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Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics

Memory effects and virial corrections in nonequilibrium dense systems

Klaus Morawetz, G. Roepke

Published May 1, 1995• 40 citations
Publisher

Abstract

A dense interacting Bose or Fermi gas is considered. Within the Kadanoff-Baym real-time Green-function technique a generalized kinetic equation is derived in the nonequilibrium ladder approximation. As a Markovian limit the Boltzmann-Uehling-Uhlenbeck equation is recovered. The relevance of retardation effects in the kinetic equation of dense systems is shown. It turns out that the stationary solution of the generalized kinetic equation reproduces the second virial coefficient of the equation of state, including the Beth-Uhlenbeck quantum corrections. We establish a generalized kinetic equation describing correlation effects in a consistent approach to nonequilibrium for Bose and Fermi systems. In this way we give a generalization of the Beth-Uhlenbeck formula that applies to nonequilibrium and to finite systems. The derivation makes use of the time dependent T-matrix equation, which establishes a generalization of the Bethe-Goldstone equation. The correlated parts of the density and energy, which can be interpreted as virial corrections, are thermodynamically consistent. In this way global energy conservation is fulfilled.

DOI
10.1103/physreve.51.4246

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A dense interacting Bose or Fermi gas is considered. Within the Kadanoff-Baym real-time Green-function technique a generalized kinetic equation is derived in the nonequilibrium ladder approximation. As a Markovian limit the Boltzmann-Uehling-Uhlenbeck equation is recovered. The relevance of retardation effects in the kinetic equation of dense systems is shown. It turns out that the stationary solution of the generalized kinetic equation reproduces the second virial coefficient of the equation of state, including the Beth-Uhlenbeck quantum corrections. We establish a generalized kinetic equation describing correlation effects in a consistent approach to nonequilibrium for Bose and Fermi systems. In this way we give a generalization of the Beth-Uhlenbeck formula that applies to nonequilibrium and to finite systems. The derivation makes use of the time dependent T-matrix equation, which establishes a generalization of the Bethe-Goldstone equation. The correlated parts of the density and energy, which can be interpreted as virial corrections, are thermodynamically consistent. In this way global energy conservation is fulfilled.
In the framework of real-time Green's functions, the general kinetic equations are investigated in a first-order gradient expansion. Within this approximation, the problem of the reconstruction of the two-time correlation functions from the one-time Wigner function was solved. For the Wigner function, a cluster expansion is found in terms of a quasiparticle distribution function. In equilibrium, this expansion leads to the well-known generalized Beth-Uhlenbeck expression of the second virial coefficient. As a special case, the T-matrix approximation for the self-energy is investigated. The quantum kinetic equation derived thus has, besides the (Markovian) Boltzmann collision integral, additional terms due to the retardation expansion which reflect memory effects. Special interest is paid to the case that bound states exist in the system. It is shown that the bound state contribution, which can be introduced via a bilinear expansion of the two-particle T matrix, follows from the first-order retardation term in the general kinetic equation. The full Wigner function is now a sum of one function describing the unbound particles and another one for the bound state contribution. The latter two functions have to be determined from a coupled set of kinetic equations. In contrast to the quantum Boltzmann equation, energy and density of a nonideal system are conserved. \textcopyright{} 1996 The American Physical Society.
A recently developed method [Semkat et al., Phys. Rev. E 59, 1557 (1999); Kremp et al., in Progress in Nonequilibrium Green’s Functions (World Scientific, Singapore, 2000), p. 34] for incorporating initial binary correlations into the Kadanoff–Baym equations (KBE) is used to derive a generalized T-matrix approximation for the self-energies. It is shown that the T-matrix obtains additional contributions arising from initial correlations. Using these results and taking the time-diagonal limit of the KBE, a generalized quantum kinetic equation in binary collision approximation is derived. This equation is a far-reaching generalization of Boltzmann-type kinetic equations: It self-consistently includes memory effects (retardation, off-shell T-matrices) as well as many-particle effects (damping, in-medium T-matrices) and spin-statistics effects (Pauli-blocking).
A single-time quantum transport equation, which includes effects beyond the quasiparticle approximation, is derived for Fermi systems in the framework of nonequilibrium real-time Green's functions theory. Ternary correlations are incorporated in the kinetic description via a cluster expansion for the self-energies (e.g., the transport vertex and the width) truncated at the level of three-body scattering amplitudes. A finite temperature/density formulation of the three-body problem is given. Corresponding three-body equations reduce to the well-known Faddeev equations in the vacuum limit. In equilibrium the equation of state contains virial corrections proportional to the third quantum virial coefficient.
In a previous publication [H. S. K\"ohler, Phys. Rev. C 51, 3232 (1995)] equilibration rates were studied for an extended system of nonequilibrium nuclear matter. The two-time Green's functions in the Kadanoff-Baym (KB) formalism were solved numerically. These quantum-mechanical calculations were compared with the Markovian (semi)classical Uehling-Uhlenbeck collision term often used in the analysis of collisions between heavy ions. The equilibration was found to be substantially slowed down by quantum effects. The theoretical as well as experimental study of nonequilibrium systems is of course of great interest in many areas of physics, e.g., within the realm of quantum transport in solid state devices. On the theoretical side various methods and approximations are the subject of intensive study. By the KB ansatz, for example, the equations can be simplified to a one-time kinetic equation while preserving the non-Markovian character. The generalized KB (GKB) ansatz of Lipavsky, Spicka, and Velicky [Phys. Rev. B 34, 6933 (1986)] is often preferred. In this paper approximations based upon the GKB ansatz are discussed in relation to the exact KB formalism. Numerical comparisons are made for both the strongly interacting nuclear medium as well as an electron plasma. A non-Markovian collision integral, including memory effects in a quasiparticle approximation, is often discussed in the literature. It is found that this approximation appreciably overestimates the collision rates even more than the classical (Boltzmann) approximation. The inclusion of a width in the spectral function, i.e., going beyond the quasiparticle approximation, gives considerable improvement. The competition between the memory and correlation effects is found to lead to an anomalous saturation of the relaxtion rate. \textcopyright{} 1996 The American Physical Society.
A quantum kinetic equation for the density matrix is derived from nonequilibrium Green functions using the generalized Kadanoff-Baym ansatz and corrections beyond. The Markovian reconstruction of the Green function and the quasistationary approximation are used to approximate the corrections, making their implementation in numerical simulations faster. On electron tunneling under conditions when the prediction of the uncorrected kinetic equation seriously departs from the exact solution, we show that the corrections reduce the error by an order of magnitude.
A link between correlation contributions to kinetic equations for dense quantum systems and the energy conservation is considered. In order that the energy be conserved by an approximate collision integral, the one-particle density matrix and the mean interaction energy are treated as independent state parameters. It is shown how the density operator method can be used to derive non-Markovian kinetic equations including the correlation effect associated with the energy conservation. A quantum generalization of the Enskog theory is discussed.