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Journal de physique

Hamiltonian of a many-electron atom in an external magnetic field and classical electrodynamics

C. Lhuillier, J.P. Faroux

Published Jan 1, 1977• 7 citations
Publisher

Abstract

The increasing precision of experiments on the Zeeman effect of many electron atoms requires an ever increasing knowledge of relativistic and radiative effects. The generalization of the Breit equation as proposed by Hegstrom includes all these effects up to order c— 3. In the non relativistic limit the resulting Hamiltonian is quite intricate, but we show in this paper that it is possible to explain almost all of its terms within the frame of classical electrodynamics. In particular, picturing the atoms as point-like particles with intrinsic magnetic moments, we show that the physical phenomena underlying the Breit equation and its recent extension are mainly two well-known classical phenomena : i) the interaction of the magnetic moment of the constituent particles with the magnetic field they experience in their rest frame; ii) the Thomas precession of the spins of the accelerated particles.

DOI
10.1051/jphys:01977003807074700

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The increasing precision of experiments on the Zeeman effect of many electron atoms requires an ever increasing knowledge of relativistic and radiative effects. The generalization of the Breit equation as proposed by Hegstrom includes all these effects up to order c— 3. In the non relativistic limit the resulting Hamiltonian is quite intricate, but we show in this paper that it is possible to explain almost all of its terms within the frame of classical electrodynamics. In particular, picturing the atoms as point-like particles with intrinsic magnetic moments, we show that the physical phenomena underlying the Breit equation and its recent extension are mainly two well-known classical phenomena : i) the interaction of the magnetic moment of the constituent particles with the magnetic field they experience in their rest frame; ii) the Thomas precession of the spins of the accelerated particles.
The external electromagnetic interactions of hydrogenic atoms, which exhibit global Galilean invariance but preserve the relativistic description of the electron, are investigated. The Hamiltonian for the free atom consists of the Breit Hamiltonian for a relativistic electron interacting with a nonrelativistic spinless proton. Approximate generators of the Galilean group are constructed in terms of individual-particle position, momentum, and spin operators in several unitarily equivalent representations. In one of these the Hamiltonian is separable in conventional relative and center-of-mass coordinates. This separability facilitates the treatment of a number of external-field problems. An effective Hamiltonian for the interaction of the atom with a constant external electric field is given and compared to that obtained by other authors. The low-energy theorem for Compton scattering from the composite system is explicitly verified including corrections due to atomic binding. This also gives an independent verification of recently obtained bound-state corrections to the atomic magnetic moment. Finally, an effective interaction of a charged Dirac particle with a hydrogenic atom is given in the representation in which the atomic Hamiltonian is separable.
The classical equations of motion of a charged point-particle with intrinsic spin under the influence of an external electromagnetic field are restated and compared with the Heisenberg equations of motion derived from the Dirac theory. The partition of angular momentum between particle and field in the classical theory is contrasted to the Dirac theory of electron spin. The analogy between the Dirac equation and the theory of parametric amplification is pointed out.A free spinning point particle moving according to the laws of classical relativistic point-particle mechanics may move along a helix. The sum of the intrinsic spin $\ensuremath{\sigma}$ and the angular momentum of the helical motion in this classical analog of zitterbewegung is an effective spin vector S which is a constant of the motion. Because of this internal motion, the effective mass MMM of the particle differs from the mass mmm which is ascribed to it in the equations of motion. Solutions are found in which S is parallel or antiparallel to the momentum, and the sign of MMM is determined by the helicity. When placed in a uniform electromagnetic field, the particle behaves as if it had a rest mass MMM and a magnetic moment $\frac{e\ensuremath{\sigma}}{\mathrm{Mc}}$, in addition to any explicit magnetic moment that may be ascribed to it.
It is natural to expect that the electromagnetic spin-spin interaction has roots in a more fundamental theory: quantum electrodynamics in this case. To show this, we take the non-relativistic limit of the Dirac-Maxwell Lagrangian, using the Foldy-Wouthuysen transformation and derive the Breit interaction by an alternative approach. By adding the Pauli term (i.e., a higher-order interaction between spin and the electromagnetic field), we calculate the correction terms to electromagnetic spin-spin interactions in the non-relativistic limit. Finally, we study some of the physical effects of these terms regarding spin-spin interactions and spin-spin entanglements. Accordingly, we provide theoretical estimates that are not yet accessible with current experiments.
In a purely nonrelativistic formulation, a Hamiltonian is obtained for the description of states of a charged particle with spin, interacting with an external electromagnetic field. For the specific cases of spin-1/2 and spin-1, the simplest choices for the Hamiltonian functions lead to a value for the (lowest order) intrinsic magnetic moment equal to the Bohr magneton in both cases. This is the same as is obtained in treatments that start from a relativistic formulation, as in the Dirac theory. The nonrelativistic and relativistic formulations both employ the ‘‘minimal coupling principle,’’ but the resulting Hamiltonians with couplings are, for very general considerations, not completely determined. However, the corresponding ambiguity that occurs in the nonrelativistic theory is also present in the relativistic formulation. The simpler nonrelativistic theory is more transparent in exhibiting these features of the problem and dispels the notion that spin (and the associated magnetic moment) require relativistic formulations for a proper understanding.
For a free Dirac electron, the Heisenberg equations define an internal dynamical system in the rest frame, isomorphic to a finite three-dimensional oscillator with a compact SO(5) phase space, such that the spin of the electron is the orbital angular momentum of the internal dynamics (Barut and Bracken 1980, 1981a). In the present work, the change in this internal dynamics due to an external magnetic field is studied. In order that the internal motion can be distinguished from the centre of mass motion, the solutions of the corresponding Hamilton and Heisenberg equations for the relativistic classical motion and the relativistic quantum mechanical spinless motion are also presented. The solutions for the electron exhibit the effect of the spin terms both in the internal motion and external motion, and we are able to identify the properties of the Zitterbewegung in the external field.
Despite the success of the Dirac equation, the incorporation of the special theory of relativity into quantum mechanics predicts some paradoxes, like that the spin prediction from Dirac equation can be only identified with non- relativistic approximations (Pauli and Foldy-Wouthysen), as well as the spin predication is a relativistic quantum phenomena because the spin prediction is a necessary requirement of the relativistic quantum mechanics only. In this paper we show that the derivation of the spin and its magnetic moment can be done with a pure classical treatment. Since we start from the classical physical laws and the classical relativity principle to get the linear Schrödinger equation as a result the derivation of the spin and its magnetic moment can be done with a pure classical treatment. This approach result a Schrödinger equation, in which we show that the spin of the electron is a non relativistic quantum phenomenon too.