Abstract The equilibrium properties of nanoscale systems can deviate significantly from standard thermodynamics due to their coupling to an environment. We investigate this here for the θ -angled spin–boson model, where we first derive a compact and general form of the classical equilibrium state including environmental corrections to all orders. Secondly, for the quantum spin–boson model we prove, by carefully taking a large spin limit, that Bohr’s quantum–classical correspondence persists at all coupling strengths. This shows, for the first time, the validity of the quantum–classical correspondence for an open system and gives insight into the regimes where the quantum system is well-approximated by a classical one. Finally, we provide the first classification of the coupling parameter regimes for the spin–boson model, from weak to ultrastrong, both for the quantum case and the classical setting. Our results shed light on the interplay of quantum and mean force corrections in equilibrium states of the spin–boson model, and will help draw the quantum to classical boundary in a range of fields, such as magnetism and exciton dynamics.
Abstract The equilibrium properties of nanoscale systems can deviate significantly from standard thermodynamics due to their coupling to an environment. We investigate this here for the θ -angled spin–boson model, where we first derive a compact and general form of the classical equilibrium state including environmental corrections to all orders. Secondly, for the quantum spin–boson model we prove, by carefully taking a large spin limit, that Bohr’s quantum–classical correspondence persists at all coupling strengths. This shows, for the first time, the validity of the quantum–classical correspondence for an open system and gives insight into the regimes where the quantum system is well-approximated by a classical one. Finally, we provide the first classification of the coupling parameter regimes for the spin–boson model, from weak to ultrastrong, both for the quantum case and the classical setting. Our results shed light on the interplay of quantum and mean force corrections in equilibrium states of the spin–boson model, and will help draw the quantum to classical boundary in a range of fields, such as magnetism and exciton dynamics.
When the coupling of a quantum system to its environment is nonnegligible, its steady state is known to deviate from the textbook Gibbs state. The Bloch-Redfield quantum master equation, one of the most widely adopted equations for solving the open quantum dynamics, cannot predict all the deviations of the steady state of a quantum system from the Gibbs state. In this paper, for a generic spin-boson model, we use a higher-order quantum master equation (in system-environment coupling strength) to analytically calculate all the deviations of the steady state of the quantum system up to second order in coupling strength. We also show that this steady state is exactly identical to the corresponding generalized Gibbs state, the so-called quantum mean force Gibbs state, at arbitrary temperature. All these calculations are highly general, making them immediately applicable to a wide class of systems well modeled by the spin-Boson model, spanning a diverse range of topics, from nanomaterials to various condensed-phase processes, and quantum computing (e.g., environment-induced corrections to the steady state of a superconducting qubit). As an example, we use our results to study the dynamics and the steady state of a solid-state double-quantum-dot system under physically relevant choices of parameters.
The Gibbs state is widely taken to be the equilibrium state of a system in contact with an environment at temperature T. However, non-negligible interactions between system and environment can give rise to an altered state. Here we derive general expressions for this mean force Gibbs state, valid for any system that interacts with a bosonic reservoir. First, we derive the state in the weak coupling limit and find that, in general, it maintains coherences with respect to the bare system Hamiltonian. Second, we develop a new expansion method suited to investigate the ultrastrong coupling regime. This allows us to derive the explicit form for the mean force Gibbs state, and we find that it becomes diagonal in the basis set by the system-reservoir interaction instead of the system Hamiltonian. Several examples are discussed including a single qubit, a three-level V-system and two coupled qubits all interacting with bosonic reservoirs. The results shed light on the presence of coherences in the strong coupling regime, and provide key tools for nanoscale thermodynamics investigations.
The Gibbs state is widely taken to be the equilibrium state of a system in contact with an environment at temperature T. However, non-negligible interactions between system and environment can give rise to an altered state. Here, we derive general expressions for this mean force Gibbs state, valid for any system that interacts with a bosonic reservoir. First, we derive the state in the weak coupling limit and find that, in general, it maintains coherences with respect to the bare system Hamiltonian. Second, we develop a new expansion method suited to investigate the ultrastrong coupling regime. This allows us to derive the explicit form for the mean force Gibbs state, and we find that it becomes diagonal in the basis set by the system-reservoir interaction instead of the system Hamiltonian. Several examples are discussed including a single qubit, a three-level V-system, and two coupled qubits all interacting with bosonic reservoirs. The results shed light on the presence of coherences in the strong coupling regime, and provide key tools for nanoscale thermodynamics investigations.
We study the thermodynamics of quantum particles with long-range interactions at T = 0. Specifically, we generalize the Hamiltonian mean-field (HMF) model to the case of bosons. We consider the Hartree approximation that becomes exact in a proper thermodynamic limit with a coupling constant k ∼ 1/ N . The equilibrium configurations are solutions of the mean-field Schrödinger equation with a cosine interaction. We show that the homogeneous phase, which is unstable in the classical regime, becomes stable in the quantum regime. The homogeneous phase is stabilized by the Heisenberg uncertainty principle. This takes place through a second-order phase transition where the control parameter is the normalized Planck constant. The homogeneous phase is unstable for and stable for . The inhomogeneous phase is stable for and disappears for . We point out analogies between the bosonic HMF model and the concept of boson stars in astrophysics. We also discuss the differences between bosons and fermions for what concerns the thermodynamic limit, the order of the phase transition and the form of the density profiles.
The dynamical convergence of a system to the thermal distribution, or Gibbs state, is a standard assumption across all of the physical sciences. The Gibbs state is determined just by temperature and energies of the system. However, at decreasing system sizes, i.e., for nanoscale and quantum systems, the interaction with their environments is not negligible. The question then arises: Is the system's steady state still the Gibbs state? If not, how may the steady state depend on the interaction details? Here, we provide an overview of recent progress on answering these questions. We expand on the state of the art along two general avenues: First, we take the static point-of-view, which postulates the so-called mean force Gibbs state. This view is commonly adopted in the field of strong coupling thermodynamics, where modified laws of thermodynamics and nonequilibrium fluctuation relations are established on the basis of this modified state. Second, we take the dynamical point of view, originating from the field of open quantum systems, which examines the time-asymptotic steady state within two paradigms. We describe the mathematical paradigm, which proves return to equilibrium, i.e., convergence to the mean force Gibbs state, and then discuss a number of microscopic physical methods, particularly master equations. We conclude with a summary of established links between statics and equilibration dynamics and provide an extensive list of open problems. This comprehensive overview will be of interest to researchers in the wider fields of quantum thermodynamics, open quantum systems, mesoscopic physics, statistical physics, and quantum optics and will find applications whenever energy is exchanged on the nanoscale, from quantum chemistry and biology to magnetism and nanoscale heat management.
Abstract We investigate the classical-quantum correspondence of non-Hermitian Spin-orbit (SO)-coupled bosonic junctions, where an effective decay term is introduced in one of the two wells. Starting from the normalized two-point functions, we analytically demonstrate that the mean-field system has a classical Hamiltonian structure, and we successfully derive a non-Hermitian discrete nonlinear Schrödinger (Gross–Pitaevskii) equation. We discover that near the symmetry-breaking phase transition point, the correspondence between classical (mean-field) and quantum dynamics is more likely to break down. Our numerical simulations of the full quantum model, limited to a finite number of particles due to computational constraints, reveal that when the effective spin–orbit coupling (SOC) strength takes half-integer values, atomic self-trapping in a non-lossy well consistently occurs regardless of the system parameters, and the corresponding quantum dynamics exhibit remarkable insensitivity to the number of particles in this scenario. Additionally, we reveal that in both the mean-field and many-particle models, the SOC effects can greatly promote the synchronous periodic oscillations between the spin-up and spin-down components, and this synchronous dynamic is closely related to symmetry.