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The Journal of Chemical Physics

On Some Points of the Bose-Einstein Condensation

L. Goldstein

Published Mar 1, 1941• 13 citations
Publisher

Abstract

The peculiar condensation in phase space of ideal Bose-Einstein gases is discussed when the internal energy states of the atoms or molecules is taken into account and when the gas of atoms without internal structure is placed in an external conservative field of force. The inclusion of the internal energy states decreases while the application of the external field increases the condensation temperature from its value in absence of either of these causes. The transition phenomenon, apart from the preceding change in the condensation temperature, proceeds in the same way as in the case of the free gas atoms without internal structure; in particular, the order of the transition remains invariable, as the continuity of the heat capacity at constant volume is maintained at the transition point.

DOI
10.1063/1.1750890

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Journal of Zhangzhou Normal University•Jan 1, 2001•0 citations
The peculiar condensation in phase space of ideal Bose-Einstein gases is discussed when the internal energy states of the atoms or molecules is taken into account and when the gas of atoms without internal structure is placed in an external conservative field of force. The inclusion of the internal energy states decreases while the application of the external field increases the condensation temperature from its value in absence of either of these causes. The transition phenomenon, apart from the preceding change in the condensation temperature, proceeds in the same way as in the case of the free gas atoms without internal structure; in particular, the order of the transition remains invariable, as the continuity of the heat capacity at constant volume is maintained at the transition point.
The condition which has to be fulfilled in order that the Bose-Einstein condensation be accompanied by a discontinuity of the heat capacity at the condensation temperature is discussed. The nature of the transition depends on the distribution of the energy levels of the individual particles forming the gas. The condensation is studied for several types of individual energy spectra. It is shown that all those Bose-Einstein (B.E.) assemblies which admit a non-ambiguous definition of the statistical distribution function present, beside interesting analogies, a qualitatively different behavior from that observed in liquid helium. It appears that as long as the transition in momentum space of non-ideal B.E. systems is not understood, the possibility of connection between B.E. condensation and the transition observed in liquid helium remains an open problem.
The properties of a trapped ideal Bose gas in n -dimensional space are studied. General analytic expressions of the critical temperature of Bose-Einstein condensation, the jump of heat capacity at and the fraction of condensation at temperatures below have been derived. How these physical quantities depend on the external potential, particle characteristics and space dimensionality are discussed. We find that when a proper external potential is taken, Bose-Einstein condensation may occur in any dimensional space.
The features of Bose condensation in an equilibrium ideal gas consisting of two types of charged fermions and their bound states—hydrogenlike atoms—in the presence of equilibrium between the photons and matter are investigated. It is shown that under such conditions the main influence on the Bose–Einstein condensation comes from the existence of levels concerned with the hyperfine splitting of the ground state of the hydrogenlike atom. The critical temperature and condensate density as functions of magnetic field are determined by considering effects due to the additional splitting of the levels of the hyperfine structure of the ground state in an external uniform static magnetic field (the Zeeman and Paschen–Back effects). It is found that under conditions of total statistical equilibrium in the system, a condensate is formed only by atoms found in the lowest energy state. It is shown that in the absence of equilibrium between radiation and matter, in the region of ultralow temperatures and low densities, the system can be treated as a multicomponent ideal gas of hydrogenlike atoms. The existence of a hierarchy of individual transition temperatures of each of the samples to the state with Bose–Einstein condensation is established. Expressions are found for the critical temperatures and number densities of particles in the condensate for each of the system components.