We investigate the dynamics of a two-qubit open quantum system, in particular the two-qubit spin-boson model in the strong coupling regime, coupled to two thermal bosonic baths under non-Markovian and non-equilibrium conditions. Two complementary approaches, the Hierarchical Equations of Motion (HEOM) and Reaction Coordinate Mapping (RCM), are employed to examine various coupling regimes between the qubits and their respective baths. The dynamical features of the model and the impact of the tunneling amplitude on quantum coherence of the system are probed using the $l_1$ -norm of coherence. The model is further shown to have non-Markovian evolution. The nontrivial task of calculating entropy production in the strong-coupling regime is performed using auxiliary density operators in HEOM. Motivated by the realization of a quantum thermal device in the strong-coupling regime, the non-equilibrium steady-state behavior of the system is investigated. Furthermore, the relationship between the heat and spin currents and the tunneling amplitude is probed.We investigate the dynamics of a two-qubit open quantum system, in particular the two-qubit spin-boson model in the strong coupling regime, coupled to two thermal bosonic baths under non-Markovian and non-equilibrium conditions. Two complementary approaches, the Hierarchical Equations of Motion (HEOM) and Reaction Coordinate Mapping (RCM), are employed to examine various coupling regimes between the qubits and their respective baths. The dynamical features of the model and the impact of the tunneling amplitude on quantum coherence of the system are probed using the $l_1$-norm of coherence. The model is further shown to have non-Markovian evolution. The nontrivial task of calculating entropy production in the strong-coupling regime is performed using auxiliary density operators in HEOM. Motivated by the realization of a quantum thermal device in the strong-coupling regime, the non-equilibrium steady-state behavior of the system is investigated. Furthermore, the relationship between the heat and spin currents and the tunneling amplitude is probed.

quant-pharXiv:2601.15026Jan 22, 20260 citations

Quantum–classical correspondence in spin–boson equilibrium states at arbitrary coupling

Federico Cerisola, Marco Berritta, Stefano Scali +3 more

Abstract The equilibrium properties of nanoscale systems can deviate significantly from standard thermodynamics due to their coupling to an environment. We investigate this here for the θ -angled spin–boson model, where we first derive a compact and general form of the classical equilibrium state including environmental corrections to all orders. Secondly, for the quantum spin–boson model we prove, by carefully taking a large spin limit, that Bohr’s quantum–classical correspondence persists at all coupling strengths. This shows, for the first time, the validity of the quantum–classical correspondence for an open system and gives insight into the regimes where the quantum system is well-approximated by a classical one. Finally, we provide the first classification of the coupling parameter regimes for the spin–boson model, from weak to ultrastrong, both for the quantum case and the classical setting. Our results shed light on the interplay of quantum and mean force corrections in equilibrium states of the spin–boson model, and will help draw the quantum to classical boundary in a range of fields, such as magnetism and exciton dynamics.Abstract The equilibrium properties of nanoscale systems can deviate significantly from standard thermodynamics due to their coupling to an environment. We investigate this here for the θ -angled spin–boson model, where we first derive a compact and general form of the classical equilibrium state including environmental corrections to all orders. Secondly, for the quantum spin–boson model we prove, by carefully taking a large spin limit, that Bohr’s quantum–classical correspondence persists at all coupling strengths. This shows, for the first time, the validity of the quantum–classical correspondence for an open system and gives insight into the regimes where the quantum system is well-approximated by a classical one. Finally, we provide the first classification of the coupling parameter regimes for the spin–boson model, from weak to ultrastrong, both for the quantum case and the classical setting. Our results shed light on the interplay of quantum and mean force corrections in equilibrium states of the spin–boson model, and will help draw the quantum to classical boundary in a range of fields, such as magnetism and exciton dynamics.

arXiv:2204.10874New Journal of PhysicsMay 1, 202421 citations

l_1

-norm of coherence. The model is further shown to have non-Markovian evolution. The nontrivial task of calculating entropy production in the strong-coupling regime is performed using auxiliary density operators in HEOM. Motivated by the realization of a quantum thermal device in the strong-coupling regime, the non-equilibrium steady-state behavior of the system is investigated. Furthermore, the relationship between the heat and spin currents and the tunneling amplitude is probed.