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Physical Review Letters

Dissipative Quantum and Classical Liouville Mechanics of the Anharmonic Oscillator

Gerard J Milburn, Catherine A. Holmes

Published May 26, 1986• 307 citations
Publisher

Abstract

We present a solution for the dynamics of an anharmonic oscillator coupled to a zero-temperature heat bath. Comparison of observable properties in a classical and quantum description uses true joint phase-space probability densities. The time evolution of the density in the quantum case is rapidly "reduced" to that given in the classical description. The rate of reduction is proportional to the product of the damping rate and the oscillator's initial energy. Quite rapidly, typical quantum recurrence effects are destroyed and the classical "whorl" structure restored. We point out the close similarity with rapid destruction of quantum coherence through dissipation.

DOI
10.1103/physrevlett.56.2237

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We present a solution for the dynamics of an anharmonic oscillator coupled to a zero-temperature heat bath. Comparison of observable properties in a classical and quantum description uses true joint phase-space probability densities. The time evolution of the density in the quantum case is rapidly "reduced" to that given in the classical description. The rate of reduction is proportional to the product of the damping rate and the oscillator's initial energy. Quite rapidly, typical quantum recurrence effects are destroyed and the classical "whorl" structure restored. We point out the close similarity with rapid destruction of quantum coherence through dissipation.
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We present the general solutions for the classical and quantum dynamics of the anharmonic oscillator coupled to a purely diffusive environment. In both cases, these solutions are obtained by the application of the Baker-Campbell-Hausdorff (BCH) formulas to expand the evolution operator in an ordered product of exponentials. Moreover, we obtain an expression for the Wigner function in the quantum version of the problem. We observe that the role played by diffusion is to reduce or to attenuate the the characteristic quantum effects yielded by the nonlinearity, as the appearance of coherent superpositions of quantum states (Schr\\"{o}dinger cat states) and revivals.
The decoherence of an anharmonic oscillator in a thermal harmonic bath is examined via a semiclassical approach. A computational strategy is presented and exploited to calculate the time dependence of the purity and the decay of individual matrix elements in the energy representation for a variety of initial states. The time dependence of the decoherence is found to depend on the temperature of the bath, the coupling strength, the initial state of the oscillator, and the choice of quantity measuring the decoherence. Recurrences in the purity and in the off-diagonal matrix elements are observed, as well as the collapse of these matrix elements to the diagonal, providing evidence for the retention of quantum coherence for time scales longer than that indicated by the purity. The results are used to analyze the utility of the Caldeira-Leggett and Redfield models of decoherence and to assess the dependence of dephasing rates on the degree of structure in phase space. In several cases we find that the dephasing dynamics can be described as an initial Zeno-effect regime, followed by a Caldeira-Leggett region, followed by recurrences.
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Phase properties of a damped anharmonic oscillator are studied within the Hermitian phase formalism of Pegg and Barnett. Exact analytical formulas for the phase distribution function, the expectation value and variance of the phase operator, and the expectation value and variance of the cosine of the phase operator are obtained assuming the zero-temperature reservoir and a coherent initial state of the system. It is shown that quantum periodicity in the evolution of phase quantities is destroyed by damping. The effect of damping on the formation of discrete superpositions of coherent states is discussed. A comparison is made between different phase approaches.
We have studied quantum-mechanical behavior of a driven Morse oscillator coupled to a bath of harmonic oscillators. The purpose is to compare the quantum behavior of such a system with the classical solutions of a driven damped Morse oscillator. We start with the quantum Liouville equation, in which the Hamiltonian of the Morse oscillator is expressed in terms of generators of an su(2) Lie algebra. This algebra and the Markovian approximation allow us to derive the generalized master equation (for the reduced density matrix of the Morse oscillator), which contains level-dependent energy and phase relaxation terms. We have numerically integrated the differential equations of the matrix elements to obtain the time evolution of the reduced density matrix and the energy of the Morse oscillator. We show that the energy of the Morse oscillator in general varies with time and eventually reaches an asymptotic oscillatory state. The mean energy value of the asymptotic oscillatory state is studied as a function of the relaxation rates and laser frequency and amplitude. Vibrational distributions have also been found as functions of laser frequency and amplitude. The shape of the distribution changes gradually as laser amplitude increases; it first peaks at the ground state at a small field amplitude, then it peaks at some excited state at a large field amplitude, and for an amplitude in between it can have two maxima. This bimodal vibrational distribution reflects the bistability observed in the classical and semiclassical models. Thus bistability exists in quantum results, not as a hysteresis loop, but as a bimodal distribution. Finally, we show that as laser intensity increases, the time series of the oscillator energy evolves from regular to quasiperiodic behavior, and eventually a chaotic-looking series appears.