In quantum mechanics, the properties of an unstable system are closely related to its corresponding energy distribution. One of the predictions of the theory is the emergence of a late-time power law in the survival probability $P(t)$ of the unstable state. However, in complex systems, similar effects may emerge due to other phenomena. This is the case for nonextensive statistical models, for some continuous lifetime distribution models, and also for certain energy-migration models applied to fluorescence. In this work, these alternative interpretations are confronted with data from time-resolved fluorescence spectroscopy experiments with erythrosine B and eosine Y as fluorophores. It turns out that some of the features expected within the quantum-mechanical description, such as the sharp transition from the exponential to the power-law regime, cannot be reproduced by the specific statistical and energy-migration parametrizations fitted in the analysis.In quantum mechanics, the properties of an unstable system are closely related to its corresponding energy distribution. One of the predictions of the theory is the emergence of a late-time power law in the survival probability $P(t)$ of the unstable state. However, in complex systems, similar effects may emerge due to other phenomena. This is the case for nonextensive statistical models, for some continuous lifetime distribution models, and also for certain energy-migration models applied to fluorescence. In this work, these alternative interpretations are confronted with data from time-resolved fluorescence spectroscopy experiments with erythrosine B and eosine Y as fluorophores. It turns out that some of the features expected within the quantum-mechanical description, such as the sharp transition from the exponential to the power-law regime, cannot be reproduced by the specific statistical and energy-migration parametrizations fitted in the analysis.

quant-pharXiv:2610.00603Oct 2, 2026

On the decay laws of unstable quantum systems

W. Garczyński

Acta Physica Polonica BJan 1, 19741 citation

Long quantum transition times due to unstable semiclassical dynamics

D. G. Levkov, A. G. Panin

Quantum transitions are described semiclassically as motions of systems along (complex) trajectories. We consider the cases when the semiclassical trajectories are unstable and find that durations of the corresponding transitions are large. In addition, we show that the probability distributions over transition times have unusual asymmetric form in cases of unstable trajectories. We investigate in detail three types of processes related to unstable semiclassical dynamics. First, we analyze recently proposed mechanism of multidimensional tunneling where transitions proceed by formation and subsequent decay of classically unstable ``states.'' The second class of processes includes one-dimensional activation transitions due to energy dispersion. In this case the semiclassical transition-time distributions have universal form. Third, we investigate long-time asymptotics of transition-time distributions in the case of overbarrier wave packet transmissions. We show that behavior of these asymptotics is controlled by unstable semiclassical trajectories which linger near the barrier top.Quantum transitions are described semiclassically as motions of systems along (complex) trajectories. We consider the cases when the semiclassical trajectories are unstable and find that durations of the corresponding transitions are large. In addition, we show that the probability distributions over transition times have unusual asymmetric form in cases of unstable trajectories. We investigate in detail three types of processes related to unstable semiclassical dynamics. First, we analyze recently proposed mechanism of multidimensional tunneling where transitions proceed by formation and subsequent decay of classically unstable ``states.'' The second class of processes includes one-dimensional activation transitions due to energy dispersion. In this case the semiclassical transition-time distributions have universal form. Third, we investigate long-time asymptotics of transition-time distributions in the case of overbarrier wave packet transmissions. We show that behavior of these asymptotics is controlled by unstable semiclassical trajectories which linger near the barrier top.

arXiv:0903.3916Physical Review ANov 18, 20092 citations

Decays of Unstable Quantum Systems

Charis Anastopoulos

arXiv:1808.03798International Journal of Theoretical PhysicsDec 18, 201816 citations

Initial and regime situations in the decay of unstable quantum systems

A. Rimini, G. Zambotti

Nuovo cimento della Società italiana di fisica. A, Nuclei, particles and fieldsJan 1, 19800 citations

Transformation of intermediate times in the decays of moving unstable quantum systems via the exponential modes

Filippo Giraldi

Abstract The transformation of canonical decay laws of moving unstable quantum systems is derived from the basic principles of quantum theory and special relativity by approximating, over intermediate times, the decay laws at rest with superpositions of exponential modes via the Prony analysis. The survival probability , which is detected in the laboratory reference frame where the unstable system moves with constant linear momentum p , is represented by the transformed form of the survival probability at rest . The transformation of the intermediate times, which is induced by the change of reference frame, is obtained by evaluating the function . Under determined conditions, this function grows linearly and the survival probability transforms, approximately, according to a scaling law over an estimated time window. The relativistic dilation of times holds, approximately, over the time window if the mass of resonance of the mass distribution density is considered to be the effective mass at rest of the moving unstable quantum system.Abstract The transformation of canonical decay laws of moving unstable quantum systems is derived from the basic principles of quantum theory and special relativity by approximating, over intermediate times, the decay laws at rest with superpositions of exponential modes via the Prony analysis. The survival probability , which is detected in the laboratory reference frame where the unstable system moves with constant linear momentum p , is represented by the transformed form of the survival probability at rest . The transformation of the intermediate times, which is induced by the change of reference frame, is obtained by evaluating the function . Under determined conditions, this function grows linearly and the survival probability transforms, approximately, according to a scaling law over an estimated time window. The relativistic dilation of times holds, approximately, over the time window if the mass of resonance of the mass distribution density is considered to be the effective mass at rest of the moving unstable quantum system.

arXiv:1902.05210Journal of Physics A Mathematical and TheoreticalSep 16, 20193 citations

P(t)

of the unstable state. However, in complex systems, similar effects may emerge due to other phenomena. This is the case for nonextensive statistical models, for some continuous lifetime distribution models, and also for certain energy-migration models applied to fluorescence. In this work, these alternative interpretations are confronted with data from time-resolved fluorescence spectroscopy experiments with erythrosine B and eosine Y as fluorophores. It turns out that some of the features expected within the quantum-mechanical description, such as the sharp transition from the exponential to the power-law regime, cannot be reproduced by the specific statistical and energy-migration parametrizations fitted in the analysis.