\stackrel{\ifmmode \dot{}\else \.{}\fi{}}{R}$, and the pseudomomentum $\mathcal{K}=\mathit{\ensuremath{\Pi}}\ensuremath{-}(\frac{e}{c})\mathit{R}\ifmmode\times\else\texttimes\fi{}\mathit{B}\ensuremath{-}e\mathit{E}t$. The pseudomomentum is a constant of the motion. Except in the absence of magnetic fields, not all of the components of either $\mathit{\ensuremath{\Pi}}$ or K commute. This complicates the quantum-mechanical formalism. The components of the pseudomomentum have simple classical interpretations, and in quantum mechanics they are related to the operator which performs a boost to a reference frame moving with constant velocity v. In this moving frame, the electric field intensity is ${\mathit{E}}^{\ensuremath{'}}=\mathit{E}+(\frac{\mathit{v}}{c})\ifmmode\times\else\texttimes\fi{}\mathit{B}$. Thus, in a frame moving with the drift velocity ${\mathit{v}}_{d}=(\frac{c}{{B}^{2}})\mathit{E}\ifmmode\times\else\texttimes\fi{}\mathit{B}$, the components of the electric field intensity perpendicular to B vanish. In this paper, the velocity boost operators are used to show the relationships between wave functions expressed in reference frames moving with repsect to each other. The dynamics of the N-particle systems are simplified by making the Power-Zienau-Woolley transformation (which reduces as a special case to a unitary transformation used by Lamb) and by using center-of-mass and internal coordinates. Generalizing previous works, it is shown how the pseudomomentum is involved in separating these degrees of freedom for N particles in both E and B. For neutral molecules, the Schr\"odinger equation is "pseudoseparated" and the internal degrees of freedom are coupled to the center of mass motion only by the "motional Stark Effect," which involves the constant of motion K. For ionic systems, only one component of the center of mass is coupled to the internal motion. Quantitative estimates of the weak center-of-mass coupling are made for both neutral and ionic n=1 and n=2 quantum states of two-body systems by perturbation expansions in powers of the field strengths. In the usual nonrigorous treatments of systems in magnetic fields, no distinction is made between $\mathit{\ensuremath{\Pi}}$ and K and both are approximated by $M\stackrel{\ifmmode \dot{}\else \.{}\fi{}}{R}$, where M is the mass of the molecule and R is taken to be the classical orbital position of a single particle having the same mass and charge. This is an excellent approximation for ground-state molecules and ions in weak fields. However, the resulting errors can be much larger if the system is in either intense fields or high-lying states (e.g., Rydberg levels). These are the conditions under which the rigorous formalism should be most useful. The determination of the wave functions and energy levels for many-particle ionic systems is complicated due to the coupling with the center of mass. The suggestion is made that it might be useful to boost the reference frame so that it moves with the velocity $\stackrel{\ifmmode \dot{}\else \.{}\fi{}}{R}$ of a single classical particle. The Schr\"odinger equation in this frame could serve as a more suitable basis for perturbative or variational treatments.
We consider the interaction between a classical time-varying electric field and the atomic electrical dipole moment operator of a finite state atom and calculate approximately the mixed state evolution of the atom with such an interaction Hamiltonian up to quadratic orders in the external classical electric field using Schrodinger’s equation for mixed state evolution. From this approximate expression for the state evolution, we evaluate the average atomic electric dipole moment as a linear-quadratic function of the electric field. Later on, we also take into account Brownian motion bath noise that couples to the atomic dynamics, so that the Schrodinger equation dynamics gets modified to the Lindblad dynamics of an open quantum system, i.e., the master equation. From the average atomic dipole moment, we obtain an expression for the average polarization field of atoms constituting the medium through which the classical electromagnetic wave propagates. This average polarization is a linear-quadratic causal functional of the electric field. The resulting Maxwell equations for wave propagation, taking into account this polarization current density, thus acquire a quadratic nonlinearity which can be used to explain higher harmonic frequencies at the output of an optical fiber when the input is excited by the electric field coming from a monochromatic laser. We are then also able to calculate the mean square fluctuations in the polarization field using the evolving atomic state, and hence the electric field propagating through the medium of atoms acquires quantum fluctuations which can be used to explain time-varying random shifts in the spectral lines. As mentioned above, we include in this article an extension of this problem to the case when there is white Gaussian noise corrupting the state evolution dynamics of the atom and also the case when there is a pairwise interaction between the spin dipoles of atoms at two different locations. In the former case, we derive an approximate formula for the polarization field as well as its temporal statistical correlations, and we show how this computation can be extended to the latter case too. When there is a pairwise interaction between the atomic spins, we use a version of the approximate quantum Boltzmann equation to calculate the first and second order marginals of the atomic states, which is then used to compute the average polarization as well as its spatio-temporal correlations. Temporal correlations using second marginals of the atomic states cannot be computed using classical probabilistic methods owing to Heisenberg uncertainty, so we propose a sequential measurement-based strategy involving computation of the joint probabilities of the atomic spin components at two different times by first measuring one component of the spin, allowing for state collapse, and then following it up with nonlinear time evolution from the collapsed two-particle state using the quantum Boltzmann equation, followed further by measurement of another component of the spin at the second time.
The Wigner representation of angular-momentum orientation in the classical limit on $J\ensuremath{\gg}1$ has been used to derive an equation of angular-momentum motion in the case of a closed two-level system interacting with an arbitrary polarized radiation. This equation enables us to carry out a theoretical analysis of angular-momentum motion and consider final states of the quantum system for all types of dipole transitions. We have found that in the case of a zero magnetic field in the final state of the system with $\stackrel{\ensuremath{\rightarrow}}{J}J$ or $\stackrel{\ensuremath{\rightarrow}}{J}J+1$ optical transition, the angular momentum is directed along or opposite to the wave vector of the radiation depending on the sign of the polarization ellipsity, while for a linear polarization the angular momentum is isotropically distributed on the plane orthogonal to the polarization vector. For the $\stackrel{\ensuremath{\rightarrow}}{J}J\ensuremath{-}1$ transition two directions of angular momentum are possible in the final state. These directions are determined by the ellipsity of polarization. The spatial size of the final distribution of the angular momentum has been defined by the quantum uncertainty, 1/J, of the angular-momentum orientation. In the case of the $\stackrel{\ensuremath{\rightarrow}}{J}J\ensuremath{-}1$ or $\stackrel{\ensuremath{\rightarrow}}{J}J,$ transition particles come into ``dark'' states while for the $\stackrel{\ensuremath{\rightarrow}}{J}J+1$ transition they occupy the ``brightest'' state. In the presence of a nonzero magnetic field, particles with $\stackrel{\ensuremath{\rightarrow}}{J}J$ transition have in the final state only one angular-momentum orientation, i.e., along or opposite to the direction of the magnetic field depending on the polarization ellipsity sign. For the $\stackrel{\ensuremath{\rightarrow}}{J}J+1$ transition both directions are possible, i.e., along and opposite to the magnetic field. In the case of the $\stackrel{\ensuremath{\rightarrow}}{J}J\ensuremath{-}1$ transition the directions of the angular momentum form a cone around the magnetic field.
The analogy between polarization optics effects and the dynamics of a spin in a magnetic field is analyzed based on the fact that the Bloch equation for a spin in a magnetic field is formally identical to the evolution equation for the quasi-spin vector of a light propagating in an optically anisotropic medium. Among the effects discussed within this framework are light polarization beats in a birefringent medium; optical activity suppression in the media with linear birefringence; suppression of linear birefringence in the media with spatially modulated gyration; 'adiabatic' transformation of light polarization in media of smoothly varying anisotropy, and two- and three-pulse polarization echoes.