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arXiv:0903.3916 · Physical Review A

Long quantum transition times due to unstable semiclassical dynamics

D. G. Levkov, A. G. Panin

Published Nov 18, 2009• 2 citations
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Abstract

Quantum transitions are described semiclassically as motions of systems along (complex) trajectories. We consider the cases when the semiclassical trajectories are unstable and find that durations of the corresponding transitions are large. In addition, we show that the probability distributions over transition times have unusual asymmetric form in cases of unstable trajectories. We investigate in detail three types of processes related to unstable semiclassical dynamics. First, we analyze recently proposed mechanism of multidimensional tunneling where transitions proceed by formation and subsequent decay of classically unstable ``states.'' The second class of processes includes one-dimensional activation transitions due to energy dispersion. In this case the semiclassical transition-time distributions have universal form. Third, we investigate long-time asymptotics of transition-time distributions in the case of overbarrier wave packet transmissions. We show that behavior of these asymptotics is controlled by unstable semiclassical trajectories which linger near the barrier top.

DOI
10.1103/physreva.80.052110

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Quantum transitions are described semiclassically as motions of systems along (complex) trajectories. We consider the cases when the semiclassical trajectories are unstable and find that durations of the corresponding transitions are large. In addition, we show that the probability distributions over transition times have unusual asymmetric form in cases of unstable trajectories. We investigate in detail three types of processes related to unstable semiclassical dynamics. First, we analyze recently proposed mechanism of multidimensional tunneling where transitions proceed by formation and subsequent decay of classically unstable ``states.'' The second class of processes includes one-dimensional activation transitions due to energy dispersion. In this case the semiclassical transition-time distributions have universal form. Third, we investigate long-time asymptotics of transition-time distributions in the case of overbarrier wave packet transmissions. We show that behavior of these asymptotics is controlled by unstable semiclassical trajectories which linger near the barrier top.
It was found recently that processes of multidimensional tunneling are generally described at high energies by unstable semiclassical trajectories. We study two observational signatures related to the instability of trajectories. First, we find an additional power-law dependence of the tunneling probability on the semiclassical parameter as compared to the standard case of potential tunneling. The second signature is a substantial widening of the probability distribution over final-state quantum numbers. These effects are studied using a modified semiclassical technique which incorporates stabilization of the tunneling trajectories. The technique is derived from first principles. We obtain expressions for the inclusive and exclusive tunneling probabilities in the case of unstable semiclassical trajectories. We also investigate the 'phase transition' between the cases of stable and unstable trajectories across certain 'critical' values of energy. Finally, we derive the relation between the semiclassical probabilities of tunneling from the low-lying and highly excited initial states. This puts on firm ground a conjecture made previously in the semiclassical description of collision-induced tunneling in field theory.
In recent papers we demonstrated a new class of barrier tunneling phenomena which can be observed in periodically driven one dimensional barrier systems (i.e., 1.5D barrier tunneling systems). In such systems the tunneling component is in general accompanied by remarkable interference fringe patterns as the perturbation strength exceeds a certain characteristic value. Such a phenomenon is quite general and is not restricted to periodically driven 1D systems, and it may be also observed in intrinsic two dimensional autonomous systems. The complex-domain semiclassical theory developed by ourselves was applied to the problem, and we succeeded in reconstructing every detail of the fringed tunneling wavefunction only by using the complexified classical tunneling trajectories. This fact greatly motivates us to investigate the mechanism of the tunneling in terms of “classical mechanics”. The later part of the present paper is devoted to asserting the generality of the “classical mechanism” of the fringed tunneling. We develop detailed semiclassical analyses in the complex domain and demonstrate that the key trajectories contributing to the fringed tunneling are quite different from the instanton-like trajectories, which works only in unperturbed or weakly-perturbed regimes. Indeed, such trajectories are traveling in the complex phase space being guided by the complexified stable and unstable manifolds which exhibit heteroclinic-like entanglement with the incoming wave manifolds.
There has been a surprising degree of uncertainty about how, or even whether, the standard semiclassical theory of Van Vleck and Gutzwiller (VVG) can be used to treat the time-dependent dynamics of tunneling through barriers. At issue is how semiclassical theory describes the time evolution of tunneling. This uncertainty has hindered development of practical techniques for semiclassical calculations of multidimensional systems. It is shown here that the VVG theory can indeed be applied to barrier tunneling, but generally requires consideration of classical trajectories with both complex initial conditions and complex time paths, even for systems with one degree of freedom. The present approach is verified by applying it to the classically forbidden propagation of a wave packet through a one-dimensional barrier---a very basic problem that cannot be treated by the VVG theory without the modifications described here.
We develop the semiclassical method of complex trajectories in application to chaotic dynamical tunneling. First, we suggest a systematic numerical technique for obtaining complex tunneling trajectories by the gradual deformation of the classical ones. This provides a natural classification of the tunneling solutions. Second, we present a heuristic procedure for sorting out the least suppressed trajectory. As an illustration, we apply our technique to the process of chaotic tunneling in a quantum mechanical model with two degrees of freedom. Our analysis reveals rich dynamics of the system. At the classical level, there exists an infinite set of unstable solutions forming a fractal structure. This structure is inherited by the complex tunneling paths and plays a central role in the semiclassical study. The process we consider exhibits the phenomenon of optimal tunneling: the suppression exponent of the tunneling probability has a local minimum at a certain energy which is thus (locally) the optimal energy for tunneling. We test the proposed method by comparison of the semiclassical results with the results of the exact quantum computations and find a good agreement.
The time behavior of a wave packet, transmitted through a potential barrier, is investigated for all times assuming it to be initially located outside the asymmetric barrier. The survival probability of the initial state, which characterizes the decay of the unstable quantum system in three time domains, is discussed. The presence of initial, exponential, and long-time regimes is a general feature of the decay process. We analytically found the three crucial points of time that separate these regimes. These characteristic times are set by simple formulae, including momentum distribution. It is then shown that the radius of convergence of the cumulant expansion for the survival probability is always small. A long-time behavior of survival probability is described by the asymptotic series whose coefficients decrease with increasing particle energy but at different rates. To be specific, we have examined the exactly solvable model of tunneling through a finite range triangular barrier.
A semiclassical method of complex trajectories for the calculation of the tunneling exponent in systems with many degrees of freedom is further developed. It is supplemented with an easily implementable technique, which enables one to single out the physically relevant trajectory from the whole set of complex classical trajectories. The method is applied to semiclassical transitions of a bound system through a potential barrier. We find that the properties of physically relevant complex trajectories are qualitatively different in the cases of potential tunneling at low energy and dynamical tunneling at energies exceeding the barrier height. Namely, in the case of high energies, the physically relevant complex trajectories describe tunneling via creation of a state close to the top of the barrier. The method is checked against exact solutions of the Schrodinger equation in a quantum mechanical system of two degrees of freedom.